Search results for "Pseudomorph"
showing 6 items of 6 documents
Electronic microdiffraction study of structural modifications resulting from the dehydration of gypsum. Prediction of the microstructure of resulting…
2001
Abstract Endothermic decomposition reactions (solid 1→solid 2+gas) generally affect only part of the inter-atomic bonds of the solid 1 structure. In consequence, the morphology and external dimensions of particles remain unchanged (the particles of solid 2 are referred to as pseudomorphs of those of solid 1). The gas release normally leads to a decrease of the molar volume of the precursor solid, resulting in cracking and formation of intra-particle porosity. This work deals with such a reaction: the dehydration of gypsum into sub-hydrated and anhydrous phases. Ultrathin (010) gypsum cleaved plates have been dehydrated under controlled conditions and studied by electron microdiffraction. Al…
On the interpretation of retrograde reaction textures in granulite facies rocks
2010
Retrograde reaction textures, such as partial pseudomorphs, coronae and symplectic coronae are a relatively common feature of granulite facies rocks and represent evidence of change of mineral modes or assemblages. Thus, such reaction textures represent one of the more potentially useful indicators of retrograde P-T evolutions. However, the interpretation of such textures requires the simultaneous consideration of the formation of the texture itself in terms of the spatial relationships in a rock, and of the changes in P-T conditions that drove the development of the reaction texture. Calculated phase diagrams provide a robust framework in which to consider reaction textures, especially via…
Valanginian isotope variation in glendonites and belemnites from Arctic Svalbard: Transient glacial temperatures during the Cretaceous greenhouse
2010
Oxygen and carbon isotope data from Cretaceous (Valanginian) glendonites and belemnites from Arctic Svalbard are presented. Oxygen isotope data from well-preserved glendonites, in conjunction with the ikaite to glendonite pseudomorph transition temperature, are used to provide an estimate of the oxygen isotope composition of ambient seawater. Calculation of such a factor is essential for robust paleotemperature estimates. Using this methodology, our paleotemperatures calculated from the oxygen isotope compositions of coexisting belemnites yield cool temperatures (4–7 °C) consistent with transient glacial polar conditions during the Cretaceous greenhouse. Cool polar temperatures during the C…
Contamination of mafic magma by partial melting of dolomitic xenoliths
2001
Mg-skarns enclosed in dunite cumulates of the Neo-Proterozoic Ioko-Dovyren intrusion (northern Baikal region, Russia) can be traced to silica-poor dolomitic host rock layers. The dominant minerals of the skarns are brucite (pseudomorph after periclase), forsterite and Cr-poor spinel. Rapid heating of quartzpoor dolomitic xenoliths led to the formation of minor olivine, followed by the breakdown of dolomite to calcite and periclase. Xenoliths were partially melted upon further heating resulting in a calcite melt. This low-density melt was quantitatively squeezed out, mixed with the surrounding mafic magma and left behind periclase and olivine. This caused the crystallization of new olivine w…
The analcime problem and its impact on the geochemistry of ultrapotassic rocks from Serbia
2004
AbstractTertiary ultrapotassic volcanic rocks from Serbia occasionally display low levels of K2O and K2O/ Na2O. In these rocks, analcime regularly appears as pseudomorphs after pre-existing leucite microphenocrysts. The process ofleucite transformation in Serbian ultrapotassic rocks is very thorough: fresh leucite survives only in ugandites from the Koritnik lava flows as well as in rare inclusions in Cpx. This paper focuses on the impact of ‘analcimization’ on the mineralogy and geochemistry ofthe Serbian ultrapotassic rocks, using the samples where leucite survived as a monitor for the process.Analcimization has had a great impact on the geochemistry of the rocks, but affects only a restr…
Microstructural modifications resulting from the dehydration of gypsum
2001
Various faces of dehydrated gypsum-cleaved blocks and single crystals have been investigated using optical microscopy, SEM, and TEM. The orientation of the cracks with respect to the initial gypsum structure and the Miller indices of all possible crack planes have been determined. These crack planes have been found to be few and to correspond to planes of high atomic density in the initial and final structures, therefore characterised by a low surface tension. These observations allow us to propose cracking criteria based on general concepts of crystal growth. The cracks' dimensions measured on different faces of the pseudomorph are distributed over several orders of magnitude and seems to …