Search results for "ROTATIONAL"

Ultrafast optics in coherently spinning molecules

2020

This thesis reports on the study of unidirectional rotation of molecules and focuses on the rotational Doppler effect occuring in the course of third-harmonic generation in coherently spinning molecules.The rotational Doppler effect appears when a circularly polarized wave interacts with an anisotropic rotating object. During the interaction, an exchange of angular momentum and energy between the field and the object occurs, leading to a frequency shift of the wave. In this work, the frequency shift of the third-harmonic generated in unidirectionaly rotating molecules has been observed. An anlytical model developped in the mansucript forsees four kinds of frequency shifts depending on the m…

Stratégies de contrôle pour la manipulation spatiale de molécules

2011

Talk given by E. Hertz; National audience

On the moving load problem in beam structures equipped with tuned mass dampers

2017

This paper proposes an original and efficient approach to the moving load problem on Euler–Bernoulli beams, with Kelvin–Voigt viscoelastic translational supports and rotational joints, and in addition, equipped with Kelvin–Voigt viscoelastic tuned mass dampers (TMDs). While supports are taken as representative of external devices such as grounded dampers or in-span supports with flexibility and damping, the rotational joints may model rotational dampers or connections with flexibility and damping arising from imperfections or damage. The theory of generalised functions is used to treat the discontinuities of the response variables, which involves deriving exact complex eigenvalues and eigen…

Slope instability in a historical and architectural interest site: the Agrigento hill (Sicily-Italy)

2014

Improved centrifugal and hyperfine analysis of ND2H and NH2D and its application to the spectral line survey of L1544

2021

Abstract Quantifying molecular abundances of astrochemical species is a key step towards the understanding of the chemistry occurring in the interstellar medium. This process requires a profound knowledge of the molecular energy levels, including their structure resulting from weak interactions between nuclear spins and the molecular rotation. With the aim of increasing the quality of spectral line catalogs for the singly- and doubly-deuterated ammonia (NH2D and ND2H), we have revised their rotational spectra by observing many hyperfine-resolved lines and more accurate high-frequency transitions. The measurements have been performed in the submillimeter-wave region (265–1565 GHz) using a fr…

Collisional shifting and broadening coefficients for the rovibrational anisotropic S(J) lines of nitrogen studied by inverse Raman spectroscopy

1996

0377-0486; Line shifting and broadening coefficients of the anisotropic S(J) lines (v = 0, J --> v = 1, J + 2) of the nitrogen molecule were measured at room temperature using high-resolution stimulated Raman spectroscopy. A rotational quantum number dependence of the S(J) line shifts was observed. In order to avoid an asymmetry of experimental origin, a suitable theoretical profile was fitted to the experimental lineshapes. This study allows the testing of the theoretical methods for calculating the line broadening coefficients in anisotropic Raman scattering, which have already been used in the analysis of infrared absorption data. The behaviour of the modified sum rule and the RPA (rando…

Determination of Temperature by Stimulated Raman Scattering of Molecular Nitrogen, Oxygen, and Carbon-Dioxide

1993

0721-7269; We have determined the temperature from SRS spectra of N2-N2, N2-CO2, O2-O2, and CO2-CO2 recorded in wide pressure and temperature ranges. The fitting procedure takes simultaneously into account the Dicke effect and motional narrowing. We have quantified the accuracy of the MEG and ECS-P models for rotational relaxation. The temperature extracted from each model is compared with thermocouple measurements. The influence of vibrational broadening and shifting is discussed in detail.

Seismogenic rotational slumps and translational glides in pelagic deep-water carbonates. Upper Tithonian-Berriasian of Southern Tethyan margin (W Sic…

2017

Abstract Soft-sediment deformation structures (SSDSs), which reflect sediment mobilization processes, are helpful to identify punctual events of paleoenvironmental stresses. In the upper Tithonian-Berriasian calpionellid pelagic limestone of the Lattimusa Fm. outcropping in the Barracu section (W Sicily), paleoenvironmental restoration reveals the occurrence of a deep-water flat basin, characterised by undeformed planar bedding, laterally passing to a gentle slope where the deformed horizons alternate with undeformed beds. Here, two types of gravity slides have been differentiated on the basis of different kinds of SSDSs, brittle deformation, involved lithofacies, geometry and morphology. T…

Heterogeneity at the Glass Transition:  Translational and Rotational Self-Diffusion

1997

Self-diffusion coefficients, D, have been measured in the glass forming liquids salol, glycerol, phenolphthaleine dimethyl ether (PDE), cresolphthaleine dimethyl ether (CDE), and ααβ-trinaphthylbenzene (TNB) in the supercooled regime. The NMR static magnetic field gradient technique was applied where D >10-14 m2 s-1 can be attained. The results are similar to previous diffusion experiments where an enhancement of translational diffusion was found in comparison with rotational diffusion and shear viscosity. Various models of spatial heterogeneity are related to a phenomenological environmental fluctuation model in view of recent diffusion and relaxation data close to the glass transition.

Rubber Forming Processes of Thin Sheets

1999

In the last decade flexible media have been increasingly utilized in sheet metal drawing processes in order to reduce the tooling cost and to improve the product quality. In the present paper an axisymmetric deep drawing process of thin steel sheets is taken into account: in particular a flexible pad is utilized in order to simplify the tooling set. The process mechanics is investigated through numerical simulations and experimental tests with the aim to find out a proper set of operative parameters allowing the stamping of sound components and to highlight the particular deformation path of the drawing cup. The comparison between the numerical predictions and the experimental verification …