Search results for "Q-BRANCH"
showing 6 items of 16 documents
Study of the Density and Temperature Dependences of the Vibrational Raman Transition in Compressed Liquid N2
1991
0021-9606; Accurate values of linewidth and line shift in the isotropic vibrational Raman spectrum of compressed liquid N2 have been obtained by using inverse Raman spectroscopy. Experiments have been performed for eight isotherms, from the normal boiling point to the critical point temperatures of N2, the number density varying between the value on the coexistence line, and the maximum value of 2.1 x 10^22 cm-3. Minima of the linewidth have been observed above 86 K, showing the increasing influence of vibration-rotation coupling (motional narrowing) competing with the broadening due to pure vibrational dephasing. Moreover, for the first time, maxima of the red line shifts have been found, …
High-Resolution Nonlinear Raman-Spectroscopy in Gases
1990
0377-0486; The resolution in the Raman spectra of gases has been greatly improved by the development of the different methods of non-linear Raman scattering. When two laser beams, one of which has a tunable frequency, are focused in a sample, a stimulated Raman process occurs as soon as the frequency difference between the two lasers is equal to a Raman-active rovibrational or rotational transition frequency. The Raman resonance can be detected in different ways: by coherent anti-Stokes Raman scattering (CARS) or the corresponding Stokes process (CSRS), by a gain in one of the beams (stimulated Raman gain spectroscopy, SRGS) or a loss in the other (inverse Raman spectroscopy, IRS), or even …
Pressure broadening, shift, and interference effect for a multiplet line in the rovibrational anisotropic stimulated raman spectrum of molecular oxyg…
1996
0022-2852; High-resolution stimulated inverse Raman spectroscopy has been applied to the study of collisional broadening, shifting, and line mixing for the O-o(J, N = 5) triplet line of the fundamental vibrational band of molecular oxygen. Accurate line broadening coefficients for the individual J components within the triplet have been measured for the first time and show a significant J dependence. The line broadening coefficients are larger than those previously obtained for unresolved pure rotational Raman lines. The additional broadening is expected to result from electronic spin relaxation. The pressure-induced line shift has been obtained for this Line and compared to the value obtai…
Collisional shifting and broadening coefficients for the rovibrational anisotropic S(J) lines of nitrogen studied by inverse Raman spectroscopy
1996
0377-0486; Line shifting and broadening coefficients of the anisotropic S(J) lines (v = 0, J --> v = 1, J + 2) of the nitrogen molecule were measured at room temperature using high-resolution stimulated Raman spectroscopy. A rotational quantum number dependence of the S(J) line shifts was observed. In order to avoid an asymmetry of experimental origin, a suitable theoretical profile was fitted to the experimental lineshapes. This study allows the testing of the theoretical methods for calculating the line broadening coefficients in anisotropic Raman scattering, which have already been used in the analysis of infrared absorption data. The behaviour of the modified sum rule and the RPA (rando…
Rotational Relaxation of Nitrogen in Ternary Mixtures N2-CO2-H2O - Consequences in Coherent Anti-Stokes-Raman Spectroscopy Thermometry
1991
0021-9606; The influence of CO2 and H2O on the rotational relaxation processes of N2 in ternary mixtures N2-CO2-H2O is investigated. The efficiency of these perturbers is responsible for significant modifications of the state-to-state relaxation rates and broadening coefficients. Flame data are well reproduced by taking into account these modifications. The role of these minor species in the determination of temperatures in premixed flames is analyzed. The present relaxation model allows us to understand why the discrepancy between observed and calculated coherent anti-Stokes Raman spectroscopy (CARS) spectra in flames is sometimes resolved by empirically adding a dephasing component to pur…
Determination of Temperature by Stimulated Raman Scattering of Molecular Nitrogen, Oxygen, and Carbon-Dioxide
1993
0721-7269; We have determined the temperature from SRS spectra of N2-N2, N2-CO2, O2-O2, and CO2-CO2 recorded in wide pressure and temperature ranges. The fitting procedure takes simultaneously into account the Dicke effect and motional narrowing. We have quantified the accuracy of the MEG and ECS-P models for rotational relaxation. The temperature extracted from each model is compared with thermocouple measurements. The influence of vibrational broadening and shifting is discussed in detail.