Search results for "Potential"

A theory ofnonverticaltriplet energy transfer in terms of accurate potential energy surfaces: The transfer reaction from π,π* triplet donors to 1,3,5…

2004

Triplet energy transfer (TET) from aromatic donors to 1,3,5,7-cyclooctatetraene (COT) is an extreme case of "nonvertical" behavior, where the transfer rate for low-energy donors is considerably faster than that predicted for a thermally activated (Arrhenius) process. To explain the anomalous TET of COT and other molecules, a new theoretical model based on transition state theory for nonadiabatic processes is proposed here, which makes use of the adiabatic potential energy surfaces (PES) of reactants and products, as computed from high-level quantum mechanical methods, and a nonadiabatic transfer rate constant. It is shown that the rate of transfer depends on a geometrical distortion paramet…

Modeling the insect mushroom bodies: application to a delayed match-to-sample task.

2013

Despite their small brains, insects show advanced capabilities in learning and task solving. Flies, honeybees and ants are becoming a reference point in neuroscience and a main source of inspiration for autonomous robot design issues and control algorithms. In particular, honeybees demonstrate to be able to autonomously abstract complex associations and apply them in tasks involving different sensory modalities within the insect brain. Mushroom Bodies (MBs) are worthy of primary attention for understanding memory and learning functions in insects. In fact, even if their main role regards olfactory conditioning, they are involved in many behavioral achievements and learning capabilities, as …

An offline/real-time artifact rejection strategy to improve the classification of multi-channel evoked potentials

2008

The primary goal of this paper is to improve the classification of multi-channel evoked potentials (EPs) by introducing a temporal domain artifact detection strategy and using this strategy to (a) evaluate how the performance of classifiers is affected by artifacts and (b) show how the performance can be improved by detecting and rejecting artifacts in offline and real-time classification experiments. Using a pattern recognition approach, an artifact is defined in this study as any signal that may lead to inaccurate classifier parameter estimation and inaccurate testing. The temporal domain artifact detection tests include: a within-channel standard deviation (STD) test that can detect sign…

The barotropic model

2003

Towards Estimation of Seasonal Water Dynamics of Winter Wheat from Ground-Based L-Band Radiometry 

2021

The vegetation optical depth (VOD) parameter contains information on plant water content and biomass, and can be estimated alongside soil moisture from currently operating satellite radiometer missions, such as SMOS (ESA) and SMAP (NASA). The estimation of water fluxes, such as plant water uptake (PWU) and transpiration rate (TR), from these Earth system parameters (VOD, soil moisture) requires assessing potential (suction tension) gradients of water and flow resistances in the soil, the vegetation and the atmosphere, yet it remains an elusive challenge especially on global scale. Here, we used a field-scale experiment to test mechanistic models for the estimation of seasonal water fluxes (…

Characterization of transport regimes and the polar dome during Arctic spring and summer using in situ aircraft measurements

2019

The springtime composition of the Arctic lower troposphere is to a large extent controlled by the transport of midlatitude air masses into the Arctic. In contrast, precipitation and natural sources play the most important role during summer. Within the Arctic region sloping isentropes create a barrier to horizontal transport, known as the polar dome. The polar dome varies in space and time and exhibits a strong influence on the transport of air masses from midlatitudes, enhancing transport during winter and inhibiting transport during summer. We analyzed aircraft-based trace gas measurements in the Arctic from two NETCARE airborne field campaigns (July 2014 and April 2015) with the Alfred W…

Bias correction of dynamically downscaled precipitation to compute soil water deficit for explaining year-to-year variation of tree growth over north…

2017

This paper documents the accuracy of a post-correction method applied to precipitation regionalized by the Weather Research and Forecasting (WRF) Regional Climate Model (RCM) for improving simulated rainfall and feeding impact studies. The WRF simulation covers Burgundy (northeastern France) at a 8-km resolution and over a 20-year long period (1989–2008). Previous results show a strong deficiency of the WRF model for simulating precipitation, especially when convective processes are involved. In order to reduce such biases, a Quantile Mapping (QM) method is applied to WRF-simulated precipitation using the mesoscale atmospheric analyses system SAFRAN («Système d'Analyse Fournissant des Rense…

Evidence of small-scale quasi-isentropic mixing in ridges of extratropical baroclinic waves

2019

Abstract. Stratosphere–troposphere exchange within extratropical cyclones provides the potential for anthropogenic and natural surface emissions to rapidly reach the stratosphere as well as for ozone from the stratosphere to penetrate deep into the troposphere, even down into the boundary layer. The efficiency of this process directly influences the surface climate, the chemistry in the stratosphere, the chemical composition of the extratropical transition layer, and surface pollution levels. Here, we present evidence for a mixing process within extratropical cyclones which has gained only a small amount of attention so far and which fosters the transport of tropospheric air masses into the…

Reappraising the appropriate calculation of a common meteorological quantity: Potential Temperature

2020

Abstract. The potential temperature is a widely used quantity in atmospheric science since it is conserved for dry air's adiabatic changes of state. Its definition involves the specific heat capacity of dry air, which is traditionally assumed as constant. However, the literature provides different values of this allegedly constant parameter, which are reviewed and discussed in this study. Furthermore, we derive the potential temperature for a temperature-dependent parameterisation of the specific heat capacity of dry air, thus providing a new reference potential temperature with a more rigorous basis. This new reference shows different values and vertical gradients, in particular in the str…

Global Climatologies of Eulerian and Lagrangian Flow Features based on ERA-Interim

2017

Abstract This paper introduces a newly compiled set of feature-based climatologies identified from ERA-Interim (1979–2014). Two categories of flow features are considered: (i) Eulerian climatologies of jet streams, tropopause folds, surface fronts, cyclones and anticyclones, blocks, and potential vorticity streamers and cutoffs and (ii) Lagrangian climatologies, based on a large ensemble of air parcel trajectories, of stratosphere–troposphere exchange, warm conveyor belts, and tropical moisture exports. Monthly means of these feature climatologies are openly available at the ETH Zürich web page (http://eraiclim.ethz.ch) and are annually updated. Datasets at higher resolution can be obtained…