Search results for "Pontederiaceae"

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Cytotoxic secondary metabolites from the endophytic fungus Aspergillus versicolor KU258497

2018

Abstract Two new isocoumarin dimers (1 and 2) and one new dihydroquinolone derivative (3) were isolated from Aspergillus versicolor, an endophyte derived from leaves of the Egyptian water hyacinth Eichhornia crassipes (Pontederiaceae), together with ten other known metabolites. Chemical structures of the isolated metabolites were determined based on HRESIMS, extensive 1D and 2D NMR spectroscopy. The relative and absolute configurations of the new natural products were established by ROESY and electronic circular dichroism (ECD) spectroscopy, respectively. The axial chirality of the isocoumarin 7,7′-homodimers (1 and 2) was deduced by TDDFT-ECD calculations. All isolated compounds were asses…

Circular dichroismbiology010405 organic chemistryChemistryStereochemistryPlant Sciencebiology.organism_classificationAntimicrobial01 natural sciencesBiochemistryEndophyte0104 chemical sciencesIsocoumarin010404 medicinal & biomolecular chemistrychemistry.chemical_compoundTermészettudományokAxial chiralityPontederiaceaeAspergillus versicolorKémiai tudományokAgronomy and Crop ScienceTwo-dimensional nuclear magnetic resonance spectroscopyBiotechnology
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