Search results for "RAMAN"
showing 10 items of 1328 documents
High-resolution spectroscopy and preliminary global analysis of C–H stretching vibrations of C2H4 in the 3000 and 6000cm−1 regions
2010
Abstract Ethylene (ethene, H2C=CH2) is a naturally occurring compound in ambient air that affects atmospheric chemistry and global climate. The C2H4 spectrum is available in databases only for the 1000 and 3000 cm−1 ranges. In this work, the ethylene absorption spectrum was measured in the 6030–6250 cm−1 range with the use of a high resolution Bruker IFS 125HR Fourier-spectrometer and a two-channel opto-acoustic spectrometer with a diode laser. As a secondary standard of wavelengths, the methane absorption spectrum was used in both cases. A preliminary analysis was realized thanks to the tensorial formalism developed by the Dijon group that is implemented in the XTDS software package [39] .…
MeCaSDa and ECaSDa: Methane and ethene calculated spectroscopic databases for the virtual atomic and molecular data centre
2013
Abstract Two spectroscopic relational databases, denoted MeCaSDa and ECaSDa, have been implemented for methane and ethene, and included in VAMDC (Virtual Atomic and Molecular Data Centre, http://portal.vamdc.eu/vamdc_portal/home.seam ). These databases collect calculated spectroscopic data from the accurate analyses previously performed for the electronic ground state of methane, ethene, and some of their isotopologues: 12CH4, 13CH4, and 12C2H4. Both infrared absorption and Raman scattering lines are included. The polyad structures are reported and the transitions are precisely described by their energy, their intensity and the full description of the lower and upper states involved in the …
A direct study of the vibrational bending effect in line mixing: The hot degenerate 1110 ← 0110 transition of CO2
1997
Abstract The study of the isotropiv Raman Q -branch of a hot band Π ← Π allows one to establish a direct connection between the vibration-rotation angular momentum coupling and the resulting spectra. Due to the l -doubling, the Q -branch is split into two subbranches characterized by either even or odd rotational quantum number j . The vibrational bending reduces the rotational transfer rates inside each of these subbranches by a factor of about two and induces an inter-subbranch coupling. The expected propensity rule towards conservation of the parity index for high rotational levels is well observed. Calculated spectra are in excellent agreement with CARS experiments for the v 1 + v 2 ← v…
Collisional broadening and shifting parameters of the RamanQbranch ofH2perturbed byN2determined from speed-dependent line profiles at high temperatur…
1996
The broadening and shifting of the {ital Q} branch of H{sub 2} diluted in N{sub 2} are studied at temperatures between 300 and 1200 K. (i) In order to account for the observed anomalies (asymmetric profiles and nonlinearity of the linewidth versus perturber concentration), the results are interpreted using a speed-dependent model in its general form. This model introduces the speed dependence of the shift and the broadening. In contrast with the previous H{sub 2}{endash}rare-gas studies, the high-temperature measurements prove the necessity to include speed-dependent broadening that was ignored in the previous studies. (ii) Concomitantly, we report as well pure H{sub 2} results including Ra…
FITTING LAW FOR THE DENSITY SHIFT OF Q(J) TRANSITIONS OF H2 IN H2–X (X: H2, He, N2) MIXTURES
1998
Abstract A variety of fitting laws have been developed for the purpose of modelling broadening effects in collisional processes, but only a few have been proposed for modelling collision-induced lineshifts in molecules. We analysed accurate stimulated Raman data obtained in several H2–X mixtures (X: H2, He and N2). For the first time, we show that an empirical law provides a very good representation of collisional lineshift coefficients in the range 300–1200 K and for J quantum number up to 9.
Pressure broadening, shift, and interference effect for a multiplet line in the rovibrational anisotropic stimulated raman spectrum of molecular oxyg…
1996
0022-2852; High-resolution stimulated inverse Raman spectroscopy has been applied to the study of collisional broadening, shifting, and line mixing for the O-o(J, N = 5) triplet line of the fundamental vibrational band of molecular oxygen. Accurate line broadening coefficients for the individual J components within the triplet have been measured for the first time and show a significant J dependence. The line broadening coefficients are larger than those previously obtained for unresolved pure rotational Raman lines. The additional broadening is expected to result from electronic spin relaxation. The pressure-induced line shift has been obtained for this Line and compared to the value obtai…
Spatial correlation of laser-generated electrons and holes in quantum wells
1995
The spatial correlation of hot electrons and holes generated by light in a semiconductor quantum well (QW) is studied. For hot electron-hole pairs in a polar material, this correlation is determined by the interaction with LO-phonons. We analyze the distribution F N (r, K) of electrons and holes which are created in a given light absorption process, with respect to their relative separation r and total quasimomentum ħK, after the emission of a number N of LO-phonons. The relationship between the spatial distribution of electrons and holes in these intermediate states and the cross-section of multi-phonon resonant Raman scattering (MPRRS) is established. Spatial correlation effects are stron…
160-GHz picosecond pulse train generation through multiwave mixing compression of a dual frequency beat signal
2002
We report the experimental generation and characterization of a 160-GHz picosecond puise train using multiple four-wave mixing temporal compression of an initial dual frequency beat signal in the anomalous-dispersion regime of a non-zero dispersion shifted fiber.
Pressure-Induced Collapse of the Charge Density Wave and Higgs Mode Visibility in 2H−TaS2
2019
The pressure evolution of the Raman active electronic excitations of the transition metal dichalcogenides $2H\text{\ensuremath{-}}{\mathrm{TaS}}_{2}$ is followed through the pressure phase diagram embedding incommensurate charge-density-wave and superconducting states. At high pressure, the charge-density wave is found to collapse at 8.5 GPa. In the coexisting charge-density-wave and superconducting orders, we unravel a strong in-gap superconducting mode, attributed to a Higgs mode, coexisting with the expected incoherent Cooper-pair breaking signature. The latter remains in the pure superconducting state reached above 8.5 GPa. Our report constitutes a new observation of such Raman active H…
CSRZ-ASK and DPSK 40 Gb/s All-Raman WDM Transmission Based on UltraWave Fiber
2006
In this paper, we report a complete experimental and numerical analysis of 40 Gb/s WDM ultra long-haul (ULH) transmission using CSRZ-DPSK and CSRZ-ASK modulation formats on UltraWavetrade fiber spans. Experimental results compare well with full numerical simulations