Search results for "RAMAN"
showing 10 items of 1328 documents
Raman and Infrared Spectra of Acoustical, Functional Modes of Proteins from All-Atom and Coarse-Grained Normal Mode Analysis
2018
The directions of the largest thermal fluctuations of the structure of a protein in its native state are the directions of its low-frequency modes (below 1 THz), named acoustical modes by analogy with the acoustical phonons of a material. The acoustical modes of a protein assist its conformational changes and are related to its biological functions. Low-frequency modes are difficult to detect experimentally. A survey of experimental data of low-frequency modes of proteins is presented. Theoretical approaches, based on normal mode analysis, are of first interest to understand the role of the acoustical modes in proteins. In this chapter, the fundamentals of normal mode analysis using all-ato…
Generation of entanglement in systems of intercoupled qubits
2014
We consider systems of two and three qubits, mutually coupled by Heisenberg-type exchange interaction and interacting with external laser fields. We show that these systems allow one to create maximally entangled Bell states, as well as three qubit Greenberger-Horne-Zeilinger and W states. In particular, we point out that some of the target states are the eigenstates of the initial bare system. Due to this, one can create entangled states by means of pulse area and adiabatic techniques, when starting from a separable (non-entangled) ground state. On the other hand, for target states, not present initially in the eigensystem of the model, we apply the robust stimulated Raman adiabatic passag…
Stimulated Raman Adiabatic Passage via bright state in Lambda medium of unequal oscillator strengths
2012
International audience; We consider the population transfer process in a Lambda-type atomic medium of unequal oscillator strengths by stimulated Raman adiabatic passage via bright-state (b-STIRAP) taking into account propagation effects. Using both analytic and numerical methods we show that the population transfer efficiency is sensitive to the ratio q(p)/q(s) of the transition oscillator strengths. We find that the case q(p) > q(s) is more detrimental for population transfer process as compared to the case where q(p) <= q(s). For this case it is possible to increase medium dimensions while permitting efficient population transfer. A criterion determining the interaction adiabaticity in th…
Stimulated Raman adiabatic passage in a $\Lambda$-system in the presence of quantum noise
2011
We exploit a microscopically derived master equation for the study of STIRAP in the presence of decay from the auxiliary level toward the initial and final state, and compare our results with the predictions obtained from a phenomenological model previously used [P. A. Ivanov, N. V. Vitanov, and K. Bergmann, Phys. Rev. A 72, 053412 (2005)]. It is shown that our approach predicts a much higher efficiency. The effects of temperature are also taken into account, proving that in b-STIRAP thermal pumping can increase the efficiency of the population transfer.
Coarse grained and fine dynamics in trapped ion Raman schemes
2004
A novel result concerning Raman coupling schemes in the context of trapped ions is obtained. By means of an operator perturbative approach, it is shown that the complete time evolution of these systems (in the interaction picture) can be expressed, with a high degree of accuracy, as the product of two unitary evolutions. The first one describes the time evolution related to an effective coarse grained dynamics. The second is a suitable correction restoring the {\em fine} dynamics suppressed by the coarse graining performed to adiabatically eliminate the nonresonantly coupled atomic level.
Stimulated Raman adiabatic passage in an open quantum system: Master equation approach
2010
A master equation approach to the study of environmental effects in the adiabatic population transfer in three-state systems is presented. A systematic comparison with the non-Hermitian Hamiltonian approach [N. V. Vitanov and S. Stenholm, Phys. Rev. A {\bf 56}, 1463 (1997)] shows that in the weak coupling limit the two treatments lead to essentially the same results. Instead, in the strong damping limit the predictions are quite different: in particular the counterintuitive sequences in the STIRAP scheme turn out to be much more efficient than expected before. This point is explained in terms of quantum Zeno dynamics.
Superluminal two-color light in multiple Raman gain medium
2014
We investigate theoretically the formation of two-component light with superluminal group velocity in a medium controlled by four Raman pump fields. In such an optical scheme only a particular combination of the probe fields is coupled to the matter and exhibits superluminal propagation, the orthogonal combination is uncoupled. The individual probe fields do not have a definite group velocity in the medium. Calculations demonstrate that this superluminal component experiences an envelope advancement in the medium with respect to the propagation in vacuum.
Theory of the bright-state stimulated Raman adiabatic passage
2009
We describe analytically and numerically the process of population transfer by stimulated Raman adiabatic passage through a bright state when the pulses propagate in a medium. Limitations of the adiabaticity are analyzed and interpreted in terms of reshaping of the pulses. We find parameters for the pulses for which the population transfer is nearly complete over long distances.
Perturbative Treatment of the Evolution Operator Associated with Raman Couplings
2006
A novel perturbative treatment of the time evolution operator of a quantum system is applied to the model describing a Raman-driven trapped ion in order to obtain a suitable 'effective model'. It is shown that the associated effective Hamiltonian describes the system dynamics up to a certain transformation which may be interpreted as a 'dynamical dressing' of the effective model.
The branching ratio of intercombination A1Σ+∼b3Π→a3Σ+/X1Σ+transitions in the RbCs molecule: Measurements and calculations
2020
Abstract We observed the A 1 Σ + ∼ b 3 Π → a 3 Σ + / X 1 Σ + laser-induced fluorescence (LIF) of the RbCs molecule excited from the ground X 1 Σ + state by the Ti:Sapphire laser. The LIF spectra from the common perturbed levels of the singlet-triplet A ∼ b complex was recorded by the Fourier-transform (FT) spectrometer with the instrumental resolution of 0.03 cm − 1 . The relative intensity distribution in the rotationally resolved A ∼ b → a 3 Σ + ( v a ) / X 1 Σ + ( v X ) progressions was measured, and their branching ratio was found to be about of 1 ÷ 5 × 10 − 4 in the bound region of the a 3 Σ + and X 1 Σ + states. The experiment was complemented with the scalar- and full-relativistic ca…