Search results for "Radiation"
showing 10 items of 5298 documents
Temperature dependence of the absorption properties of silanol groups in amorphous : Are silanol groups organized in clusters?
2011
Abstract We present a study on the vacuum-ultraviolet (VUV) and infrared (IR) absorption of silanol groups in amorphous silicon dioxide ( a - SiO 2 ) in the range of temperature from 4 to 300 K. The observed temperature induced modifications of IR and VUV absorption spectra are interpreted as due to a process of conversion of free into H-bonded silanol groups. The changes of the amplitude of the VUV absorption spectra are shown to be linearly correlated to the changes of the IR absorption of free Si–OH groups. This point together with the evidence that the shape of the Si–OH VUV absorption does not depend on temperature demonstrates that the different silanol group sub-species have differen…
Absorption band at 7.6 eV induced by γ-irradiation in silica glasses
2001
Optical absorption of defects induced by γ-irradiation in both natural and synthetic silica is experimentally investigated in the vacuum-ultraviolet (UV) range. Our results show that γ-rays, in a dose range of 1000 Mrad, induce an absorption band centered at 7.6 eV, the so-called E band, whose growth kinetics is not related to γ-activated precursors but to defects of the glassy matrix directly induced via the breaking of Si–O bonds occurring under γ-irradiation. Moreover, we observe that γ-rays do not bleach the E band present in some silica samples before irradiation, so ruling out that the associated defects can be precursors of the paramagnetic E′ centers, also induced by γ-irradiation.
Electronic effects in the production of smali dianionic gold clusters by electron attachment on to stored Au-n, n = 12-28
1999
Abstract Single charged gold clusters Au n -, 12 n 28, are stored in a Penning trap, size selected and transformed into dianions, Au2- n by the application of an electron beam. At the onset of dianion production, that is that range of cluster sizes n where the smallest doubly charged clusters are observed, the measured intensity ratio of the dianions to their precursors is not a continuous function of cluster size. Instead, there is a strong odd-even effect and a comparatively intense signal of Au2-18 The observed structures are very reminiscent of similar phenomena in the abundance spectra of metal clusters as observed by Knight et al. (1984, Phys. Rev. Lett., 52, 2141), which gave ris…
Selective quantification of humidity and ammonia by optical excitation of molecular semiconductor-doped insulator (MSDI) sensors
2015
MSDI (molecular semiconductor-doped insulator) ammonia sensors have been investigated using cyclic optical excitation as multi-signal generation method. This method enables a selective quantification of both humidity in the range of 30–70 %rh and ammonia concentration in the range of 0–30 ppm with a single sensor at room temperature.
Electronic coupling responsible for energy transfer in columnar liquid crystals
1999
Electronic coupling is the driving force for energy transfer in molecular materials and consists of several components. We determine the strength of dipolarrmultipolar coupling and coupling due to orbital overlap for excitation transport in triphenylene columnar liquid crystals. We use time-resolved fluorescence spectroscopy and computer simulations. The fit of the experimental and simulated fluorescence decays reveals that the transfer process is dominated by short range interactions .multipolar and orbital overlap but the contribution of long range dipolar interactions cannot be neglected. q 1999 Elsevier Science B.V. All rights reserved.
Evaluation of multiple-scattering contribution in extended X-ray absorption fine structure for MO4 and MO6 clusters
1994
Abstract We present a theoretical ab initio evaluation of the multiple-scattering contribution in the extended X-ray absorption fine structure for MO4 and MO6 clusters with M = Mg, Ca, Mn, Zn, Se, Sr, Mo, Ag, Te, Ba, Nd, Tb, W, Au or Bi. The dependence of the multiple-scattering signal on the absorber type, the photoelectron angular momentum and the local distortion is discussed. It is shown that the multiple-scattering contribution is significant in the photoelectron wave-vector range up to 6–7 A−1 and strongly depends on both the path geometry and the atomic species involved in the scattering process.
A Universal and Sensitive Method for Gas Chromatographic Determination of Volatile Substrates and Metabolites
1978
The concentration of solutes from aqueous solutions in the μl range is still a problem in gas chromatographic trace analysis (e.g. J.S. Fritz, Acc. Chem. Res. 10, 67, 1977).
Laser driven parametric amplification in the xuv and soft-x-ray spectral range
2011
We present the first experimental realization of a new x-ray laser scheme based on strong-field parametric amplification of high-order harmonic radiation. With a simple semi-classical model, we can identify the most important experimental parameters, the spectral range and the small signal gain in gases. Using a single amplifier stage a small signal gain of 8000 has been obtained in Argon for the spectral range of 40-50 eV, using 350 fs, 7 mJ pulses at 1.05 µm. In Helium, we observed a small signal gain of 280 around 300 eV using 6 fs, 1.5 mJ pulses at 800 nm.
The effect of energy-dependent detector efficiency in electron spectroscopic methods: XPS, AES and DCEMS
1993
Systematic studies were performed to investigate the distorting effect of the electron energy dependence of the channeltron detector efficiency on the shape of data distributions in electron spectroscopy. In agreement with earlier results for electron energies up to 3 keV, it was found that a virtually energy-independent shape of the electron distribution might be achieved even in a very broad range of electgron energies (up to 15 keV) by appropriate selection of the operational high voltage of a channeltron. However, the efficieny of channeltrons was also found to depend on count rates, indicating one of the principal difficulties in comparing distribution recorded under different experime…
Nonlinear refraction and absorption of spectrally tuneable picosecond pulses in carbon disulfide
2021
Abstract We analyze the spectral dependence of the nonlinear refractive index and nonlinear absorption coefficient of carbon disulfide (CS2) in the spectral range of 400–1100 nm using picosecond laser pulses. An increase of the nonlinear refractive index of CS2 at the shorter wavelength region compared with the near infrared region (9 × 10−14 cm2 W−1 (λ = 700 nm) and 4 × 10−14 cm2 W−1 (λ = 1000 nm), respectively) follows by a decrease of this parameter at the wavelengths below 600 nm. We compare the spectral dependences of the lower- and higher-order nonlinear absorption coefficients in carbon disulfide. The three-photon absorption coefficient was found to be maximal at λ = 1000 nm (β3PA = …