Search results for "ROM"
showing 10 items of 37506 documents
Synthesis, crystal structure and magnetic properties of the cyclic tetranuclear compound [Cu4(pz)4(hppa)2(H2O)4] [pz = pyrazolate; hppa = R,S-2-hydro…
2019
Abstract The synthesis, X-ray structure and magnetic properties of the neutral tetranuclear copper(II) complex of formula [Cu4(pz)4(hppa)2(H2O)4] (1) [Hpz = pyrazole and hppa = R,S-2-hydroxo-2-phenyl-2-(1-pyrazolyl)acetate] are reported. Remarkably, the structure of 1 reveals the presence of the S- and R-forms of the new hppa ligand which is formed in situ in the complex reaction between copper(II), pyrazole and phenylmalonate in water:methanol solvent mixture under ambient conditions. The two crystallographically independent copper(II) ions [Cu(1)/Cu(2)] are five-coordinate in square pyramidal surroundings. Three nitrogen atoms, from two pz groups and one hppa ligand and one oxygen atom of…
Analysis of salivary detection of P16INK4A and RASSF1A promoter gene methylation and its association with oral squamous cell carcinoma in a Colombian…
2019
Background Epigenetic factors play a fundamental role in the etiopathogenesis of oral squamous cell carcinoma (OSCC). This study evaluated if salivary detection of P16INK4A/RASSF1A gene promoter methylation might be linked to the clinical/histological features of OSCC in a Colombian population. Material and Methods Methylation-specific polymerase chain reaction (MSP-PCR) was used to detect the methylation frequency of P16INK4A/RASSF1A genes in DNA obtained from whole saliva collected of 40 healthy controls (HC) and 43 OSCC patients. Determination of the clinical performance of MSP-PCR assay was based on standard algorithms derived from two-way contingency table analysis. The association of …
Dietary and Household Sources of Prenatal Exposure to Polybrominated Diphenyl Ethers (PBDEs) in the INMA Birth Cohort (Spain)
2016
This study looked at predictors of exposure to polybrominated diphenyl ethers (PBDEs) with a focus on dietary and household-level factors. Concentrations of BDE-47, -99, -153, and -209 and their sum (∑PBDEs) were measured in cord serum. Spanish women (n = 541) completed two semiquantitative food frequency questionnaires during the first and third trimesters of pregnancy. The daily mean intake (grams) of eggs, dairy products, meat, cereals and pasta, vegetables and pulses, fruits, shellfish and cephalopods, and fish, and the weekly mean intake (servings) of lean, large oily, other oily, and other fish from both questionnaires were averaged. Information on house size, curtains and carpets at …
Analysis of psychoactive substances in water by information dependent acquisition on a hybrid quadrupole time-of-flight mass spectrometer.
2016
Emerging drugs of abuse, belonging to many different chemical classes, are attracting users with promises of “legal” highs and easy access via internet. Prevalence of their consumption and abuse through wastewater-based epidemiology can only be realized if a suitable analytical screening procedure exists to detect and quantify them in water. Solid-phase extraction and ultra-high performance liquid chromatography quadrupole time-of-flight-mass spectrometry (UHPLC–QqTOF–MS/MS) was applied for rapid suspect screening as well as for the quantitative determination of 42 illicit drugs and metabolites in water. Using this platform, we were able to identify amphetamines, tryptamines, piperazines, p…
Volcanic structures investigation through SAR and seismic interferometric methods: The 2011-2013 Campi Flegrei unrest episode
2019
Observations from satellites provide high-resolution images of ground deformation allowing to infer deformation sources by developing advanced modeling of magma ascent and intrusion processes. Nevertheless, such models can be strongly biased without a precise model of the internal structure of the volcano. In this study, we jointly exploited two interferometric techniques to interpret the 2011–2013 unrest at Campi Flegrei caldera (CFc). The first is the Interferometric Synthetic Aperture Radar (InSAR) technique, which provides highly-resolved spatial and temporal images of ground deformation. The second is the Ambient Noise Tomography (ANT), which images subsurface structures, providing the…
New advances in dial-lidar-based remote sensing of the volcanic CO2 flux
2017
We report here on the results of a proof-of-concept study aimed at remotely sensing the volcanic CO2 flux using a Differential Adsorption lidar (DIAL-lidar). The observations we report on were conducted on June 2014 on Stromboli volcano, where our lidar (LIght Detection And Ranging) was used to scan the volcanic plume from ~ 3 km distance from the summit vents. The obtained results prove that a remotely operating lidar can resolve a volcanic CO2 signal of a few tens of ppm (in excess to background air) over km-long optical paths. We combine these results with independent estimates of plume transport speed (from processing of UV Camera images) to derive volcanic CO2 flux time-series of ≈16-3…
Using scintillometry to assess reference evapotranspiration methods and their impact on the water balance of olive groves
2016
Abstract Reference evapotranspiration (ET 0 ) is widely used for irrigation scheduling, to promote an efficient use of water resources for a sustainable agro-ecosystem productivity, as well as to manage water quality and to face other environmental concerns. As suggested by ASCE-EWRI and FAO, standard Penman–Monteith methods are generally applied for an accurate estimation of ET 0 from hourly to daily scale. In absence of detailed meteorological information several simplified equations, using a limited number of variables, have been proposed as alternative. In this paper, the performance of different reference evapotranspiration methods, at hourly (Penman–Monteith, Pristley–Taylor, Makkink …
The BepiColombo MORE gravimetry and rotation experiments with the ORBIT14 software
2016
The BepiColombo mission to Mercury is an ESA/JAXA cornerstone mission, consisting of two spacecraft in orbit around Mercury addressing several scientific issues. One spacecraft is the Mercury Planetary Orbiter, with full instrumentation to perform radio science experiments. Very precise radio tracking from Earth, on-board accelerometer and optical measurements will provide large data sets. From these it will be possible to study the global gravity field of Mercury and its tidal variations, its rotation state and the orbit of its centre of mass. With the gravity field and rotation state, it is possible to constrain the internal structure of the planet. With the orbit of Mercury, it is possib…
Lidar sounding of volcanic plumes
2013
ABSTRACT Accurate knowledge of gas composition in volcanic plumes has high scientific and societal value. On the one hand, it gives information on the geophysical processes taking place inside volcanos; on the other hand, it provides alert on possible eruptions. For this reasons, it has been suggested to monitor volcanic plumes by lidar. In particular, one of the aims of the FP7 ERC project BRIDGE is the measurement of CO 2 concentration in volcanic gases by differential absorption lidar. This is a very challenging task due to the harsh environment, the narrowness and weakness of the CO 2 absorption lines and the difficulty to procure a suitable laser source. This paper, after a review on r…
Validation of the Sentinel-3 Ocean and Land Colour Instrument (OLCI) Terrestrial Chlorophyll Index (OTCI): Synergetic Exploitation of the Sentinel-2 …
2018
Continuity to the Medium Resolution Imaging Spectrometer (MERIS) Terrestrial Chlorophyll Index (MTCI) will be provided by the Sentinel-3 Ocean and Land Colour Instrument (OLCI), and to ensure its utility in a wide range of operational applications, validation efforts are required. In the past, these activities have been constrained by the need for costly airborne hyperspectral data acquisition, but the Sentinel-2 Multispectral Instrument (MSI) now offers a promising alternative. In this paper, we explore the synergetic use of Sentinel-2 MSI data for validation of the Sentinel-3 OLCI Terrestrial Chlorophyll Index (OTCI) over the Valencia Anchor Station, a large agricultural site in the Valen…