Search results for "ROTATIONAL"
showing 10 items of 381 documents
Drops of3Heatoms with good angular-momentum quantum numbers
2000
The stability of drops made of ${}^{3}\mathrm{He}$ atoms is studied by means of a Monte Carlo variational method using wave functions with good angular momentum quantum numbers. The number of constituents considered is in the range 34--40. It is found that the minimal bound drop requires 35 atoms (perhaps 34) and that the preferred wave function must have the maximum spin.
Development of the Hamiltonian and transition moment operators of symmetric top molecules using the O(3)⊃C∞v⊃C3v group chain
2005
Abstract We present a development of the Hamiltonian, dipole moment, and polarizability operators for XY3Z molecules. These rovibrational operators are written with the aid of a tensorial formalism derived from the one already used in Dijon and adapted to the XY3Z symmetric tops in a recent paper [A. El Hilali, V. Boudon, M. Loete, J. Mol. Spectrosc. 234 (2005) 166–174]. We use the O (3) ⊃ C∞v ⊃ C3v group chain. Expressions for the matrix elements are derived for these operators.
Spectroscopy of XY5Z (C4v) Molecules: Development of the Hamiltonian and the Transition Moment Operators Using a Tensorial Formalism
2000
We present a development of the Hamiltonian, dipole moment, and polarizability operators of XY(5)Z (C(4v)) molecules using a tensorial formalism derived from the one developed previously in Dijon for XY(6) molecules. These operators are involved in the calculation of the energies and intensities of rovibrational transitions and are essential for spectrum simulations. Expressions for the matrix elements are derived for all these operators. Copyright 2000 Academic Press.
Squeezing induced by spontaneous rotational symmetry breaking
2009
In this communication we study in depth the phenomenon of quadrature squeezing generated via spontaneous rotational symmetry breaking discussed for the first time in [1]. The idea can be put in short as follows. Consider a degenerate optical parametric oscillator (DOPO) tuned to the first family of transverse modes at the signal frequency, and having perfectly spherical mirrors. When pumped above threshold with a Gaussian beam and within a classical description, it is easy to show that a TEM 10 mode with an arbitrary orientation (measured by θ at Fig. 1) emerges at the subharmonic, hence breaking the rotational symmetry of the system in the transverse plane. Quantum effects are then quite i…
The Influence of Particular Modes of Vibration
1986
When vibration stress occurs at the place of work, 1, 2, or 3 directions of the coordinate system related to man, or vectors of these axes, can be involved (Fig. 1). In such multiaxial vibration, the stress may predominate in one direction or may have similar magnitudes in all directions. In addition, rotational vibration about these axes may also take place (see section “Rotational Vibration,” p. 125).
A local picture associated with a triply degenerate vibrational mode: vibrational and rovibrational local states
1998
International audience; Abstract: A symmetrized basis adapted to the study of some vibrational excited states of spherical top molecules is proposed. This basis, consistent with the Cartesian picture associated with a three-dimensional mode, is then tested numerically through various XY6 and XY4 molecules. In addition, some simulations, made with 238UF6 and a simplified version of an effective Hamiltonian, clearly show that the method can be further extended through the construction of a symmetrized local rovibrational basis.
Induction mechanisms in a von Kármán swirling flows of liquid Gallium
2004
International audience; Using in situ magnetic field measurements, we study the induction mechanisms in a swirling flow of liquid Gallium generated inside a cylinder, in the gap between two coaxial rotating discs. The von Kármán flow generated in this manner has both helicity and differential rotation. Magnetic Reynolds numbers Rm up to 7 (based on the disc rim speed) are generated. We study the magnetic induction when an external field is applied successively along the axis, in the azimuthal direction or tranverse to the axis of rotation. In the first two cases, both the flow and the magnetic field are axisymmetric, and an effective mechanism of conversion from poloidal to toroidal field e…
Field-free molecular alignment of CO2 mixtures in presence of collisional relaxation
2008
The present work explores the extension of the concept of short-pulse-induced alignment to dissipative environments within quantum mechanical density matrix formalism (Liouville equation) from the weak to the strong field regime. This is illustrated within the example of the CO2 molecule in mixture with Ar and He, at room temperature, for which a steep decrease of the alignment is observed at moderate pressure because of the collisional relaxation. The field-free alignment is measured by a polarization technique where the degree of alignment is monitored in the time domain by measuring the resulting transient birefringence with a probe pulse Raman induced polarization spectroscopy (RIPS) Co…
Analytical formula for calculating the focal shift in apodized systems
1998
We report a quite simple analytical formula for the evaluation of the focal shift in apodized systems, with or without rotational invariance. Specifically it is shown that the magnitude of the focal shift is determined by the product of the Fresnel number of the focusing geometry and the standard deviation of a mapped version of the azimuthal average of the pupil transmittance. To illustrate our approach, several examples are examined.
Rotational Doppler Frequency Shift from Time‐Evolving High‐Order Pancharatnam–Berry Phase: A Metasurface Approach
2021
The Doppler frequency shift of sound or electromagnetic waves has been widely investigated in many different contexts and, nowadays, represents a formidable tool in medicine, engineering, astrophysics, and optics. Such effect is commonly described in the framework of the universal energy-momentum conservation law. In particular, the rotational Doppler effect has been recently demonstrated using light carrying orbital angular momentum. When a wave undergoes a cyclic adiabatic transformation of its Hamiltonian, it is known to acquire the so-called Pancharatnam–Berry (PB) phase. In this work, an experimental evidence of the direct connection between the high-order PB phase time evolution on th…