Search results for "Quadrupole"
showing 10 items of 460 documents
Searches for Large-Scale Anisotropy in the Arrival Directions of Cosmic Rays Detected above Energy of $10^{19}$ eV at the Pierre Auger Observatory an…
2014
Spherical harmonic moments are well-suited for capturing anisotropy at any scale in the flux of cosmic rays. An unambiguous measurement of the full set of spherical harmonic coefficients requires full-sky coverage. This can be achieved by combining data from observatories located in both the northern and southern hemispheres. To this end, a joint analysis using data recorded at the Telescope Array and the Pierre Auger Observatory above 1019 eV is presented in this work. The resulting multipolar expansion of the flux of cosmic rays allows us to perform a series of anisotropy searches, and in particular to report on the angular power spectrum of cosmic rays above 1019 eV. No significant devia…
The application of phospholipid removal columns and ultra-high performance liquid chromatography-tandem quadrupole mass spectrometry for quantificati…
2016
In this study a robust and sensitive method based on a proposed sample purification procedure, using zirconia-coated Phree™ columns and analysis by ultra-high performance liquid chromatography with triple quadrupole tandem mass spectrometry are presented for the assessment of multi-class antibiotics in farmed fish species. The sample preparation procedure benefited from combined precipitation of proteins and selective removal of phospholipids by Phree™ columns, resulting in a high sensitivity of the method (LOQ 0.3-9mgkg(-1)). The in-house validation results (precision, repeatability, decision limit CCα, detection capability CCβ, etc.) indicate that the elaborated method is fully suitable f…
Determination of pharmaceutical residues in wastewater using high performance liquid chromatography coupled to quadrupole-Orbitrap mass spectrometry
2016
Abstract A multi-class method for the determination of 24 emerging pharmaceutical residues has been developed and validated. The method is based on solid-phase extraction of wastewater samples using Strata-X cartridges followed by high performance liquid chromatography coupled to hybrid quadrupole − Orbitrap high resolution mass spectrometry (HPLC-Q-Orbitrap-HRMS). A single-laboratory validation procedure showed satisfactory analytical performance. The analysis of 21 samples collected at the wastewater treatment plant in Riga revealed the occurrence of 20 compounds of different therapeutic classes. The highest concentration was found for the central nervous system stimulator caffeine − up t…
An automatic L1-based regularization method for the analysis of FFC dispersion profiles with quadrupolar peaks
2023
Fast Field-Cycling Nuclear Magnetic Resonance relaxometry is a non-destructive technique to investigate molecular dynamics and structure of systems having a wide range of ap- plications such as environment, biology, and food. Besides a considerable amount of liter- ature about modeling and application of such technique in specific areas, an algorithmic approach to the related parameter identification problem is still lacking. We believe that a robust algorithmic approach will allow a unified treatment of different samples in several application areas. In this paper, we model the parameters identification problem as a con- strained L 1 -regularized non-linear least squares problem. Following…
Mass Spectrometry in Food Quality and Safety
2015
Abstract In recent years, mass spectrometry has gained a wide recognition as a selective and fast technique for the analysis and assessment of a wide range of food products. The state of the art in the determination of safety and quality of food is presented to illustrate the capability of this technique for classification and grading, defect and disease detection, distribution and visualization of chemical attributes, and evaluations of overall quality of meat, fish, fruits, vegetables, and other food products. The features of mass spectrometry for each category were summarized in the aspects of the investigated quality and safety attributes, the used systems (triple quadrupole, quadrupole…
Instabilities of ion motion in a linear Paul trap
2006
Abstract We have investigated the stability properties of a linear radio frequency ion trap with cylindrical electrodes. Inside the region of stability for an ideal trap we found a number of instabilities similar to those experimentally observed in three-dimensional traps. They arise from higher order contributions to the ideal quadrupole trapping potential. The static potential for axial confinement shifts the radial ion oscillation frequencies and leads to additional instabilities.
Cryogenic Particle Accumulation In ATRAP And The First Antihydrogen Production Within A Magnetic Gradient Trap For Neutral Antimatter
2008
ATRAP has made many important improvements since CERN's Antiproton Decelerator (AD) was restarted in 2006. These include substantial increases in the number of positrons (e+) and antiprotons (Pbars) used to make antihydrogen (Hbar) atoms, a new technique for loading electrons (e−) that are used to cool Pbars and e+, implementation of a completely new, larger and more robust apparatus in our second experimental zone and the inclusion of a quadrupole Ioffe trap intended to trap the coldest Hbar atoms produced. Using this new apparatus we have produced large numbers of Hbar atoms within a Penning trap that is located within this quadrupole Ioffe trap using a new technique which shows promise f…
Antihydrogen production within a Penning-Ioffe trap.
2008
Slow antihydrogen (H) is produced within a Penning trap that is located within a quadrupole Ioffe trap, the latter intended to ultimately confine extremely cold, ground-state H[over ] atoms. Observed H[over ] atoms in this configuration resolve a debate about whether positrons and antiprotons can be brought together to form atoms within the divergent magnetic fields of a quadrupole Ioffe trap. The number of detected H atoms actually increases when a 400 mK Ioffe trap is turned on.
Antiproton confinement in a Penning-Ioffe trap for antihydrogen.
2007
Antiprotons ((p) over bar) remain confined in a Penning trap, in sufficient numbers to form antihydrogen ((H) over bar) atoms via charge exchange, when the radial field of a quadrupole Ioffe trap is added. This first demonstration with (p) over bar suggests that quadrupole Ioffe traps can be superimposed upon (p) over bar and e(+) traps to attempt the capture of (H) over bar atoms as they form, contrary to conclusions of previous analyses.
Trapped ion density distribution in the presence of He-buffer gas
1981
The spatial density distribution of Ba+ ions, confined in a rf quadrupole trap, has been measured by laser scanning across the trap. This allows to determine the ion temperature, assuming thermal equilibrium. Under UHV conditions the average ion energy has been found to be one tenth of the trap potential well depth. Collisions with He at pressures up to 5×10−6 mbar reduce the ion temperature by a factor of 3.