Search results for "RSE"
showing 10 items of 11150 documents
Políticas de acceso abierto a la ciencia en las universidades españolas
2013
El objetivo del artículo es analizar el estado de la cuestión de las políticas en favor del acceso abierto (OA) a la ciencia en las universidades españolas. Para ello se han establecido cinco grandes mecanismos de intervención (la creación de infraestructuras y prestación de servicios, la comunicación y difusión, la incentivación económica, la coordinación institucional así como la reglamentación u obligación) que permiten llevar a cabo políticas a favor del acceso abierto y que hemos utilizado para el análisis y la valoración de la situación. La recogida de datos se ha basado en un cuestionario enviado a los vice-rectores de investigación y se ha complementado con la consulta de directorio…
A Hard X-Ray View of Scorpius X-1 with INTEGRAL : Nonthermal Emission?
2006
We present here simultaneous INTEGRAL/RXTE observations of Sco X-1, and in particular a study of the hard X-ray emission of the source and its correlation with the position in the Z-track of the X-ray color-color diagram. We find that the hard X-ray (above about 30 keV) emission of Sco X-1 is dominated by a power-law component with a photon index of ~3. The flux in the power-law component slightly decreases when the source moves in the color-color diagram in the sense of increasing inferred mass accretion rate from the horizontal branch to the normal branch/flaring branch vertex. It becomes not significantly detectable in the flaring branch, where its flux has decreased by about an order of…
Accrétion et éjection dans les systèmes binaires X transitoires à trous noirs : le cas de GRS 1716-249
2020
I buchi neri transienti (BHT) sono tra le sorgenti con emissione ai raggi X più luminose della galassia. Grazie all’elevato flusso in banda X e alla loro alta variabilità temporale. queste sorgenti offrono un’opportunità unica per studiare la fisica dell’accrescimento in straordinareie condizioni fisiche. I BHT mostrano episodici outburst caratterizzati da diverse luminosità in banda X e γ, diverse forme spettrali e proprietà della variabilità temporale. L’obiettivo di questa tesi è lo studio della geometria, dei meccanismi e dei processi fisici coinvolti nell’emissione del buco nero transiente GRS 716-249. Di seguito presento l’analisi spettrale e temporale delle osservazioni della GRS 171…
Gaia -ESO Survey: Analysis of pre-main sequence stellar spectra
2015
This paper describes the analysis of UVES and GIRAFFE spectra acquired by the Gaia-ESO Public Spectroscopic Survey in the fields of young clusters whose population includes pre-main sequence (PMS) stars. Both methods that have been extensively used in the past and new ones developed in the contest of the Gaia-ESO survey enterprise are available and used. The internal precision of these quantities is estimated by inter-comparing the results obtained by such different methods, while the accuracy is estimated by comparison with independent external data, like effective temperature and surface gravity derived from angular diameter measurements, on a sample of benchmarks stars. Specific strategi…
Quantitative evaluation of the phenolic profile in fruits of six avocado (Persea americana) cultivars by ultra-high-performance liquid chromatography…
2016
The phenolic profiles of six varieties of avocado (Persea americana) grown in Sicily were investigated. The ultra-high-performance liquid chromatography-heated electrospray-mass spectrometry method was developed to determine qualitative and quantitative changes in fruits at two different ripening stage. Nineteen individual phenolic compounds were detected in avocado pulp extracts. Gallic acid, sinapinic acid, vanillin, p-coumaric acid, and gentisic acid were present only in ripe fruits. On the contrary, epicatechin decreased with fruit ripening, whereas protocatechuic acid, 4-hydroxybenzoic acid, chlorogenic acid, and benzoic acid were relatively stable or exhibited erratic changes with fru…
Accélération de la convergence et algorithme proximal
1995
Nous faisons une première étude de la question de savoir s'il est possible d'accélérer des suites issues de l'algorithme proximal ou de la méthode de l'inverse partiel par des méthodes d'extrapolation.
Effect of short-chain alcohols on surfactant-mediated reversed-phase liquid chromatographic systems.
2010
The behaviour of β-blockers in a reversed-phase liquid chromatographic (RPLC) column with mobile phases containing a short-chain alcohol (methanol, ethanol or 1-propanol), with and without the surfactant sodium dodecyl sulphate (SDS), was explored. Two surfactant-mediated RPLC modes were studied, where the mobile phases contained either micelles or only surfactant monomers at high concentration. Acetonitrile was also considered for comparison purposes. A correlation was found between the effects of the organic solvent on micelle formation (monitored by the drop weight procedure) and on the nature of the chromatographic system (as revealed by the retention, elution strength and peak shape of…
Submicellar and micellar reversed-phase liquid chromatographic modes applied to the separation of beta-blockers.
2009
The behaviour of a reversed-phase liquid chromatographic (RPLC) system (i.e. elution order, resolution and analysis time), used in the analysis of β-blockers with acetonitrile-water mobile phases, changes drastically upon addition of an anionic surfactant (sodium dodecyl sulphate, SDS). Surfactant monomers cover the alkyl-bonded phase in different extent depending on the concentration of both modifiers, in the ranges 1 × 10-3-0.15 M SDS and 5-50% acetonitrile. Meanwhile, the surfactant is dissolved in the mobile phase as free monomers, associated in small clusters or forming micelles. Four characteristic RPLC modes are yielded, with transition regions between them: hydro-organic, micellar, …
Performance of different C18 columns in reversed-phase liquid chromatography with hydro-organic and micellar-organic mobile phases
2014
Column selection in reversed-phase liquid chromatography (RPLC) can become a challenge if the target compounds interact with the silica-based packing. One of such interactions is the attraction of cationic solutes to the free silanols in silica-based columns, which is a slow sorption-desorption interaction process that gives rise to tailed and broad peaks. The effect of silanols is minimised by the addition of a competing agent in the mobile phase, such as the anionic surfactant sodium dodecyl sulphate (SDS). In micellar-organic RPLC, the adsorption of an approximately fixed amount of SDS monomers gives rise to a stable modified stationary phase, with properties remarkably different from th…
Comparative study of solvation parameter models accounting the effects of mobile phase composition in reversed-phase liquid chromatography
2007
Solvation parameter models relate linearly compound properties with five fundamental solute descriptors (excess molar refraction, dipolarity/polarizability, effective hydrogen-bond acidity and basicity, and McGowan volume). These models are widely used, due to the availability of protocols to obtain the descriptors, good performance, and general applicability. Several approaches to predict retention in reversed-phase liquid chromatography (RPLC) as a function of these descriptors and mobile phase composition are compared, assaying the performance with a set of 146 organic compounds of diverse nature, eluted with acetonitrile and methanol. The approaches are classified in two groups: those t…