Search results for "Pyrolytic carbon"
showing 5 items of 15 documents
Superconducting properties of polycrystalline YBCO prepared by a pyrolytic process
1994
Polycrystalline YBCO was prepared by a pyrolytic process starting from citrate and tartrate precursors. The effect of the precursor on the superconducting properties was investigated by means of magnetic measurements using a SQUID magnetometer, a Vibrating-Sample Magnetometer and an a.c. susceptometer. The critical temperature is not affected by the type of precursor (Tc=85 K for both). On the other hand, the precursor plays an important role on the critical current density, which is found to be an order of magnitude higher in the sample obtained from citrates (Jc(77K, H=0)=2.3·104 A/cm2 and 103 A/cm2 for the from-citrate and from-tartrate sample, respectively).
Size dependence of the Josephson critical behavior in pyrolytic graphite TEM lamellae
2014
We have studied the transport characteristics of TEM lamellae of different widths obtained from a graphite sample with electrical contacts at the edges of the embedded interfaces. The temperature dependence of the resistance, as well as the current-voltage characteristics, are compatible with the existence of Josephson-coupled superconducting regions. The transition temperature at which the Josephson behavior sets in decreases with a decreasing interface width and vanishes for widths below 200 nm. This interface-size dependence provides an explanation for differences observed in the transport behavior of graphite-based samples with interfaces, and it appears to be related to the influence o…
Characterization of commercial synthetic resins by pyrolysis-gas chromatography/mass spectrometry: application to modern art and conservation.
2009
To characterize a set of synthetic resins, a methodology by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) has been developed. The studied reference materials were commercial versions of a wide range of synthetic resins. For each polymer, the pyrolytic and chromatographic conditions were optimized to adequately resolve the fragment mixture in a short time. The proposed analytical method does not require previous treatment of the sample, and due to its high sensitivity, only a small sample quantity in the microgram range can be used. The pyrolysis temperature was found to have little effect on the obtained pyrograms. The summarized data set for the individual polymer materials, es…
Mass spectrometric investigation of polymers: Thermal degradation of truxillic and truxinic polyamides
1975
The thermal degradation mechanism of four isomeric truxillic and truxinic polyamides were investigated by direct pyrolysis in the ion source of a mass spectrometer. Thermal degradation reactions were followed directly by this method by detecting the thermal and electron impact-induced fragments. The results obtained have shown that the thermal degradation products are sensibly different for the head-to-head (hh) and head-to-tail (ht) polymers and that the predominant pyrolytic process is the cyclobutane ring cleavage. In the hh isomers, both symmetrical and asymmetrical cyclobutane ring cleavage was detected, while in the ht isomers only symmetrical cleavage occurs; this explains the notice…
Pyrolytic formation of polycyclic aromatic hydrocarbons from sesquiterpenes
2012
Author's version of an article in the journal: Food Chemistry. Also available from the publisher at: http://dx.doi.org/10.1016/j.foodchem.2012.06.033 The products of the pyrolysis of four sesquiterpenes, β-caryophyllene, α-cedrene, longifolene and valencene, have been examined. Pyrolysis was carried out at 300, 400 and 500 °C, the products determined by GC–MS and then examined for similarities and differences using multivariate data analysis. Analysis showed that longifolene was most resistant and caryophyllene least resistant to pyrolysis with cedrene and valencene occupying intermediate positions. While the compounds were largely unchanged at 300 °C, polycyclic aromatic hydrocarbons (PAHs…