Search results for "Quantum physic"
showing 10 items of 1596 documents
Analysis of highly excited 'hot' bands in the SO2 molecule: ν2 + 3ν3 - ν2 and 2ν1 + ν2 + ν3 - ν2
2010
International audience; We set up a variational procedure of assignments of transitions and we applied it to the analysis very weak 'hot' bands, v(2) + 3v(3) - v(2) and 2v(1) + v(2) + v(3) - v(2), of the SO2 molecule. As the first step of the study, the 'cold' bands, 3v(3) and 2v(1) + v(3), are re-analysed and transitions belonging to those bands are assigned up to the values of quantum numbers J(max.) = 60, K-a(max.) = 19, and J(max.) = 69, K-a(max.) = 20 for the bands 3v(3) and 2v(1) + v(3), respectively. After 'cleaning' the experimental spectrum from transitions belonging to the 3v(3) and 2v(1) + v(3) bands, a variational procedure was used that allowed us to assign 230 and 115 transiti…
XXI Dynamics of Molecular Collisions Meeting
2007
International audience
Localization from inertial data and sporadic position measurements
2020
International audience; A novel estimation strategy for inertial navigation in indoor/outdoor environments is proposed with a specific attention to the sporadic nature of the non-periodic measurements. After introducing the inertial navigation model, we introduce an observer providing an asymptotic estimate of the plant state. We use a hybrid dynamical systems representation for our results, in order to provide an effective, and elegant theoretical framework. The estimation error dynamics with the proposed observer shows a peculiar cascaded interconnection of three subsystems (allowing for intuitive gain tuning), with perturbations occurring either on the jump or on the flow dynamics (depen…
On the projective geometry of entanglement and contextuality
2019
A possible quantic motivation of the structure of quantum group: continuation
2012
Motivated by Quantum Mechanics considerations, we expose some cross product constructions on a groupoid structure. Furthermore, critical remarks are made on some basic formal aspects of the Hopf algebra structure.
Modèles quantiques à deux états avec croisements de niveaux décrits par les fonctions de Heun
2019
The thesis is devoted to the fundamental problem of excitation and manipulation of quantum systems, having discrete energy spectrum, via external laser fields. We examine the semiclassical time- dependent quantum two-state problem, when the external electromagnetic field is resonant or quasi-resonant for some two of many levels of the system. The focus of the thesis is on the analytic description of the non- adiabatic evolution of quantum systems subject to excitation by level-crossing field configurations. In the present thesis we classify the complete set of the semiclassical time-dependent quantum two-state models solvable in terms of the five function of the Heun class.Main results of t…
Sur le rôle des singularités hamiltoniennes dans les systèmes contrôlés : applications en mécanique quantique et en optique non-linéaire.
2012
This thesis has two goals: the first one is to improve the control techniques in quantum mechanics, and more specifically in NMR, by using the tools of geometric optimal control. The second one is the study of the influence of Hamiltonian singularities in controlled systems. The chapter about optimal control study three classical problems of NMR : the inversion problem, the influence of the radiation damping term, and the steady state technique. Then, we apply the geometric optimal control to the problem of the population transfert in a three levels quantum system to recover the STIRAP scheme.The two next chapters study Hamiltonian singularities. We show that they allow to control the polar…
Negatively Curved Nanographene with Heptagonal and [5]Helicene Units
2020
Negatively curved nanographene (NG) 4, having two heptagons and a [5]helicene, was unexpectedly obtained by aryl rearrangement and stepwise cyclodehydrogenations. X-ray crystallography confirmed the saddle-shaped structures of intermediate 3 and NG 4. The favorability of rearrangement over helicene formation following radical cation or arenium cation mechanisms is supported by theoretical calculations. NG 4 demonstrates a reversible mechanochromic color change and solid-state emission, presumably benefiting from its loose crystal packing. After resolution by chiral high-performance liquid chromatography, the circular dichroism spectra of enantiomers 4-(P) and 4-(M) were measured and showed …