Search results for "Process"
showing 10 items of 22310 documents
Biogeography and diversity of South Atlantic Cretaceous echinoids: implications for circulation patterns
2000
Abstract This survey of echinoid species living on the African and South American margins of the South Atlantic Ocean in Cretaceous times is based on a review of published species and abundant unpublished material. The synthetic approach is used to ascertain how the South Atlantic was colonised by echinoids from the time it first opened in the Early Cretaceous until communications were established with the North Atlantic and Mediterranean–Tethys in the Late Cretaceous. The survey focuses on the biogeographical origin of immigrant species and their relations with Indo-Madagascan, North Atlantic and Mediterranean–Tethyan faunas. Qualitative variations in species diversity are also studied whe…
Palaeoceanographic significance of the Tethyan ‘Livello Selli’ (Early Aptian) from the Hybla Formation, northwestern Sicily: biostratigraphy and high…
2002
High-resolution micropalaeontological and chemostratigraphic records for the Hauterivian–Aptian succession outcropping at Calabianca (NW Sicily) provide new insight into the palaeoclimatic and palaeoceanographic evolution of the Tethys Ocean. Calcareous nannofossil and planktonic foraminiferal biostratigraphy together with δ13C chemostratigraphy allowed the identification of a hiatus in the Barremian and a major one including most of the Upper Aptian, the entire Lower Albian and part of the Middle Albian. The Livello Selli equivalent was identified on the basis of lithology and well constrained by calcareous plankton biostratigraphy as well as by the δ13C curve. The multi-proxy record from …
Photocatalytic ozonation for a sustainable aquaculture: A long-term test in a seawater aquarium
2019
Abstract A long-term test at a laboratory scale with a closed system (a coral reef aquarium) has been carried out to study the potentialities of photocatalytic ozonation and photocatalysis for the removal of noxious organic compounds in recirculating systems (aquaria and recirculating aquaculture systems) working with a minimum make up of new water. Attention has been focused not only on the depuration capabilities but also on possible negative phenomena, some of which could become apparent only at long times. After having tuned the system by setting appropriate operating conditions and procedures, positive results were obtained. In particular, it was observed that the alternation of photoc…
Gas-liquid chromatographic analyses
1983
Abstract The gas chromatography of mixtures of n -alkyl acetates (CH 3 COOR, R = C 1 —C 8 ) and methyl esters of aliphatic n -carboxylic acids (R′COOCH 3 , R′ = C 1 —C 8 ) and certain of their monochlorinated derivatives has been studied on Carbowax 20M and SE-30 glass capillary columns under the same operating conditions. The separation of the isomeric monochlorinated esters was complete on Carbowax 20M, whereas on SE-30 the peaks of 6- and 7-chlorooctyl acetates and methyl (ω − 1)- and (ω − 2)-chlorooctanoates and -nonanoates partly overlapped. The complete separation of the mixtures could not be achieved, however, on Carbowax 20M, in spite of the use of various operating conditions. The …
Photocatalytic oxidation of phenol on TiO2 powders. A Fourier transform infrared study
1994
Abstract In the present paper a detailed investigation of a well known photoreaction, i.e. phenol photodegradation in the presence of TiO2, has been carried out. The Fourier transform infrared (FT-IR) technique has been used to characterize the catalyst surface and to follow the photoprocess by “in situ” measurements in a gas—solid regime, simulating the aqueous liquid—solid regime in which this photodegradation reaction has been usually carried out. The influence on the photoprocess of the surface hydroxylation of the catalyst has been investigated and the presence of some reaction intermediates has been revealed by FT-IR. The experimental results have demonstrated that the chosen gas—soli…
Molecular simulation studies of water physisorption in zeolites
2006
We report a series of Grand Canonical Monte Carlo simulations of water adsorption in NaY and NaX faujasite, as well as in silicalite-1. Computed adsorption isotherms and heats of adsorption were in good agreement with the available experiments. The existence of cyclic water hexamers in NaX located in the 12-ring windows, recently disclosed by neutron diffraction experiments (Hunger et al., J. Phys. Chem. B, 2006, 110, 342-353) was reproduced in our simulations. Interestingly enough, such cyclic hexamer clusters were also observed in the case of NaY, in which no stabilizing cation is present in the 12-ring window. We also report cation redistribution upon water adsorption for sodium faujasit…
Spectral studies of zinc octacarboxyphthalocyanine aggregation
2009
The association of zinc octacarboxyphthalocyanine, was studied using UV–vis absorption and fluorescence emission spectroscopy; the effects of dye concentration, pH and solvents on spectra were discussed. Calculations showed that the dye dimerized in aqueous solutions ranging from 5.0 × 10−7 to 5.0 × 10−5 mol/dm3, at 25 °C. The dimerization constant of 106 dm3/mol and the spectral Q band shift of 1185 cm−1 imparted by dimerization indicated strong π–π interactions between phthalocyanine molecules. Red S1 fluorescence of the dye monomer was observed in various solutions which was quenched owing to molecular association and other factors. The strong influence of pH on both aggregation and fluo…
Origin of peak asymmetry and the effect of temperature on solute retention in enantiomer separations on imprinted chiral stationary phases
1995
Abstract In enantiomer separations of d - and l -phenylalanine anlilide ( d,l -PA) on l -PA-imprinted chiral stationary phases (CSPs), the use of an aqueous buffer-organic solvent mixture as mobile phase resulted in improved column efficiency compared with what has previously been observed using mobile phases containing acetic acid as modifier. The dependence of the chromatographic parameters on flow-rate and sample load was studied. A strong dependence of the asymmetry factor ( A s ) of the l -form on sample load and a weak dependence on flow-rate indicate that the non-linear adsorption isotherm is the main reason for the broad peaks observed in this system. Depending on the method used fo…
Photocatalytic degradation of dyes by using a membrane reactor
2004
Abstract Dyes are organic compounds used in textile, food and drug industries, and their abatement represents one of the main problems in the treatment processes because generally they are very stable toxic compounds. In this work, two commercial azo-dyes, i.e. Congo Red (C32H22N6Na2O6S2) and Patent Blue (C27H31N2NaO6S2), in aqueous solution were degraded in a photocatalytic membrane reactor by using TiO2 Degussa P25 as the catalyst. Different system configurations and irradiating sources were studied, and the influence of some operational parameters such as the pressure in the membrane cell and the initial concentration of the substrates was determined. A comparison between suspended and e…
On the Existence of Different Zeolite-Associated Topological Redox Isomers. Electrochemistry of the Y Zeolite-Associated Mn(Salen)N3 Complex
2002
The electrochemical properties of Y zeolite-associated MnIII(salen)N3 (salen = trans-(R,R)-1,2-bis(salicyldeneamino)cyclohexane) has been investigated using polymer film electrodes immersed into neutral aqueous solutions. Zeolite Y-associated Mn(III)−salen complexes are reduced in one-electron reversible process at −0.25 V versus SCE. The electrochemical response is discussed in terms of the existence of two topological redox isomers: a weakly boundary-associated Mn(salen) complex, whose electrochemical response corresponds to a reversible one-electron transfer controlled by diffusion of the positive ions of the supporting electrolyte through the zeolite surface windows and channels, and a…