Search results for "Polymer science"
showing 10 items of 157 documents
Phase behavior of low-functionality, telechelic star block copolymers.
2010
We apply state-of-the-art, Grand Canonical Monte Carlo simulations to determine the self-organization and phase behavior of solutions of block copolymer stars. The latter consist of f AB-block copolymers with N monomers each, which contain a solvophilic block A and solvophobic block B, and which are tethered on a common center on their A-side. We vary the degree of polymerization N and the relative composition of the block copolymer arms and investigate the interplay between macrophase and microphase separation in the system. Preliminary results of the effect of increasing the number of arms, f of the stars are also presented.
Hydrostatic and structural pressure in compressed paper webs and press felts
1995
Macromol. Chem. Phys. 2/2017
2017
Cover Picture: Macromol. Chem. Phys. 17/2004
2004
Macromol. Chem. Phys. 10/2009
2009
Hans Wolfgang Spiess 60
2002
Macromol. Chem. Phys. 14/2008
2008
Durability of biodegradable polymers for the conservation of cultural heritage
2019
The use of polymers for conservation of cultural heritage is related to the possibility to slow down or stop natural deterioration which, in many cases, corresponds to stopping the entrance of liquid water and to favour spontaneous water vapour removal. Unfortunately, hydrophobicity is generally favoured by surface roughness and thus competitive with transparency. It is therefore important to find an optimal balance hydrophobicity, transparency and durability (especially to photooxidation). However, polymers typically used for applications in this field come from non-renewable resources and are not biodegradable. In this work, the mechanical, structural and optical properties of PLA, PBAT a…
Membranes and More. Membrane-Mimetic Approach to Advanced Materials. ByJ. H. Fendler, Advances in Polymeric Science, Vol. 113, Springer, Berlin 1994,…
1995
A synthetic molecular pentafoil knot
2011
Knots are being discovered with increasing frequency in both biological and synthetic macromolecules and have been fundamental topological targets for chemical synthesis for the past two decades. Here, we report on the synthesis of the most complex non-DNA molecular knot prepared to date: the self-assembly of five bis-aldehyde and five bis-amine building blocks about five metal cations and one chloride anion to form a 160-atom-loop molecular pentafoil knot (five crossing points). The structure and topology of the knot is established by NMR spectroscopy, mass spectrometry and X-ray crystallography, revealing a symmetrical closed-loop double helicate with the chloride anion held at the centre…