Search results for "RECTIFICATION"
showing 4 items of 44 documents
Nanopore charge inversion and current-voltage curves in mixtures of asymmetric electrolytes
2018
[EN] We consider the screening of the negative charges (carboxylic acid groups) fixed on the surface of a conical-shaped track-etched nanopore by divalent magnesium (Mg2+) and trivalent lanthanum (La3+). The experimental current (I)-voltage (V) curves and current rectification ratios allow discussing fundamental questions about the overcompensation of spatially-fixed charges by multivalent ions over nanoscale volumes. The effects of charge inversion or reversal on nanopore transport are discussed in mixtures of asymmetric electrolytes (LaCl3 and MgCl2 with KCl). In particular, pore charge inversion is demonstrated for La3+ as well as for mixtures of this trivalent ion at low concentrations …
Corporate social irresponsibility: What we know and what we need to know
2022
Corporate social irresponsibility (CSI) is a critical issue for managers and researchers. In fact, the number of studies on this subject from diverse literature is rapidly increasing, seeking to answer questions regarding the core elements of CSI, its antecedents, and consequences. This paper offers a comprehensive literature review of this topic, identifying and assessing previous studies, synthesizing their findings, and highlighting knowledge gaps. Additionally, it offers recommendations regarding how to move forward. Our review identified 155 studies published from 1962 to 2020 that describe the antecedents, outcomes, mediators, and moderators of CSI according to different levels of ana…
Heat rectification in He II counterflow in radial geometries
2018
Abstract We consider heat rectification in radial flows of turbulent helium II, where heat flux is not described by Fourier's law, but by a more general law. This is different from previous analyses of heat rectification, based on such law. In our simplified analysis we show that the coupling between heat flux and the gradient of vortex line density plays a decisive role in such rectification. Such rectification will be low at low and high values of the heat rate, but it may exhibit a very high value at an intermediate value of the heat rate. In particular, for a given range of values for the incoming heat ow, the outgoing heat flow corresponding to the exchange of internal and external tem…
Net currents obtained from zero-average potentials in single amphoteric nanopores
2013
We have studied experimentally and theoretically the rectifying properties of a single asymmetric nanopore functionalized with amphoteric lysine groups and characterized the net current obtained with zero-average time dependent potentials. The pH-controlled rectification phenomena may be relevant to bio-electrochemistry, pH sensing and regulation, and energy conversion. (C) 2013 Elsevier B.V. All rights reserved.