Search results for "ROUGE"
showing 10 items of 60 documents
Study of the hydrolysis of lithium hydride
2015
The hydrolysis of LiH at room temperature and under low water vapor pressure (PH2O < 10 hPa) is investigated by thermogravimetry and FTIR spectroscopy with low sample mass. Then, to be closer to industrial conditions, hydrolysis of LiH is studied by manometry either in closed (adjustable PH2O) or open (constant PH2O) system using larger amounts of sample and heavy water. Products of the reaction are characterized by X-ray diffraction and FTIR spectroscopy. The first set of experiments show that the mechanism of hydrolysis starts with the formation of lithium oxide Li2O. Then, when the oxide layer is sufficiently thick, the hydrolysis reaction is followed by the formation of lithium hydroxid…
Quantification des Brettanomyces par qPCR
2017
International audience; Brettanomyces bruxellensis est une levure d’altération du vin avec de faibles besoins nutritionnels, résistante à l’éthanol et aux faibles pH, lui permettant une implantation en vin durant ou après la fermentation alcoolique (Conterno et al., 2006). B. bruxellensis est capable de produire des phénols volatils (éthyl-4-phénol, éthyl-4-gaïacol et éthyl-4-catéchol) (Oelofse et al., 2008). Ces molécules volatiles odorantes amènent un caractère phénolé et animal au vin connu sous le nom de « caractère Brett ». D’autres molécules (2-acétyltétrahydropyridine et 2-éthyltétrahydropyridine) produites par B. bruxellensis sont également responsables d’une déviation organoleptiqu…
Te-As-Se glass microstructured optical fiber for the middle infrared
2009
International audience; We present the first fabrication, to the best of our knowledge, of chalcogenide microstructured optical fibers in Te-As-Se glass, their optical characterization, and numerical simulations in the middle infrared. In a first fiber, numerical simulations exhibit a single-mode behavior at 3.39 and 9.3 μm, in good agreement with experimental near-field captures at 9.3 μm. The second fiber is not monomode between 3.39 and 9.3 μm, but the fundamental losses are 9 dB/m at 3:39 μm and 6 dB/m at 9.3 μm. The experimental mode field diameters are compared to the theoretical ones with a good accordance.
Fourth-order cascaded Raman shift in AsSe chalcogenide suspended-core fiber pumped at 2 μm
2011
International audience; Cascaded Raman wavelength shifting up to the fourth order ranging from 2092 to 2450nm is demonstrated using a nanosecond pump at 1995nm in a low-loss As38Se62 suspended-core microstructured fiber. These four Stokes shifts are obtained with a low peak power of 11W, and only 3W are required to obtain three shifts. The Raman gain coefficient for the fiber is estimated to (1.6 +-0.5)x 10e−11 m/W at 1995nm. The positions and the amplitudes of the Raman peaks are well reproduced by the numerical simulations of the nonlinear propagation.
Identification of markers that can be recognised using spectroscopic sensors and which reflect key stages in the cooking of meat and fish
2016
One of the purposes of the Opticook project is to install spectroscopic sensors in ovens, so equipping them with non intrusive tools allowing following cooking process of meat and fish. The hypothesis on which sensors were developed was: are muscular proteins proper probes to discriminate among several cooking degrees? Thus, at the beginning of the project several tools were used to characterise effect of several cooking degrees on macroscopic properties (texture and colour) of beef, chicken and cod fillet samples. Following, calorimetry and spectroscopic techniques were used to study transformations at molecular scale. In particular, visible spectroscopy followed denaturation of haemprotei…
Suspended core tellurite glass optical fibers for infrared supercontinuum generation
2011
International audience; We report the fabrication and characterization of tellurite TeO(2)-ZnO-Na(2)O (TZN) microstructured suspended core optical fibers (MOFs). These fibers are designed for infrared supercontinuum generation with zero dispersion wavelength (ZDW) at 1.451 mu m. The measured losses at this wavelength are approximately 6 dB/m for a MOF with a 2.2 mu m diameter core. The effective area of a particular fiber is 3.5 mu m(2) and the nonlinear coefficient is calculated to be 437 W(-1)km(-1). By pumping a 20 cm long fiber at 1.56 mu m with a sub-nj femtosecond laser source, we generate a supercontinuum (SC) spanning over 800 nm in the 1-2 mu m wavelength range.
Tellurites fibers for infrared supercontinuum sources : opto-geometric profiles and extrinsic absorptions management
2016
This PhD thesis work focuses on the synthesis and purification of vitreous materials used for the development of waveguides with varied profiles, dedicated to supercontinuum (SC) generation between 1 and 5 μm.Concerning the purification of tellurite glasses, several leads were followed, but best results are obtained for the purification of the TeO2-ZnO-Na2O glassy system by the means of zinc fluoride. Attenuation measurements performed on several meter-long single-index fiber samples reveal the nearly complete elimination of water-related absorptions between 3 and 4 μm (OH ions concentration lower than 1 ppm mass.). Such water-purified glasses were firstly dedicated to microstructured optic…
chalcogenide materials for nonlinear integreted optics in mid-infrared
2019
Elaboration and characterization of new compositions of chalcogenide materials exhibiting nonlinear effects for integrated optic applications and fabrication of low-loss waveguides.
Development of functionalizable azaBODIPYs for the conception of theranostic agents and bimodal probes for imaging uses
2020
The in vivo use of optical imaging is still limited by the lack of near infrared emitting probes. This thesis work focuses on the optimization and valorization of a water-soluble fluorescent platform whose optical properties enable an in vivo use. Two distinct applications were investigated for this WazaBY (Water-soluble azaBODIPY) platform: use as a PET (or SPECT) / optical bimodal probe, and as a theranostic agent. Concerning the first project, we were able to develop a targetted SPECT/optical bimodal probe, which was radiometallated with indium 111. Using xenografted murine models, we were able to show a clear accumulation of the probe in the tumor 24 hours after injection. Moreover, the…
Contribution to the study and to the optimization of active thermographic process applied to surface crack detection
2017
The aim of this work is the detection of open and subjacent defects in metallic materials using laser-material interaction coupled with infrared thermography. This process is a possible alternative for magnetic particles testing and dye penetrant testing in the field of non-destructive testing. This work is divided into three main parties. At first, we have been interested in the characterization of optical and thermophysical properties of materials we used, in order to have good boundary conditions and also for the needs of temperatures fields measurements for validation. The second part concern the development of a numerical simulation model with two step approach: the first involves mode…