Search results for "Precipitation"
showing 10 items of 826 documents
Millennial-scale climate variability during the last 12.5 ka recorded in a Caribbean speleothem
2013
Abstract We present a speleothem stable oxygen isotope record for the last 12.5 ka based on two stalagmites from western Cuba. The δ18O signal is interpreted to represent past precipitation variability. Both stalagmites show a pronounced transition from higher δ18O values (indicating drier conditions) to more negative δ18O values (suggesting wetter conditions) between 10 and 6 ka. This transition is also visible in a planktonic δ18O record off Haiti. On orbital timescales, the δ18O value of Caribbean precipitation, thus, strongly resembles the oxygen isotope composition of Caribbean surface water. On millenial timescales, the speleothem δ18O record shows a high correlation to a North Atlant…
Natural isotopes support groundwater origin as a driver of mire type and biodiversity in Slitere National Park, Latvia
2020
Slitere National Park in Latvia is home to rich fens with many endangered and threatened plant species. This study aims to address how the hydrological systems affect vegetation biodiversity (cf. Wolejko et al. 2019) in the mire systems of the National Park: the base-rich inter-dune mires and extremely base-rich calcareous fens. Groundwater samples from these areas were collected for measurements of ion composition and natural isotopes of C, H and O. Also, we simulated groundwater flow paths from the highest local topographical point (a nearby sandy plateau) to the sea, and calculated the residence times of these groundwater flows. The results show that the inter-dune mires are supplied by …
Precipitation of potassium as hazenite from washing water of spent alkaline batteries
2022
Hazenite (KNaMg2(PO4)2 × 14 H2O), a new type of struvite mineral, was precipitated from the potassium-rich washing water of spent alkaline battery black mass. Hazenite can be used as a fertilizer, which would be an additional benefit derived from the sustainable recovery of battery materials. Precipitation experiments were performed using different pH values (9.5–12), Mg:K:PO4 ratios ((1.0–1.5):1:(1.0–1.5)) and temperatures (10–40 °C). Based on the results, hazenite precipitated in a wide pH range under alkaline conditions. The precipitation kinetics were fast, and the purity of the hazenite was high. Overall, hazenite can be precipitated at room temperature without the addition of excess c…
Lignin recovery from spent alkaline pulping liquors using acidification, membrane separation, and related processing steps: A Review
2019
The separation of lignin from the black liquor generated during alkaline pulping is reviewed in this article with an emphasis on chemistry. Based on published accounts, the precipitation of lignin from spent pulping liquor by addition of acids can be understood based on dissociation equilibria of weak acid groups, which affects the solubility behavior of lignin-related chemical species. Solubility issues also govern lignin separation technologies based on ultrafiltration membranes; reduction in membrane permeability is often affected by conditions leading to decreased solubility of lignin decomposition products and the presence of colloidal matter. Advances in understanding of such phenomen…
Gravimetric determination of palladium with biguanide sulfate
1986
Abstract Biguanides are interesting reagents for the determination of palladium owing to their solubility, chemical resistance, and selectivity in moderately acidic solutions. A procedure for the gravimetric determination of palladium(II) in the form of Pd(HL)2SO4, where HL = biguanide, is proposed and the conditions of precipitation, treatment of the precipitate, precision, accuracy, and selectivity of the procedure are discussed.
The effect of gold addition on the catalytic performance of copper manganese oxide catalysts for the total oxidation of propane
2011
Mixed copper manganese oxide catalysts (Hopcalite) have been studied for the total oxidation of propane, as a model for hydrocarbon volatile organic compound emission control. Catalysts were prepared using coprecipitation with and without gold. Calcination temperature influenced the catalyst activity and those prepared at 300 °C were the most active. Characterization showed that the catalysts had a nanowire-type morphology, and for those containing gold it was present as metallic particles occluded within the nanowires. The incorporation of gold into the catalyst enhanced the activity for propane conversion, but the presence of gold did not noticeably enhance the light-off activity. Althou…
Hexagonal nanosheets from the exfoliation of Ni2+-Fe3+ LDHs: a route towards layered multifunctional materials
2010
Here we report the synthesis of a crystalline micrometric-sized hexagonal-shaped Ni2+-Fe3+ LDH by following a modified homogeneous precipitation method. The exfoliation of the material in formamide leads to stable suspensions of hexagonal nanometric sheets, which have been extensively characterized. Our data confirm that the intrinsic properties of the bulk material are retained by these segregated nanosheets, thus opening the door for their use in the development of layered multifunctional materials.
X-ray Photoelectron-spectroscopy Investigation of Pumice-supported Nickel-catalysts
1995
Pumice-supported nickel catalysts, prepared by the method of slow homogeneous precipitation with urea, were analysed by x-ray photoelectron spectroscopy (XPS). By comparison with similarly prepared silica- and alumina-supported nickel catalysts, a preferential interaction of Ni2+ with Al3+ of the support has been determined. A quantitative XPS analysis indicated large segregation of nickel to the surface. The treatment with H2 at 673 K and 1073 K produced a partial reduction of Ni+2 to Ni0. The extent of the reduction was largest at 1073 K and in this case the reduced Ni in the metallic phase was detectable by x-ray diffraction. A decrease of the Ni 2p/Si 2p intensity ratio occurring in the…
The Use of Ca- and Mg-Rich Fly Ash as a Chemical Precipitant in the Simultaneous Removal of Nitrogen and Phosphorus - Recycling and Reuse
2019
The European Union’s circular economy strategy aims to increase the recycling and re-use of products and waste materials. According to the strategy, the use of industry waste material should be more effective. A chemical precipitation method to simultaneously remove phosphorus and nitrogen from synthetic (NH4)2HPO4 solution and the liquid phase of anaerobic digestate using fly ash as a precipitant was tested. Fly ash is a waste material formed in the power plant process. It mainly contains calcium oxide (CaO) and magnesium oxide (MgO). Saturated precipitant solution was prepared from fly ash, which was added in small proportions to (NH4)2HPO4 solution during the experiment. Fly ash’s effect…
Effect of weather conditions on somatic cell score in Sicilian Valle del Belice ewes
2010
Mastitis susceptibility of Valle del Belice ewes from the south of Sicily to temperature, humidity, precipitation, solar radiation, sun hours, air pressure, wind-speed and wind-direction measured by a public weather station was investigated using 65,848 test-day somatic cell score (SCS) records of 5,237 ewes. All weather parameters had an effect on SCS in a regression approach. Extreme values of maximum and minimum temperaturehumidity indices resulted in increased SCS. Higher precipitation, solar radiation and sun hours resulted in increased SCS, whereas higher air pressure and wind speed resulted in reduced SCS.