Search results for "RILL"
showing 10 items of 1272 documents
Effect of extrusion and photoxidation on polyethylene/clay nanocomposites
2009
Polyethylene (a 1:1 blend of m-LLDPE and z-LLDPE) double layer silicate clay nanocomposites were prepared by melt extrusion using a twin screw extruder. Maleic anhydride grafted polyethylene (PEgMA) was used as a compatibiliser to enhance the dispersion of two organically modified monmorilonite clays (OMMT): Closite 15A (CL15) and nanofill SE 3000 (NF), and natural montmorillonite (NaMMT). The clay dispersion and morphology obtained in the extruded nanocomposite samples were fully characterised both after processing and during photo-oxidation by a number of complementary analytical techniques. The effects of the compatibiliser, the organoclay modifier (quartenary alkyl ammonium surfactant) …
The effect of partial exfoliation of multilayer silicate filler particles on the elastic properties of a polymer composite
2018
Abstract A method for stepwise calculation the elastic constants of a three-phase composite, including the polymer matrix, the fully exfoliated silicate nanolayers and the platelike silicate particles in the form of multilayer intercalated stacks is considered. A theoretical analysis is carried out by using the Mori–Tanaka theory of an equivalent medium. The influence of degree of exfoliation (the ratio of exfoliated filler content to the total filler content) on the reinforcing efficiency is studied and discussed. A comparative analysis of experimental data of elastic modulus for a rigid polyurethane/montmorillonite composite and prediction results is carried out. It is shown, that with gr…
Structural studies of adsorbed protein (betalactoglobulin) on natural clay (montmorillonite)
2014
International audience; In this work, the adsorption of a small globular protein (betalactoglobulin, BLG), on a natural montmorillonite clay (Mt) was investigated in acidic buffer (pH = 3). The combination of different characterization techniques such as zetametry, X-ray diffraction, transmission electronic microscopy, fluorescence and solid state nuclear magnetic resonance spectroscopies shed light on the interaction mechanism between the clay mineral and the proteins. For low BLG concentration, a slight increase of the interlayer spacing of the clay mineral was noticed as well as structural changes of the protein. In contrast, as the concentration of BLG increased, the adsorption led to a…
Disentangling the Role of Chain Conformation on the Mechanics of Polymer Tethered Particle Materials
2019
[Image: see text] The linear elastic properties of isotropic materials of polymer tethered nanoparticles (NPs) are evaluated using noncontact Brillouin light spectroscopy. While the mechanical properties of dense brush materials follow predicted trends with NP composition, a surprising increase in elastic moduli is observed in the case of sparsely grafted particle systems at approximately equal NP filling ratio. Complementary molecular dynamics simulations reveal that the stiffening is caused by the coil-like conformations of the grafted chains, which lead to stronger polymer–polymer interactions compared to densely grafted NPs with short chains. Our results point to novel opportunities to …
Nanoclays for Conservation
2019
Within the conservation of artworks materials, this chapter describes innovative strategies based on clay nanoparticles that are promising for protective coating, surface cleaning, and consolidation. We present the preparation of polymer/montmorillonite nanocomposites, which are revealed as efficient protective coatings for highly porous stones, marbles, and bread-made artifacts. Anticorrosive films for metal substrates have been obtained by polymer filling with laponite and halloysite nanotubes (HNTs) containing corrosion inhibitors into their lumen. The dispersion of hydrophobically modified HNTs into chitosan matrix drives to fabricate biofilms with surface cleaning capacity. Rust stains…
A Fractional-Order Model of Biopolyester Containing Naturally Occurring Compounds for Soil Stabilization
2019
Currently, the use of polymers and biopolymers as soil-stabilizer additives for control of the soil degradation, deterioration, and desertification and for improving the arid and semiarid soils has been expanded significantly in the agricultural sector. This research was conducted to determine the effect of naturally occurring compounds, such as quercetin (Q) and sodium montmorillonite (NaMMt) at different weight ratios, in biopolyester, such as polylactic acid (PLA), aiming to formulate ecosustainable materials to control the soil degradation and to protect the environment. As known, the use of sophisticated analytical tools to describe the material rheology and melting properties is nowad…
Morphology, rheology, and mechanical properties of a new nanobiocomposite
2015
Nanobiocomposites are a new class of biodegradable polymer materials with an ultrafine phase dispersion of the order of a few nanometers in a biodegradable polymer matrix that shows very interesting properties often very different from those of conventional filled polymers. In this work the morphology and the rheological and mechanical properties of a new nanobiocomposite made of a biodegradable copolyester based blend with an organomodified montmorillonite have been investigated to evaluate its possible use in several applications. SAXS diffractograms and TEM micrographs show that the in both the adopted processing conditions an hybrid intercalated/exfoliated morphology is observed. Rheolo…
Rapeseed oil-based rigid polyisocyanurate foams modified with nanoparticles of various type
2014
Polyisocyanurate foams have been developed using a polyol system partially derived from rapeseed oil (RO). The effect of nanofillers with iso-dimensional geometry (zinc oxide), nanofibers (carbon nanotubes), and nanoplatelets (organically modified montmorillonite) on stiffness and strength of the foams has been studied. It was demonstrated that the tensile properties of the filled foams are enhanced by roughly the same proportion as the stiffness and strength of monolithic filled polymers.
Synthesis and Characterization of the Hybrid Clay-Based Material Montmorillonite-Melanoidin: A Potential Soil Model
2010
The study of the interactions among metals, minerals, and humic substances is essential in understanding the migration of inorganic pollutants in the geosphere. A considerable amount of organic matter in the environment is associated with clay minerals. To understand the role of organic matter in the environment and its association with clay minerals, a hybrid clay-based material (HCM), montmorillonite (STx-1)-melanoidin, was prepared from L-tyrosine and L-glutamic acid by the Maillard reaction. The HCM was characterized by elemental analysis, nuclear magnetic resonance, x-ray photoelectron spectroscopy (XPS), scanning transmission x-ray microscopy (STXM), and thermal analysis. The presence…
Partial Discharge Tests Using CIGRE Method II Upon Nanocomposite Epoxy Resins
2007
Nanocomposite polymers are becoming a new family of dielectric materials with promising insulating properties. In order to apply this technology to insulation systems, a study about the material longterm endurance (life) is needed. In this paper results from comparative life tests performed upon base and nanostructured epoxy resin samples are presented. The nanofiller is a organophillic-modified ultra-clean montmorillonite. Specimens were subjected to ageing under surface discharge phenomena using a standard electrode configuration, that is the CIGRE method II. Life data and partial discharge phase resolved patterns, acquired during time under stress, are presented and commented, in order t…