Search results for "Radical"
showing 10 items of 1401 documents
Papel de los radicales libres en el ejercicio físico agotador. Efecto de la administración de antioxidantes
2004
RESUMEN Desde hace algunos años es conocido que el ejercicio físico regular y no agotador tiene efectos beneficiosos. Se sabe que es importante en el tratamiento de la diabetes mellitus o la cardiopatía isquémica, que mejora el perfil lipídico del plasma, y puede ayudar a perder peso. Sin embargo los beneficios del ejercicio desaparecen con el agotamiento y la falta de entrenamiento. Durante el ejercicio físico agotador se genera tal cantidad de especies reactivas del oxígeno (ERO) que las defensas antioxidantes se ven incapaces de prevenir el daño que éstas inducen. Sin embargo son cada vez más los trabajos que apuntan hacia el papel de las ERO en la señalización celular y en las adaptacio…
Study of Atrp Process for the Grafting of Vinyl Monomers on PVC and PVDF
2014
STUDY OF ATRP PROCESS FOR THE GRAFTING OF VINYL MONOMERS ON PVC AND PVDF Sonia Lanzalaco, Onofrio Scialdone, Alessandro Galia, Rosalia Mauro, Flavia Lazzano Dipartimento di Ingegneria Chimica, Gestionale, Informatica, Meccanica, Viale delle Scienze, Palermo e-mail: sonia.lanzalaco@unipa.it ATRP (atom transfer radical polymerization) has been recently used to prepare graft copolymers with regularly-spaced polymer chains from polymeric macroinitiators that have pendant chemical groups containing radically transferable halogen atoms [1]. The halogen atom serves as initiation site for the polymerization of side chains. Furthermore, Matyjaszewsky and Gennaro showed that an externally applied ele…
Theoretical and experimental studies of some main group compounds : from closed shell interactions to singlet diradicals and stable radicals
2012
Acquiring knowledge of different interactions within and between molecules is a fascinating undertaking as it not only deepens our understanding of chemical bonding but also offers insight into electronic structures, molecular properties and the connections between these two. This dissertation combines together three main group chemistry related topics within the aforementioned theme. Research presented in the first third of this dissertation describes wave function and density functional theory studies of weak inter- and intramolecular interactions in pnictogen-based dimers X3Pn···PnX3 (Pn = N-Bi; X = F-I), dithallenes RTlTlR (R = H, Me, tBu, Ph) and octachalcogen dications Ch82+ (Ch = S, …
Innovation and Ambidexterity
2022
El documento forma parte de los materiales docentes programados mediante la ayuda del Servei de Política Lingüística de la Universitat de València. Análisis comparativo de los conceptos de Innovación y Ambidestreza Comparative Analysis of the Innovation and Ambidexterity Concepts
Paramagnetic aluminium β-diketiminate
2012
The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry. peerReviewed
Changes in the Phytochemical Profile and Antioxidant Properties of Prunus persica Fruits after the Application of a Commercial Biostimulant Based on …
2022
Plant biostimulants are formulations that are experiencing great success from the perspective of sustainable agriculture. In this work, we evaluated the effect derived from the application of a biostimulant based on algae and yeast extracts (Expando®) on the agronomic yield and nutraceutical profile of two different cultivars (“Sugar Time” and “West Rose”) of Prunus persica (peach). Although, at the agronomic level, significant effects on production yields were not recorded, the biostimulant was able to reduce the ripening time, increase the fruit size, and make the number of harvestable fruits homogeneous. From a nutraceutical point of view, our determinations v…
Biochar Particles Obtained from Agricultural Carob Waste as a Suitable Filler for Sustainable Biocomposite Formulations
2022
In the context of sustainable and circular economy, the recovery of biowaste for sustainable biocomposites formulation is a challenging issue. The aim of this work is to give a new life to agricultural carob waste after glucose extraction carried out by a local factory for carob candy production. A pyrolysis process was carried out on bio-waste to produce biofuel and, later, the solid residual fraction of pyrolysis process was used as interesting filler for biocomposites production. In this work, biochar particles (BC) as a pyrolysis product, after fuels recovery of organic biowaste, specifically, pyrolyzed carobs after glucose extraction, were added on poly(butylene-adipate-co-terephthalat…
CCDC 1057507: Experimental Crystal Structure Determination
2015
Related Article: Ian S. Morgan, Akseli Mansikkamäki, Georgia A. Zissimou, Panayiotis A. Koutentis, Mathieu Rouzières, Rodolphe Clérac and Heikki M. Tuononen|2015|Chem.-Eur.J.|21|15843|doi:10.1002/chem.201501343
CCDC 1057506: Experimental Crystal Structure Determination
2015
Related Article: Ian S. Morgan, Akseli Mansikkamäki, Georgia A. Zissimou, Panayiotis A. Koutentis, Mathieu Rouzières, Rodolphe Clérac and Heikki M. Tuononen|2015|Chem.-Eur.J.|21|15843|doi:10.1002/chem.201501343
CCDC 725615: Experimental Crystal Structure Determination
2009
Related Article: E.Coronado, C.Gimenez-Saiz, F.M.Romero, A.Tarazon|2009|Inorg.Chem.|48|2205|doi:10.1021/ic802218j