Search results for "Principi"
showing 10 items of 580 documents
Graphite-supported TiO2 for 4-nitrophenol degradation in a photoelectrocatalytic reactor
2009
WOS: 000274769500044
Nanostructured anatase TiO2 densified at high pressure as advanced visible light photocatalysts
2015
This study reports on characterization and photoactivity of nanostructured TiO2 samples, which have been permanently densified under high pressures, up to 2.1 GPa. Commercial Mirkat 211 anatase has been used as a benchmark sample, in order to investigate the effect of unidirectional high pressure on structural, optical and photocatalytic properties of TiO2. Vibrational Raman spectroscopy shows that the treatment does not cause transitions among the different crystalline phases of titanium dioxide. UV-vis diffuse reflectance spectra reveal that increasing pressure gives rise to a shift of the absorption onset towards higher wavelength enhancing the photoactivity under visible radiation. Samp…
N-Doped Anatase/Rutile Photocatalysts for the Synthesis of Aromatic Aldehydes Under Ultraviolet and Solar Irradiation
2015
N-doped anatase/rutile photocatalysts were prepared by a sol-gel method, using TiCl4 as TiO2 precursor and urea as N-dopant source. The catalysts required a thermal treatment at temperature higher than 300 degrees C to achieve actual nitrogen doping; this treatment also allowed obtaining crystalline and hydrophobic samples. Moreover, nitrogen doping modified the surface of samples by increasing the anatase to rutile phase ratio and hydrophilicity. The catalysts were characterized by BET specific surface area, XRD, ESEM, TGA, FT-IR, DRS and XPS measurements, with particular attention to the assessment of the N-doping effect. It was found that XPS analysis should be used together with DRS and…
Partial photocatalytic oxidation of glycerol in TiO2 water suspensions
2010
2nd European Conference on Environmental Applications of Advanced Oxidation Processes -- SEP 09-11, 2009 -- Nicosia, CYPRUS
Photodegradation of pharmaceutical drugs in aqueous TiO2 suspensions: mechanism and kinetics
2007
WOS: 000251165800003
Selectivity of hydroxyl radical in the partial oxidation of aromatic compounds in heterogeneous photocatalysis
2007
Abstract The photocatalytic oxidation of different benzene derivatives has been investigated in order to understand how the substituent group affects the selectivity to hydroxylated compounds. Experimental runs were performed by using TiO2 (Merck) aqueous suspensions at natural pH irradiated by near-UV light. The organic molecules used as substrate contained an electron withdrawing group (EWG) (nitrobenzene, cyanobenzene, benzoic acid, 1-phenylethanone), an electron donor one (EDG) (phenol, phenylamine, N-phenylacetamide) or both an EWG and an EDG (4-chlorophenol). The results clearly indicated that the primary photocatalytic oxidation of aromatic compounds containing an EDG gives rise main…
Autocatalytic Photo-Oxidation of 2-Methoxybenzyl Alcohol and O2 Quenching therein
2014
Process for the production of bromine
2016
A process for the preparation of molecular bromine, by means of advanced oxidation processes or their combination is disclosed
Economical aspects, toxicity, and environmental fate of cerium oxide
2020
Abstract The present chapter reports some economical aspects of the cerium oxide market. Porter’s and PESTEL analyses have been used to evidence the strengths and weaknesses of the ceria market, along with the potentiality and opportunities within the years to come. The wide use of CeO2 nanoparticles in many applications requires to consider also issues related to their toxicity and environmental fate. In this regard, some contradictory reports in the relevant literature have been surveyed, thus highlighting the need for further and detailed investigation on these topics in order to propose effective strategies of risk assessment and environmental remediation.
Advances in selective conversions by heterogeneous photocatalysis
2010
Selective photocatalytic conversions are offering an alternative green route for replacing environmentally hazardous processes with safe and energy efficient routes. This paper reports the most recent advances in the application of heterogeneous photocatalysis to synthesize valuable compounds by selective oxidation and reduction.