Search results for "Plume"
showing 10 items of 208 documents
Reactive halogen chemistry in volcanic plumes
2007
[1] Bromine monoxide (BrO) and sulphur dioxide (SO2) abundances as a function of the distance from the source were measured by ground-based scattered light Multiaxis Differential Optical Absorption Spectroscopy (MAX-DOAS) in the volcanic plumes of Mt. Etna on Sicily, Italy, in August–October 2004 and May 2005 and Villarica in Chile in November 2004. BrO and SO2 spatial distributions in a cross section of Mt. Etna's plume were also determined by Imaging DOAS. We observed an increase in the BrO/SO2 ratio in the plume from below the detection limit near the vent to about 4.5 × 10−4 at 19 km (Mt. Etna) and to about 1.3 × 10−4 at 3 km (Villarica) distance, respectively. Additional attempts were …
Volcanic plume monitoring at Mount Etna by diffusive (passive) sampling
2004
[1] This paper reports the use of diffusive tubes in determining HF, HCl, and SO2 in the volcanic plume of Mount Etna in an attempt to highlight the potential of this method in studying volcanoes. In a first application a network of 18 diffusive tubes was installed on Etna's flanks, aimed at evaluating the atmospheric dispersion of the volcanic plume on a local scale. Results showed a monotonic decrease in volatile air concentrations with distance from the craters (HF from 0.15 to <0.003 μmol m−3, HCl from 2 to <0.01 μmol m−3, and SO2 from 11 to 0.04 μmol m−3), revealing the prevalently volcanic contribution. Matching of SO2/HCl and HCl/HF volatile ratios with contemporaneous measurements a…
Sources, size distribution, and downwind grounding of aerosols from Mount Etna
2006
The number concentrations and size distributions of aerosol particles >0.3 mm diameter were measured at the summit of Mount Etna and up to 10 km downwind from the degassing vents during July and August 2004. Aerosol number concentrations reached in excess of 9 106 L1 at summit vents, compared to 4–8 104 L1 in background air. Number concentrations of intermediate size particles were higher in emissions from the Northeast crater compared to other summit crater vents, and chemical composition measurements showed that Northeast crater aerosols contained a higher mineral cation content compared to those from Voragine or Bocca Nuova, attributed to Strombolian or gas puffing activity within the ve…
The tropospheric processing of acidic gases and hydrogen sulphide in volcanic gas plumes as inferred from field and model investigations
2007
Abstract. Improving the constraints on the atmospheric fate and depletion rates of acidic compounds persistently emitted by non-erupting (quiescent) volcanoes is important for quantitatively predicting the environmental impact of volcanic gas plumes. Here, we present new experimental data coupled with modelling studies to investigate the chemical processing of acidic volcanogenic species during tropospheric dispersion. Diffusive tube samplers were deployed at Mount Etna, a very active open-conduit basaltic volcano in eastern Sicily, and Vulcano Island, a closed-conduit quiescent volcano in the Aeolian Islands (northern Sicily). Sulphur dioxide (SO2), hydrogen sulphide (H2S), hydrogen chlori…
Porous aerosol in degassing plumes of Mt. Etna and Mt. Stromboli
2016
Abstract. Aerosols of the volcanic degassing plumes from Mt. Etna and Mt. Stromboli were probed with in situ instruments on board the Deutsches Zentrum für Luft- und Raumfahrt research aircraft Falcon during the contrail, volcano, and cirrus experiment CONCERT in September 2011. Aerosol properties were analyzed using angular scattering intensities and particle size distributions simultaneously measured with the Polar Nephelometer and the Forward Scattering Spectrometer probes (FSSP series 100 and 300), respectively. Aerosols of degassing plumes are characterized by low values of the asymmetry parameter (between 0.6 and 0.75); the effective diameter was within the range of 1.5–2.8 µm and the…
The primary volcanic aerosol emission from Mt Etna: Size-resolved particles with SO2 and role in plume reactive halogen chemistry
2018
International audience; Volcanoes are an important source of aerosols to the troposphere. Within minutes after emission, volcanic plume aerosol catalyses conversion of co-emitted HBr, HCl into highly reactive halogens (e.g. BrO, OClO) through chemical cycles that cause substantial ozone depletion in the dispersing downwind plume.This study quantifies the sub-to-supramicron primary volcanic aerosol emission (0.2-5 μm diameter) and its role in this process. An in-situ ground-based study at Mt Etna (Italy) during passive degassing co-deployed an optical particle counter and Multi-Gas SO2 sensors at high time resolution (0.1 Hz) enabling to characterize the aerosol number, size-distribution and…
Petrogenetic evolution of metabasalts and metakomatiites of the lower Onverwacht Group, Barberton Greenstone Belt (South Africa)
2019
A well-preserved sequence, by Archean standards, of mantle-derived metabasalts and metakomatiites forms large parts of the lower Onverwacht Group of the Barberton Greenstone Belt (South Africa). To elucidate the origin of mafic and ultramafic rocks from this 3.55 to 3.45 Ga sequence, we present a comprehensive geochemical dataset including major and trace elements as well as Lu-Hf and Sm-Nd isotope compositions for a variety of metavolcanic rocks. These include metabasalts of the amphibolite-facies Sandspruit and Theespruit Formations as well as metabasalts and metakomatiites of the lower greenschist-facies Komati Formation. Based on their incompatible trace element patterns, the basalts of…
Petrology of mafic lavas within the Onega plateau, central Karelia: evidence for 2.0 Ga plume-related continental crustal growth in the Baltic Shield
1998
The Onega plateau constitutes part of a vast continental flood basalt province in the SE Baltic Shield. It consists of Jatulian-Ludikovian submarine volcanic, volcaniclastic and sedimentary sequences attaining in places 4.5 km in thickness. The parental magmas of the lavas contained ∼10% MgO and were derived from melts generated in the garnet stability field at depths 80–100 km. The Sm-Nd mineral and Pb-Pb whole-rock isochron ages of 1975 ± 24 and 1980 ± 57 Ma for the upper part of the plateau and a SHRIMP U-Pb zircon age of 1976 ± 9 Ma for its lower part imply the formation of the entire sequence within a short time span. These ages coincide with those of picrites in the Pechenga-Imandra b…
The radiogenic isotope composition of the high-latitude North Atlantic mantle
1997
New Sr, Nd, and Pb isotope data on North Atlantic high-latitude (about 69°30'N to 76°30'N) intraplate and ridge volcanic rocks, together with published data, are used to evaluate the mantle sources contributing to Iceland and the surrounding ridges. Considerable overlap between Icelandic lavas and depth-filtered North Atlantic mid-oceanic-ridge basalts (MORBs) in all isotope plots confirm that a MORB asthenosphere-plume mixing model can explain the ranges of isotope compositions found on Iceland. Regional isotope patterns north of lat 53°N show two distinct mantle domains. Lavas forming a low-radiogenic-Pb, high-radiogenic-Sr array occur north of central Iceland, whereas volcanic rocks form…
Volcanism on the Eggvin Bank (Central Norwegian-Greenland Sea, latitude ∼71°N): age, source, and relationship to the Iceland and putative Jan Mayen p…
2004
Abstract The Eggvin Bank (Central Norwegian-Greenland Sea, latitude ∼71°N) is a topographically anomalous shallow area with scattered volcanic peaks extending between the island of Jan Mayen and East Greenland and straddling the northern segment of the mid-Atlantic Kolbeinsey Ridge axis. Basalts dredged from the Eggvin Bank range from variably depleted, tholeiitic, near-axis lavas to enriched, transitional-to-alkaline, off-axis seamount lavas. In terms of normalised incompatible element patterns, the most depleted, near-axis tholeiite is similar to neighbouring Kolbeinsey Ridge basalts, whereas the off-axis, transitional-to-alkaline lavas are similar to other alkaline basalts occurring clos…