Search results for "RECOGNITION"
showing 10 items of 3607 documents
Assessing local differences between the spatio-temporal second-order structure of two point patterns occurring on the same linear network
2021
Abstract We introduce Local Indicators of Spatio-Temporal Association (LISTA) functions on linear networks and use them to build a statistical test for local second-order structure. This allows to identify differences in the spatio-temporal clustering behaviour of two point patterns, a point pattern of interest and a background one, both occurring on the same linear network. We assess the performance of the testing procedure for local second-order structure through simulation studies under a variety of scenarios that also account for different generating point processes. We show that the proposed local test is able to correctly identify the spatio-temporal difference in the local second-ord…
Steady-state and tracking analysis of a robust adaptive filter with low computational cost
2007
This paper analyses a new adaptive algorithm that is robust to impulse noise and has a low computational load [E. Soria, J.D. Martin, A.J. Serrano, J. Calpe, and J. Chambers, A new robust adaptive algorithm with low computacional cost, Electron. Lett. 42 (1) (2006) 60-62]. The algorithm is based on two premises: the use of the cost function often used in independent component analysis and a fuzzy modelling of the hyperbolic tangent function. The steady-state error and tracking capability of the algorithm are analysed using conservation methods [A. Sayed, Fundamentals of Adaptive Filtering, Wiley, New York, 2003], thus verifying the correspondence between theory and experimental results.
A new method for linear affine self-calibration of stationary zooming stereo cameras
2012
This paper presents a simple, yet effective, method to recover the affine structure of a scene from a (stereo) pair of stationary zooming cameras. The proposed method solely relies on point correspondences across images and no knowledge about the scene whatsoever is required. Our method exploits implicit properties of the projective camera matrices of zooming cameras and allows to estimate the affine structure of a scene by solving a linear system of equations. The 3D reconstruction results obtained by using our method, on both real and simulated data, have remarkably validated its feasibility.
3-D shape reconstruction in an active stereo vision system using genetic algorithms
2003
Abstract The recovery of 3-D shape information (depth) using stereo vision analysis is one of the major areas in computer vision and has given rise to a great deal of literature in the recent past. The widely known stereo vision methods are the passive stereo vision approaches that use two cameras. Obtaining 3-D information involves the identification of the corresponding 2-D points between left and right images. Most existing methods tackle this matching task from singular points, i.e. finding points in both image planes with more or less the same neighborhood characteristics. One key problem we have to solve is that we are on the first instance unable to know a priori whether a point in t…
Molecular recognition of N-acetyltryptophan enantiomers by β-cyclodextrin
2017
The enantioselectivity of β-cyclodextrin (β-CD) towards L- and D-N-acetyltryptophan (NAcTrp) has been studied in aqueous solution and the crystalline state. NMR studies in solution show that β-CD forms complexes of very similar but not identical geometry with both L- and D-NAcTrp and exhibits stronger binding with L-NAcTrp. In the crystalline state, only β-CD–L-NAcTrp crystallizes readily from aqueous solutions as a dimeric complex (two hosts enclosing two guest molecules). In contrast, crystals of the complex β-CD–D-NAcTrp were never obtained, although numerous conditions were tried. In aqueous solution, the orientation of the guest in both complexes is different than in the β-CD–L-NAcTrp …
Classification of flavonoid compounds by using entropy of information theory
2013
A total of 74 flavonoid compounds are classified into a periodic table by using an algorithm based on the entropy of information theory. Seven features in hierarchical order are used to classify structurally the flavonoids. From these features, the first three mark the group or column, while the last four are used to indicate the row or period in a table of periodic classification. Those flavonoids in the same group and period are suggested to show maximum similarity in properties. Furthermore, those with only the same group will present moderate similarity. In this report, the flavonoid compounds in the table, whose experimental data in bioactivity and antioxidant properties have been prev…
Molecular recognition of naphthalene diimide ligands by telomeric quadruplex-DNA: the importance of the protonation state and mediated hydrogen bonds.
2016
In depth Monte Carlo conformational scans in combination with molecular dynamics (MD) simulations and electronic structure calculations were applied in order to study the molecular recognition process between tetrasubstituted naphthalene diimide (ND) guests and G-quadruplex (G4) DNA receptors. ND guests are a promising class of telomere stabilizers due to which they are used in novel anticancer therapeutics. Though several ND guests have been studied experimentally in the past, the protonation state under physiological conditions is still unclear. Based on chemical intuition, in the case of N-methyl-piperazine substitution, different protonation states are possible and might play a crucial …
Binding Mode and Selectivity of a Scorpiand-Like Polyamine Ligand to Single- and Double-Stranded DNA and RNA: Metal- and pH-Driven Modulation
2017
The interaction of a polyazacyclophane ligand having an ethylamine pendant arm functionalized with an anthryl group (L), with the single-stranded polynucleotides polyA, polyG, polyU, and polyC as well as with the double-stranded polynucleotides polyA-polyU, poly(dAT)(2), and poly(dGC)(2) has been followed by UV/Vis titration, steady state fluorescence spectroscopy, and thermal denaturation measurements. In the case of the single-stranded polynucleotides, the UV/Vis and fluorescence titrations permit to distinguish between sequences containing purine and pyrimidine bases. For the double-stranded polynucleotides the UV/Vis measurements show for all of them hypochromicity and bathochromic shif…
Four-, five- and six-coordinated Zn-II complexes of OH-containing ligands: Syntheses, structure and reactivity
2002
Four-, five- and six-coordinated complexes of Zn-II with OH-rich molecules possessing an ONO binding core were synthesized, characterized and their structures were established by single-crystal X-ray diffraction, The corresponding metal ion geometries were found to be distorted tetrahedral, square pyramidal and octahedral, respectively. The complexes exhibit interesting lattice structures such as layered and corrugated sheets owing to the presence of a number of weak intermolecular interactions. The five-coordinated, water-bound Zn-II complex was studied because of its putative hydrolysis property towards p-nitrophenyl acetate. (C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
Effects of side chains of oxatub[4]arene on its conformational interconversion, molecular recognition and macroscopic self-assembly.
2017
A series of oxatub[4]arenes with different alkyl side chains have been synthesized. The conformational interconversion, molecular recognition and macroscopic self-assembly behaviour of oxatub[4]arene derivatives were investigated. The difference in side chains slightly changes the binding affinities, but results in different self-assembly morphologies at the solid state.