Search results for "RHEOLOGY"
showing 10 items of 430 documents
Dilute solution rheology of flexible macromolecules (bead–rod model)
1974
The rheological behavior of dilute solutions of flexible macromolecules is studied by means of a freely jointed multiple bead–rod model. The solution of the equations describing the mechanics of the system is obtained by means of a numerical procedure, which applies to arbitrary flow conditions. The case of the transient stress in uniaxial elongational flow is developed in some detail. A comparison with bead–spring models shows both quantitative and qualitative differences which are briefly discussed.
Revealing Magnetite Nanoparticles Aggregation Dynamics – A SLS and DLS Study
2010
\(\mathrm{Fe}_{3}\mathrm{O}_{4}\) nanoparticles in aqueous suspensions are not stable but aggregate, tremendously changing the rheological properties of the nanofluid. Modified version of both the Static Light Scattering (SLS) setup and of Dynamic Light Scattering (DLS) setup experiment were used to monitor \(\mathrm{Fe}_{3}\mathrm{O}_{4}\) nanoparticle aggregation in aqueous diluted suspension. The experiments are described in detail and the variation of the average aggregate diameter in time is presented in this work.
The rheology of three-phase suspensions at low bubble capillary number
2015
We develop a model for the rheology of a three-phase suspension of bubbles and particles in a Newtonian liquid undergoing steady flow. We adopt an 'effective-medium' approach in which the bubbly liquid is treated as a continuous medium which suspends the particles. The resulting three-phase model combines separate two-phase models for bubble suspension rheology and particle suspension rheology, which are taken from the literature. The model is validated against new experimental data for three-phase suspensions of bubbles and spherical particles, collected in the low bubble capillary number regime. Good agreement is found across the experimental range of particle volume fraction ([Formula: s…
Magnetorheology: Fluids, Structures and Rheology
2002
Magnetorheological suspensions are complex fluids which show a transition from a liquid behavior to a solid one upon application of a magnetic field. This transition is due to the the attractive dipolar forces between the particles which have been magnetized by the applied field. The formation of a network of particles or aggregates throughout the suspension is the basic phenomena which is responsible for the strength of the solid phase. In this paper we shall give an overview on the fluids and their properties and we shall especially emphasize the interplay between magnetic forces which are responsible for the gelling of the suspension and on the other hand of hydrodynamic and thermal forc…
Thermoreversible gelation of kappa-carrageenan: relation between conformational transition and aggregation.
2003
Abstract We have studied, by optical rotation dispersion, light scattering and rheology, the κ-Carrageenan system to elucidate the processes involved in gel formation (on decreasing the temperature) and gel melting (on increasing the temperature). Our results show that, on decreasing the temperature, a conformational transition from coils to double helices first occurs, followed by aggregation of the double helices into domains and gel formation at appropriate polymer concentration. Structural details of this sequence are better revealed by re-heating the system. Melting appears as a two-step process characterized by first a conformational change of helices involved in junction zones betwee…
Comparison between bitumen modified with crumb tyre rubber and styrene butadiene styrene
2009
The improvements in terms of mechanical properties due to the use of polymers to modify bitumens in road paving applications have already been widely demonstrated. The aim of this paper is to show how the rheology and the performance of a bituminous binder mixed with crumb rubber recycled from used tyres (CR-MB), could be comparable with a styrene butadiene styrene (SBS-MB) created with the same base binder and currently used for road applications. Physical, chemical and performance characterization followed by rheological and storage stability analyses have been undertaken as the basis for the comparison. The results of the investigation indicate that the blended CR-MB shows large improvem…
Data from: Coping with the climate: cuticular hydrocarbon acclimation of ants under constant and fluctuating conditions
2018
Terrestrial arthropods achieve waterproofing by a layer of cuticular hydrocarbons (CHCs). At the same time, CHCs also serve as communication signals. To maintain waterproofing under different climate conditions, insects adjust the chemical composition of their CHC layer, but this may affect the communication via CHC. The detailed acclimatory changes of CHCs and how these influence their physical properties are still unknown. Here, we studied acclimation in two closely related ant species with distinct CHC profiles, Myrmica rubra and Myrmica ruginodis, in response to constant or fluctuating temperature and humidity regimes. We measured how acclimation affected CHC composition and viscosity, …
Supramolecular Eutecto Gels: Fully Natural Soft Materials
2018
The obtainment of materials featured by high environmental compatibility is one of the main goals of modern research. On this subject, we herein report the first example of supramolecular gel in deep eutectic solvents. In particular, we prepared gels of the L-amino acids isoleucine and tryptophan in choline chloride/phenylacetic acid 1:2. All gel components are readily available and nontoxic. Gels have been fully characterized by standard gelation tests, rheology, X-ray diffraction, morphology and gelation kinetics. Data collected show that gels properties depend on the gelator nature. In particular, gel phases exhibit strong colloidal forces and, this high mechanical resistance, together w…
Simulations of non-spherical particles suspended in a shear flow
2000
The lattice-Boltzmann method was used to investigate the effects of the shape and concentration of the particles on the rheological properties of non-Brownian suspensions for non-zero Reynolds numbers. Several case studies were analyzed and the methods used were found to give accurate predictions for these systems. The viscosity of suspensions of both spherical and non-spherical particles was determined as functions of shear rate and concentration of particles. It was shown that, for high shear rates, shear thickening appears. This phenomenon is particularly pronounced for particles of irregular shape.
Production of innovative, recycled and high-performance asphalt for road pavements
2010
Abstract The paper deals with a specific laboratory study aiming at perfectioning recycled asphalt with high mechanical performance, for surface and structural layers of flexible pavements. The aim of the research was to combine in the same material the maximum possible quantity of recycled asphalt (RA), coming from degraded asphalt layers, together with high structural performance of the recycled mixtures obtained (mainly stability, load spreading properties, rutting and fatigue resistance) that should not be lower, or possibly better than those offered by traditional asphalt mixture, made with virgin binder and aggregate. For this purpose, innovative recycled mixtures, close-graded and wi…