Search results for "Pluton"
showing 10 items of 80 documents
Risk of Lung Cancer Mortality in Nuclear Workers from Internal Exposure to Alpha Particle-emitting Radionuclides
2017
Supplemental Digital Content is available in the text.
Understanding and Predicting Plutonium Alloys Aging: A Coupled Experimental and Theoretical Approach
2003
Understanding plutonium aging is a real challenge that requires developing very ambitious modeling and experiments. Examples of the different techniques developed and the physical values that can be reached are presented here.
Application of isotope-dilution laser ablation ICP-MS for direct determination of Pu concentrations in soils at pg g(-1) levels.
2003
The methods available for determination of environmental contamination by plutonium at ultra-trace levels require labor-consuming sample preparation including matrix removal and plutonium extraction in both nuclear spectroscopy and mass spectrometry. In this work, laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was applied for direct analysis of Pu in soil and sediment samples. Application of a LINA-Spark-Atomizer system (a modified laser ablation system providing high ablation rates) coupled with a sector-field ICP-MS resulted in detection limits as low as 3x10(-13) g g(-1) for Pu isotopes in soil samples containing uranium at a concentration of a few microg g(-1). …
Geometric aspects of synkinematic granite intrusion into a ductile shear zone — an example from the Yunmengshan core complex, northern China
2005
The Cretaceous Yungmengshan core complex in northern China contains a large syntectonic granodiorite batholith that intrudes a slightly older diorite intrusion. A major gently dipping ductile decollement shear zone is developed along the contact of the diorite and granodiorite. The shear zone is invaded by a large volume of granitic and pegmatite veins associated with the main granodiorite batholith during activity of the shear zone under high-grade metamorphic conditions. Progressively older veins are more strongly deformed into tight cylindrical fold structures rotated into parallelism with the lineation and foliation in the shear zone. Parallelism of veins to the foliation is partly due …
Geochemical Interactions of Plutonium with Opalinus Clay Studied by Spatially Resolved Synchrotron Radiation Techniques
2017
Plutonium plays an important role within nuclear waste materials because of its long half-life and high radiotoxicity. The aim of this study was to investigate with high spatial resolution the reactivity of the more oxidized forms of Pu(V,VI) within Opalinus Clay (OPA) rock, a heterogeneous, natural argillaceous rock considered as a potential repository host. A combination of synchrotron based X-ray microprobe and bulk techniques was used to study the spatial distribution and molecular speciation of Pu within OPA after diffusion and sorption processes. Microscopic chemical images revealed a pronounced impact of geochemical heterogeneities concerning the reactivity of the natural barrier mat…
The effect of titanite and other HFSE-rich mineral (Ti-bearing andradite, zircon, eudialyte) fractionation on the geochemical evolution of silicate m…
2008
Abstract We present trace element data for HFSE-rich minerals (titanite, eudialyte, Ti-bearing andradite, zircon) from plutonic rocks of the Eocene Tamazeght complex, High Atlas Mountains, Morocco. In most lithologies significant amounts of titanite are present and as such, titanite fractionation played a major role in the evolution of the HFSE budget of the whole complex. By combining our data with published titanite–melt partition coefficients we explore the effects of titanite fractionation on the evolution of geochemical parameters (Zr/Hf, Nb/Ta, La/Lu and Th/U ratios) during differentiation of silicate melts in detail. Based upon this, we further discuss the genetic relationships betwe…
Thermodynamic studies of actinide complexes. 1. A reappraisal of the solution equilibria between plutonium(IV) and ethylenediaminetetraacetic acid (E…
2007
Abstract A detailed reevaluation of the complexation equilibria of plutonium(IV) with the polyaminocarboxylic sequestering agent EDTA4− has been performed in 1 M (H,K)NO3 media at 298 K by means of visible absorption spectrophotometry and glass-electrode potentiometry at millimolar concentration levels. The high binding affinity even under strongly acidic conditions supports the exclusive formation of the neutral Pu(EDTA) complex over the range 0.01 ≤ [H+] ≤ 0.9 M with an apparent formation constant of log β110 = 25.8(1) at 0.9 M HNO3. Extrapolation to zero ionic strength using the SIT approach provides the first ever-reported NEA–TDB compliant estimate of β 110 0 ( log β 110 0 = 32.2 ( 3 )…
Zvaigžņotā Debess: 2016, Vasara (232)
2016
Contents: “ZVAIGŽŅOTĀ DEBESS” FORTY YEARS AGO: A.Balklavs. New Studies and Conclusions on Nucleus of the Galaxy (abridged) ; U.Dzērvītis. Discussion on Planetary System of Barnard’s Star Continues (abridged) ; M.Eliāss. Meeting of Solar Radio Radiation Section (abridged) ; DEVELOPMENTS in SCIENCE: O.Dumbrājs. Neutrino Oscillations: from the Outset to the Nobel Prize ; R.Misa. Conversation with Andris Ambainis on Quantum Computing Science ; DISCOVERIES: F.Gahbauer. First Direct Detection of Gravitational Waves ; I.Pundure. ATLASGAL Survey of Milky Way Completed ; SPACE RESEARCH and EXPLORATION: J.Jaunbergs. The Story of Pluto’s Satellites ; K.Schwartz. Conducting Ice and Magnetic Field of Ur…
Observation of Collisional De-Excitation Phenomena in Plutonium
2022
Proceedings for the "virtual Workshop on the Atomic Structure of Actinides & Related Topics" conference submitted to the special issue of Atoms "Atomic Structure of the Heaviest Elements". A program of research towards the high-resolution optical spectroscopy of actinide elements for the study of fundamental nuclear structure is currently ongoing at the IGISOL facility of the University of Jyväskylä. One aspect of this work is the development of a gas-cell-based actinide laser ion source using filament-based dispensers of long-lived actinide isotopes. We have observed prominent phenomena in the resonant laser ionization process specific to the gaseous envir…
In-gas-cell laser ionization studies of plutonium isotopes at IGISOL
2016
Abstract In-gas-cell resonance laser ionization has been performed on long-lived isotopes of Pu at the IGISOL facility, Jyvaskyla. This initiates a new programme of research towards high-resolution optical spectroscopy of heavy actinide elements which can be produced in sufficient quantities at research reactors and transported to facilities elsewhere. In this work a new gas cell has been constructed for fast extraction of laser-ionized elements. Samples of 238–240,242 Pu and 244 Pu have been evaporated from Ta filaments, laser ionized, mass separated and delivered to the collinear laser spectroscopy station. Here we report on the performance of the gas cell through studies of the mass spec…