Search results for "Proton"
showing 10 items of 5886 documents
Combined effect of solvent content, temperature and pH on the chromatographic behaviour of ionisable compounds.
2008
The organic solvent content and the pH in the mobile phase are the usual main factors in reversed-phase liquid chromatographic separations, owing to their strong effects on retention and/or selectivity. Temperature is often neglected. However, even in cases where the impact of this factor on selectivity is minor, the reduction in analysis time is still an interesting reason to consider it. In addition, ionisable compounds may exhibit selectivity changes, owing to the interaction of organic solvent and/or temperature with pH. The separation of ionisable compounds (nine diuretics: bendroflumethiazide, benzthiazide, bumetanide, chlorthalidone, furosemide, piretanide, probenecid, trichloromethi…
Proton Dynamics in In:BaZrO3: Insights on the Atomic and Electronic Structure from X-ray Absorption Spectroscopy
2009
The local structure of Ba2+, Zr4+, and In3+ in In:BaZrO3 is investigated with EXAFS for samples having 0 to 75% In3+ content. It is found that indium can be inserted in any ratio in the host matrix oxide and that the oxygen coordination shell displays an In-O distance very similar to the Zr-O length. In the Zr-rich compositions, there is a preferred dopant-vacancy association that, however, does not give rise to dopant-proton interaction in the hydrated samples. The tendency of Ba2+ to be attracted toward the dopant site is attributed to the electrostatic interaction with the dopant and to the structural rearrangement around the In3+ site. Third cumulant analysis at high temperatures (up to…
CONTRIBUTION OF PSEUDO-FOCUSED SOFT PROTONS TO THE BACKGROUND OF ATHENA
2021
This PhD thesis explores the role of low energy protons, the so-called ‘soft protons', as a component of the background in view of the future ESA's X-ray mission Athena. As a matter of fact, a high level of soft proton flux at the focal plane of Athena can adversely affect the scientific goals of the mission. To prevent this, a correct estimate of the soft proton flux expected at the focal plane of the satellite is fundamental. Such an estimate can be achieved only if the reflectivity of soft protons from the optics is well understood, with efforts on both the experimental and the theoretical sides. To this aim, I applied the model of reflectivity of particles at grazing incidence proposed …
X-ray Spectroscopy of (Ba,Sr,La)(Fe,Zn,Y)O3-δIdentifies Structural and Electronic Features Favoring Proton Uptake
2020
Mixed protonic–electronic conducting oxides are key functional materials for protonic ceramic fuel cells. Here, (Ba,Sr,La)(Fe,Zn,Y)O3−δ perovskites are comprehensively investigated by X-ray spectroscopy (in oxidized and reduced states). Extended X-ray absorption fine structure shows that Zn,Y doping strongly increases the tendency for Fe–O–Fe buckling. X-ray absorption near-edge spectroscopy at the Fe K-edge and X-ray Raman scattering at the O K edge demonstrate that both iron and oxygen states are involved when the samples are oxidized, and for the Zn,Y doped materials, the hole transfer from iron to oxygen is less pronounced. This can be correlated with the observation that these material…
Preparation and XAFS studies of organotin(IV) complexes with adenosine and related compounds and calf thymus DNA
2007
Complexes of adenosine and related compounds (adenosine-5’-monophosphate, adenosine-5’-triphosphate and pyridoxal-5-phosphate) with Bu2SnO and/or BuSnCl2 were prepared in the solid state. The compositions of the complexes were determined by standard analytical methods. It was found that the complexes contain the organotin(IV) moiety and the ligand in a ratio of 1:1. The FT-IR spectra demonstrated that Bu2SnO reacts with the D-ribose moiety of the ligands, while Bu2SnCl2 is coordinated to the deprotonated phosphate group. The basic part of the ligands does not participate directly in complex formation. Comparison of the experimental Mossbauer Δ (quadrupole splitting) values with those calcul…
Physicochemical Investigation of the Solubilization of Ytterbium Nitrate in AOT Reverse Micelles and Liquid Crystals
2006
A wide investigation of the solubilization of the water-soluble salt Yb(NO3)(3) in sodium bis(2-ethylhexyl)sulfosuccinate (AOT) reverse micelles and AOT liquid crystals has been carried out. After saturation of water/AOT/organic solvent w/o microemulsions with pure Yb(NO3)(3), the Yb(NO3)(3)/AOT composites were prepared by complete evaporation under vacuum of the volatile components (water and organic solvent) of the salt-containing microemulsions. It was observed that these composites can be totally dissolved in pure n-heptane or CCl4, allowing the solubilization of a noticeable amount of Yb(NO3)(3) in quite dry apolar media. By UV-vis-NIR, FT-IR, and H-1 NMR spectroscopies, some informati…
"Table 2" of "Measurement of ZZ production in pp collisions at sqrt(s)=7 TeV and limits on anomalous ZZZ and ZZgamma couplings with the ATLAS detecto…
2014
The measured total cross sections. The first systematic uncertainty is the combined systematic uncertainty excluding luminosity, the second is the luminosity.
"Table 1" of "Measurement of ZZ production in pp collisions at sqrt(s)=7 TeV and limits on anomalous ZZZ and ZZgamma couplings with the ATLAS detecto…
2014
The measured fiducial cross sections. The first systematic uncertainty is the combined systematic uncertainty excluding luminosity, the second is the luminosity.
"Table 16" of "Measurement of the production cross section for Z/gamma* in association with jets in pp collisions at sqrt(s) = 7 TeV with the ATLAS d…
2014
Measured normalized leading jet differential cross section 1/sigma_DY dsigma/dpt for the electron channel and the muon channel in the individual lepton fiducial regions and uncorrected for QED effects.
"Table 15" of "Measurement of the production cross section for Z/gamma* in association with jets in pp collisions at sqrt(s) = 7 TeV with the ATLAS d…
2014
Measured normalized inclusive jet differential cross section 1/sigma_DY dsigma/dpt for the electron channel and the muon channel in the individual lepton fiducial regions and uncorrected for QED effects.