Search results for "RADIATION"

showing 10 items of 5298 documents

Nd:YAG laser induced E′ centers probed by in situ absorption measurements

2005

We investigated various types of commercial silica irradiated with a pulsed Nd:YAG laser radiation (4.66 eV), with exposure time ranging up to 10000 s. Transient E' centers were probed in situ by measuring the amplitude of the optical absorption band at 5.8 eV (due to E' centers) both during and after irradiation. The laser-induced absorption is observed only in natural samples, whereas the synthetic materials exhibit high toughness to radiation effect. The reported results evidence that the kinetics of E' centers is influenced by their reaction with diffusing molecular hydrogen H2 made available by dimerization of radiolytic H0.

Condensed Matter - Materials ScienceAbsorption spectroscopyChemistryKineticsAnalytical chemistryMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesCondensed Matter PhysicsLaserElectronic Optical and Magnetic Materialslaw.inventionAbsorption bandlawNd:YAG laserRadiolysisMaterials ChemistryCeramics and CompositesIrradiationAbsorption (electromagnetic radiation)Journal of Non-Crystalline Solids
researchProduct

Bleaching of optical activity induced by UV Laser exposure in natural silica

2004

We report experimental data on two types of natural silica, differing for their OH content, irradiated with UV photons (4.66 eV) from a pulsed Nd:YAG laser. Irradiation induces a reduction of the absorption band at 5.12eV and of the associated emissions at 3.14eV and 4.28eV, ascribed to twofold coordinated Ge (=Ge'') centers pre-existing in our samples. The bleaching is mainly due to the post-irradiation conversion of =Ge'' into the paramagnetic H(II) center via trapping of a H atom. Comparison with literature data points out the peculiarities of silica with a low Ge concentration as regards UV induced transformations.

Condensed Matter - Materials ScienceChemistryAnalytical chemistryMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesDisordered Systems and Neural Networks (cond-mat.dis-nn)TrappingCondensed Matter - Disordered Systems and Neural NetworksCondensed Matter PhysicsLaseroptical fibers radiation effects radiation-induced attenuationElectronic Optical and Magnetic Materialslaw.inventionParamagnetismlawAbsorption bandAtomMaterials ChemistryCeramics and CompositesUv laserIrradiationUltraviolet radiation
researchProduct

Free-standing 2D metals from binary metal alloys

2020

Recent experiment demonstrated the formation of free-standing Au monolayers by exposing Au-Ag alloy to electron beam irradiation. Inspired by this discovery, we used semi-empirical effective medium theory simulations to investigate monolayer formation in 30 different binary metal alloys composed of late d-series metals Ni, Cu, Pd, Ag, Pt, and Au. In qualitative agreement with the experiment, we find that the beam energy required to dealloy Ag atoms from Au-Ag alloy is smaller than the energy required to break the dealloyed Au monolayer. Our simulations suggest that similar method could also be used to form Au monolayers from Au-Cu alloy and Pt monolayers from Pt-Cu, Pt-Ni, and Pt-Pd alloys.

Condensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale PhysicsalloysMesoscale and Nanoscale Physics (cond-mat.mes-hall)effective medium approximationMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesmetalliseokset2D materialslcsh:Physicslcsh:QC1-999electron beam irradiation
researchProduct

Spectroscopic parameters related to non bridging oxygen hole centers in amorphous-SiO2

2005

The relationship between the luminescence at 1.9 eV and the absorption bands at 2.0 eV and at 4.8 eV were investigated in a wide variety of synthetic silica samples exposed to different gamma- and beta-ray irradiation doses. We found that the intensities of these optical bands are linearly correlated in agreement with the model in which they are assigned to a single defect. This finding allows to determine spectroscopic parameters related to optical transitions efficiency: the oscillator strength of the 4.8 eV results ~200 times higher than that of the 2.0 eV; the 1.9 eV luminescence quantum yield under 4.8 eV excitation is lower (by a factor ~3) than that under 2.0 eV excitation. These res…

Condensed Matter - Materials ScienceLuminescencePhotoluminescenceAbsorption spectroscopyOscillator strengthChemistrySettore FIS/01 - Fisica SperimentaleOptical spectroscopyMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesQuantum yieldSilicaCondensed Matter PhysicsAbsorptionElectronic Optical and Magnetic MaterialsMaterials ChemistryCeramics and CompositesDefectAtomic physicsAbsorption (electromagnetic radiation)SpectroscopyLuminescenceExcitation
researchProduct

Revealing the importance of interfaces for pure spin current transport

2021

Spin transport phenomena underpin an extensive range of spintronic effects. In particular spin transport across interfaces occurs in most device concepts, but is so far poorly understood. As interface properties strongly impact spin transport, one needs to characterize and correlate them to the fabrication method. Here we investigate pure spin current transport across interfaces and connect this with imaging of the interfaces. We study the detection of pure spin currents via the inverse spin Hall effect in Pt and the related spin current absorption by Pt in Py-Cu-Pt lateral spin valves. Depending on the fabrication process, we either find a large (inverse) spin Hall effect signal and low sp…

Condensed Matter - Materials ScienceMaterials scienceCondensed matter physicsCondensed Matter - Mesoscale and Nanoscale Physics530 PhysicsMeasure (physics)Materials Science (cond-mat.mtrl-sci)FOS: Physical sciencesDirect imagingSpin current530 PhysikCharacterization (materials science)Mesoscale and Nanoscale Physics (cond-mat.mes-hall)Condensed Matter::Strongly Correlated ElectronsAbsorption (electromagnetic radiation)Spin-½
researchProduct

Optical absorption induced by UV laser radiation in Ge-doped amorphous silica probed by in situ spectroscopy

2007

We studied the optical absorption induced by 4.7eV pulsed laser radiation on Ge-doped a-SiO2 synthesized by a sol-gel technique. The absorption spectra in the ultraviolet spectral range were measured during and after the end of irradiation with an in situ technique, evidencing the growth of an absorption signal whose profile is characterized by two main peaks near 4.5eV and 5.7eV and whose shape depends on time. Electron spin resonance measurements performed ex situ a few hours after the end of exposure permit to complete the information acquired by optical absorption by detection of the paramagnetic Ge(1) and Ge-E' centers laser-induced in the samples.

Condensed Matter - Materials ScienceMaterials scienceGeAbsorption spectroscopyOptical absorptionDopingAnalytical chemistryMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesDisordered Systems and Neural Networks (cond-mat.dis-nn)RadiationOptical radiationCondensed Matter - Disordered Systems and Neural NetworksCondensed Matter Physicsmedicine.disease_causelaw.inventionParamagnetismUV laserlawsilicamedicineIrradiationAbsorption (electromagnetic radiation)Electron paramagnetic resonanceUltraviolet
researchProduct

Hydrogen-related conversion processes of Ge-related point defects in silica triggered by UV laser irradiation

2005

The conversion processes of Ge-related point defects triggered in amorphous SiO2 by 4.7eV laser exposure were investigated. Our study has focused on the interplay between the (=Ge•-H) H(II) center and the twofold coordinated Ge defect (=Ge••). The former is generated in the post-irradiation stage, while the latter decays both during and after exposure. The post-irradiation decay kinetics of =Ge•• is isolated and found to be anti-correlated to the growth of H(II), at least at short times. From this finding it is suggested that both processes are due to trapping of radiolytic H0 at the diamagnetic defect site. Furthermore, the anti-correlated behavior is preserve…

Condensed Matter - Materials ScienceMaterials scienceHydrogenKineticsPhotodissociationchemistry.chemical_elementMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesCondensed Matter Physicsmedicine.disease_causePhotochemistryCrystallographic defectElectronic Optical and Magnetic MaterialsAmorphous solidchemistryImpuritymedicineIrradiationUltraviolet
researchProduct

UV-Photoinduced Defects In Ge-Doped Optical Fibers

2005

We investigated the effect of continuous-wave (cw) UV laser radiation on single-mode Ge-doped H2- loaded optical fibers. An innovative technique was developed to measure the optical absorption (OA) induced in the samples by irradiation, and to study its dependence from laser fluence. The combined use of the electron spin resonance (ESR) technique allowed the structural identification of several radiation-induced point defects, among which the Ge(1) (GeO4 -) is found to be responsible of induced OA in the investigated spectral region.

Condensed Matter - Materials ScienceMaterials scienceOptical fiberbusiness.industryDopingMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesDisordered Systems and Neural Networks (cond-mat.dis-nn)RadiationCondensed Matter - Disordered Systems and Neural NetworksFluenceCrystallographic defectoptical fibers radiation effects radiation-induced attenuationlaw.inventionlawOptoelectronicsIrradiationAbsorption (electromagnetic radiation)businessElectron paramagnetic resonance
researchProduct

Probing giant magnetoresistance with THz spectroscopy

2014

We observe a giant magnetoresistance effect in CoFe/Cu-based multistack using THz time-domain spectroscopy. The magnetic field-dependent dc conductivity, electron scattering time, as well as spin-asymmetry parameter of the structure are successfully determined.

Condensed Matter::Materials ScienceMaterials scienceCondensed matter physicsScatteringTerahertz radiationGiant magnetoresistanceElectronSpectroscopyElectron scatteringTerahertz spectroscopy and technologyMagnetic field
researchProduct

Radiation Response of Ce-Doped Phosphosilicate Optical Fibers

2014

International audience; We report an experimental study of the radiation effects on silica-based multimode optical fibers (OFs) either doped with Phosphorus or with Phosphorus and Cerium. Online Radiation-Induced-Absorption (RIA) measurements were performed in the UV-visible spectral domain under 10 keV X-ray Irradiation. Optical Absorption (OA) in the Near Infrared Region (NIR) and Electron Paramagnetic Resonance (EPR) measurements were also performed on γ-irradiated OFs.

Condensed Matter::Materials Science[SPI]Engineering Sciences [physics]irradiation effectsSettore FIS/01 - Fisica Sperimentale
researchProduct