Search results for "Polyaminoacid"

showing 9 items of 9 documents

A facile way to build up branched high functional polyaminoacids with tunable physicochemical and biological properties

2016

Abstract Here, for the first time, branched polyaminoacids bearing α-amino acids as side functions, namely PAA-co-AA and PGA-co-AA, are prepared by heterophase ring opening of polysuccinimide (PSI) with l -arginine or glycine in aqueous environment and at controlled pH. The modulation of the pH of the reaction leads to high-molecular-weight copolymers with tunable functionalization and, as consequence, with tailor-made physicochemical properties. Furthermore, a branched polyaminoacid carrying a preformed bioactive peptide ( l -trileucine) and l -arginine as side pendants, named PATA-co-AA, was synthesized via a similar pathway thus leading to complex biomimetic materials potentially exploit…

Circular dichroismCombinatorial polymer chemistryPolyaminoacidMaterials sciencePolymers and PlasticsGlycineGeneral Physics and Astronomy02 engineering and technologyArginine010402 general chemistryRing (chemistry)01 natural sciencesBioinspiredPhysics and Astronomy (all)CopolymerTrileucineMaterials ChemistryCopolymerOrganic chemistrychemistry.chemical_classificationPolymers and PlasticAqueous solutionOrganic Chemistry021001 nanoscience & nanotechnologyBiomaterial0104 chemical sciencesAmino acidchemistrySurface modificationTitration0210 nano-technologyMacromoleculeEuropean Polymer Journal
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NANOTECHNOLOGIES FOR BIOMEDICAL APLICATIONS

2010

DRUG DELIVERY SYSTEMS POLYAMINOACIDS NANOMEDICINESettore CHIM/09 - Farmaceutico Tecnologico Applicativo
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SOLUBLE AND WATER-SWELLABLE POLYAMINOACIDIC CONSTRUCTS FOR DRUG DELIVERY

2004

DRUG DELIVERYChemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoPOLYAMINOACIDIC CONSTRUCTSDrug deliveryPharmacology
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Composite nanoparticles based on hyaluronic acid chemically cross-linked with alpha,beta-polyaspartylhydrazide.

2007

In this paper, new composite nanoparticles based on hyaluronic acid (HA) chemically cross-linked with alpha,beta polyaspartylhydrazide (PAHy) were prepared by the use of a reversed-phase microemulsion technique. HA-PAHy nanoparticles were characterized by FT-IR spectroscopy, confirming the occurrence of the chemical cross-linking, dimensional analysis, and transmission electron micrography, showing a sub-micrometer size and spherical shape. Zeta potential measurements demonstrated the presence of HA on the nanoparticle surface. A remarkable affinity of the obtained nanoparticles toward aqueous media that simulate some biological fluids was found. Stability studies showed the absence of chem…

Polymers and PlasticsBiocompatibilityCell SurvivalNanoparticleBioengineeringAntineoplastic AgentsPolymeric nanoparticles hyaluronic acid polyaminoacidBiomaterialschemistry.chemical_compoundDrug Delivery SystemsMicroscopy Electron TransmissionPolymer chemistryHyaluronic acidSpectroscopy Fourier Transform InfraredMaterials ChemistryZeta potentialHumansMicroemulsionHyaluronic AcidParticle SizeChemical decompositionChemistryHydrolysisEquipment DesignNylonsCross-Linking ReagentsHydrazinesChemical engineeringNanoparticlesFluorouracilDrug carrierK562 CellsNanogelBiomacromolecules
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SCAFFOLDS BASED ON HYALURONIC ACID AND POLYAMINOACIDS AS ARTIFICIAL ECM SUBSTITUTES

2009

SCAFFOLDS HYALURONIC ACID POLYAMINOACIDSSettore CHIM/09 - Farmaceutico Tecnologico Applicativo
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EVALUATION OF POLYAMINOACIDIC POLYMERS AS GENE TRANFER AGENTS TO RESPIRATORY EPITHELIAL CELLS AND OF THEIR BIOPHYSICAL PROPERTIES IN THE PRESENCE OF …

2010

Settore CHIM/09 - Farmaceutico Tecnologico ApplicativoPOLYAMINOACIDIC POLYMERS GENE TERAPY CYSTIC FIBROSIS
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HYBRID SYSTEMS FOR TISSUE ENGINEERING

2009

Settore CHIM/09 - Farmaceutico Tecnologico Applicativocomposite scaffolds tissue engineering hyaluronic acid polyaminoacids
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Hydrophilic and hydrophobic copolymers of a polyasparthylhydrazide bearing positive charges as vector for gene therapy

2008

BACKGROUND: The design of polymeric vectors for gene delivery provided with specific properties is one of the most critical aspects for a successful gene therapy. These polymers should be biocompatible as well as able to carry efficiently DNA to target tissues and to transfect it into cells. RESULTS: The formation of complexes of poly[(α,β-asparthylhydrazide)–poly(ethylene glycol)] and poly[(α,β-asparthylhydrazide)–hexadecylamine] copolymers functionalised with glycidyltrimethylammonium chloride (PAHy–PEG-GTA and PAHy–C16-GTA, respectively) with DNA was studied. The effects of the introduction of hydrophilic (PEG) or hydrophobic (C16) moieties on the chains of PAHy–GTA copolymers, such as t…

chemistry.chemical_classificationcationic polyaminoacidMaterials sciencePolymers and PlasticsPAHy-GTA copolymers polyaspartylhydrazidefungiOrganic ChemistrySupramolecular chemistryDNA protectionPolymerGene deliveryPolyelectrolytechemistry.chemical_compoundpolyion complexchemistryPolymer chemistryPEG ratioMaterials ChemistrySide chainEthylene glycolDNA
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The contribution of methyl groups dynamics to the dynamical transition of proteins

2008

protein dynamicneutron scatteringpolyaminoacids
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