Search results for "QE"
showing 10 items of 457 documents
Global aerosol modeling with MADE3 (v3.0) in EMAC (based on v2.53): model description and evaluation
2019
Recently, the aerosol microphysics submodel MADE3 (Modal Aerosol Dynamics model for Europe, adapted for global applications, third generation) was introduced as a successor to MADE and MADE-in. It includes nine aerosol species and nine lognormal modes to represent aerosol particles of three different mixing states throughout the aerosol size spectrum. Here, we describe the implementation of the most recent version of MADE3 into the ECHAM/MESSy Atmospheric Chemistry (EMAC) general circulation model, including a detailed evaluation of a 10-year aerosol simulation with MADE3 as part of EMAC.We compare simulation output to station network measurements of near-surface aerosol component mass conc…
Lignin oxidation products in soil, dripwater and speleothems from four different sites in New Zealand
2020
Lignin oxidation products (LOPs) are widely used as vegetation proxies in climate archives, such as sediment and peat cores. The total LOP concentration, Σ8, provides information on the abundance of vegetation, while the ratios C/V and S/V of the different LOP groups also provide information on the type of vegetation. Recently, LOP analysis has been successfully applied to speleothem archives. However, there are many open questions concerning the transport and microbial degradation of LOPs on their way from the soil into the cave system. These processes could potentially alter the original source-dependent LOP signals, in particular the C/V and S/V ratios, and thus complicate their interpre…
Quantification of lignin oxidation products as vegetation biomarkers in speleothems and cave drip water
2018
Here we present a sensitive method to analyze lignin oxidation products (LOPs) in speleothems and cave drip water to provide a new tool for paleo-vegetation reconstruction. Speleothems are valuable climate archives. However, compared to other terrestrial climate archives, such as lake sediments, speleothems contain very little organic matter. Therefore, very few studies on organic biomarkers in speleothems are available. Our new sensitive method allows us to use LOPs as vegetation biomarkers in speleothems. Our method consists of acid digestion of the speleothem sample followed by solid-phase extraction (SPE) of the organic matter. The extracted polymeric lignin is degraded in a microwave-a…
Characterisation of NO production and consumption: new insights by an improved laboratory dynamic chamber technique
2014
Biogenic NOx emissions from natural and anthropogenically influenced soils are currently estimated to amount to 9 Tg a−1, hence a significant fraction of global NOx emissions (45 Tg a−1). During the last three decades, a large number of field measurements have been performed to quantify biogenic NO emissions. To study biogenic NO emissions as a function of soil moisture, soil temperature, and soil nutrients, several laboratory approaches have been developed to estimate local/regional NO emissions by suitable upscaling. This study presents an improved and automated laboratory dynamic chamber system (consisting of six individual soil chambers) for investigation and quantification of all quant…
Applicability and consequences of the integration of alternative models for CO2 transfer velocity into a process-based lake model
2019
Freshwater lakes are important in carbon cycling, especially in the boreal zone where many lakes are supersaturated with the greenhouse gas carbon dioxide (CO2) and emit it to the atmosphere, thus ventilating carbon originally fixed by the terrestrial system. The exchange of CO2 between water and the atmosphere is commonly estimated using simple wind-based parameterizations or models of gas transfer velocity (k). More complex surface renewal models, however, have been shown to yield more correct estimates of k in comparison with direct CO2 flux measurements. We incorporated four gas exchange models with different complexity into a vertical process-based physico-biochemical lake model, MyLak…
Revisiting the disappearance of terrestrial dissolved organic matter in the ocean: a δ13C study
2014
Organic carbon (OC) depleted in 13C is a widely used tracer for terrestrial organic matter (OM) in aquatic systems. Photochemical reactions can, however, change δ13C of dissolved organic carbon (DOC) when chromophoric, aromatic-rich terrestrial OC is selectively mineralized. We assessed the robustness of the δ13C signature of DOC (δ13CDOC) as a tracer for terrestrial OM by estimating its change during the photobleaching of chromophoric DOM (CDOM) from 10 large rivers. These rivers cumulatively account for approximately one-third of the world's freshwater discharge to the global ocean. Photobleaching of CDOM by simulated solar radiation was associated with the photochemical mineralization of…
Diversity and mineral substrate preference in endolithic microbial communities from marine intertidal outcrops (Isla de Mona, Puerto Rico)
2017
14 pages; International audience; Endolithic microbial communities are prominent features of intertidal marine habitats, where they colonize a variety of substrates, contributing to their erosion. Almost 2 centuries worth of naturalistic studies focused on a few true-boring (euendolithic) phototrophs, but substrate preference has received little attention. The Isla de Mona (Puerto Rico) intertidal zone offers a unique setting to investigate substrate specificity of endolithic communities since various phosphate rock, limestone and dolostone outcrops occur there. High-throughput 16S rDNA genetic sampling, enhanced by targeted cultivation, revealed that, while euendolithic cyanobacteria were …
X-ray CT analyses, models and numerical simulations: a comparison with petrophysical analyses in an experimental CO2 study
2016
An essential part of the collaborative research project H2STORE (hydrogen to store), which is funded by the German government, was a comparison of various analytical methods for characterizing reservoir sandstones from different stratigraphic units. In this context Permian, Triassic and Tertiary reservoir sandstones were analysed. Rock core materials, provided by RWE Gasspeicher GmbH (Dortmund, Germany), GDF Suez E&P Deutschland GmbH (Lingen, Germany), E.ON Gas Storage GmbH (Essen, Germany) and RAG Rohöl-Aufsuchungs Aktiengesellschaft (Vienna, Austria), were processed by different laboratory techniques; thin sections were prepared, rock fragments were crushed and cubes of 1 cm edge leng…
Micro- and nano-porosity of the active Alpine Fault zone, New Zealand
2020
Porosity reduction in rocks from a fault core can cause elevated pore fluid pressures and consequently influence the recurrence time of earthquakes. We investigated the porosity distribution in the New Zealand's Alpine Fault core in samples recovered during the first phase of the Deep Fault Drilling Project (DFDP-1B) by using two-dimensional nanoscale and three-dimensional microscale imaging. Synchrotron X-ray microtomography-derived analyses of open pore spaces show total microscale porosities in the range of 0.1 %–0.24 %. These pores have mainly non-spherical, elongated, flat shapes and show subtle bipolar orientation. Scanning and transmission electron microscopy reveal the…
Control of 3-D tectonic inheritance on fold-and-thrust belts: insights from 3-D numerical models and application to the Helvetic nappe system
2020
We apply three-dimensional (3-D) thermo-mechanical numerical simulations of the shortening of the upper crustal region of a passive margin in order to investigate the control of 3-D laterally variable inherited structures on fold-and-thrust belt evolution and associated nappe formation. We consider tectonic inheritance by employing an initial model configuration with basement horst and graben structures having laterally variable geometry and with sedimentary layers having different mechanical strength. We use a visco-plastic rheology with a temperature-dependent flow law and a Drucker–Prager yield criterion. The models show the folding, detachment (shearing off) and horizontal transport of …