Search results for "Raft"

Iminium Catalysis (n → π*)

2016

9,10-Phenanthrenedione as Visible-Light Photoredox Catalyst: A Green Methodology for the Functionalization of 3,4-Dihydro-1,4-Benzoxazin-2- Ones thro…

2018

A visible-light photoredox functionalization of 3,4-dihydro-1,4-benzoxazin-2-ones through a Friedel-Crafts reaction with indoles using an inexpensive organophotoredox catalyst is described. The reaction uses a dual catalytic system that is formed by a photocatalyst simple and cheap, 9,10-phenanthrenedione, and a Lewis acid, Zn(OTf)2. 5W white LEDs are used as visible-light source and oxygen from air as a terminal oxidant, obtaining the corresponding products with good yields. The reaction can be extended to other electron-rich arenes. Our methodology represents one of the most valuable and sustainable approach for the functionalization of 3,4-dihydro-1,4-benzoxazin-2-ones, as compared to th…

Squaramide-Catalyzed Asymmetric aza-Friedel-Crafts/N,O-Acetalization Domino Reactions Between 2-Naphthols and Pyrazolinone Ketimines

2017

N-Boc ketimines derived from pyrazolin-5-ones were explored to develop an unprecedented domino aza-Friedel-Crafts/N,O-acetalization reaction with 2-naphthols. The novel method requires a catalyst loading of only 0.5 mol % of a bifunctional squaramide catalyst, is scalable to gram amounts, and provides a new series of furanonaphthopyrazolidinone derivatives bearing two vicinal tetra-substituted stereogenic centers in excellent yields (95-98 %) and stereoselectivity (>99:1 d.r. and 97-98 % ee). A different reactivity was observed in the case of 1-naphthols and other electron-rich phenols, which led to the aza-Friedel-Crafts adducts in 70-98 % yield and 47-98 % ee.

Hierarchical Beta zeolites as catalysts in a one-pot three-component cascade Prins–Friedel–Crafts reaction

2020

Hierarchical Beta zeolites obtained from concentrated reaction mixtures (H2O/Si = 2.5–7.0) in the presence of CTAB and their conventional and nanosponge analogues were investigated in a one-pot cascade environmentally friendly Prins–Friedel–Crafts reaction of butyraldehyde with 3-buten-1-ol and anisole under mild conditions (60 °C). The highest yields of the desired products with 4-aryltetrahydropyran structure were achieved when using hierarchical zeolites characterised by well-developed mesoporosity (facilitating the formation of bulky intermediates and products) and by an increased fraction of highly accessible (evaluated by TTBPy method) medium-strength Bronsted acid sites. Acid sites w…

How Many Phosphoric Acid Units Are Required to Ensure Uniform Occlusion of Sterically Stabilized Nanoparticles within Calcite?

2019

Polymerization-induced self-assembly (PISA) mediated by reversible addition-fragmentation chain transfer (RAFT) polymerization offers a platform technology for the efficient and versatile synthesis of well-defined sterically stabilized block copolymer nanoparticles. Herein we synthesize a series of such nanoparticles with tunable anionic charge density within the stabilizer chains, which are prepared via statistical copolymerization of anionic 2-(phosphonooxy)ethyl methacrylate (P) with non-ionic glycerol monomethacrylate (G). Systematic variation of the P/G molar ratio enables elucidation of the minimum number of phosphate groups per copolymer chain required to promote nanoparticle occlusi…

The BepiColombo MORE gravimetry and rotation experiments with the ORBIT14 software

2016

The BepiColombo mission to Mercury is an ESA/JAXA cornerstone mission, consisting of two spacecraft in orbit around Mercury addressing several scientific issues. One spacecraft is the Mercury Planetary Orbiter, with full instrumentation to perform radio science experiments. Very precise radio tracking from Earth, on-board accelerometer and optical measurements will provide large data sets. From these it will be possible to study the global gravity field of Mercury and its tidal variations, its rotation state and the orbit of its centre of mass. With the gravity field and rotation state, it is possible to constrain the internal structure of the planet. With the orbit of Mercury, it is possib…

Subarcsecond Location of IGR J17480-2446 with Rossi XTE

2012

On 2010 October 13, the X-ray astronomical satellite Rossi XTE, during the observation of the newly discovered accretion powered X-ray pulsar IGR J17480--2446, detected a lunar occultation of the source. From knowledge of lunar topography and Earth, Moon, and spacecraft ephemeris at the epoch of the event, we determined the source position with an accuracy of 40 mas (1{\sigma} c.l.), which is interesting, given the very poor imaging capabilities of RXTE (\sim 1\circ). For the first time, using a non-imaging X-ray observatory, the position of an X-ray source with a subarcsecond accuracy is derived, demonstrating the neat capabilities of a technique that can be fruitfully applied to current a…

Estimating Missing Information by Cluster Analysis and Normalized Convolution

2018

International audience; Smart city deals with the improvement of their citizens' quality of life. Numerous ad-hoc sensors need to be deployed to know humans' activities as well as the conditions in which these actions take place. Even if these sensors are cheaper and cheaper, their installation and maintenance cost increases rapidly with their number. We propose a methodology to limit the number of sensors to deploy by using a standard clustering technique and the normalized convolution to estimate environmental information whereas sensors are actually missing. In spite of its simplicity, our methodology lets us provide accurate assesses.

Seismic sources and stress transfer interaction among axial normal faults and external thrust fronts in the Northern Apennines (Italy): A working hyp…

2016

In this study we analyse the main potential seismic sources in some axial and frontal sectors of the Northern Apennines, in Italy. This region was hit by a peculiar series of earthquakes that started in 1916 on the external thrust fronts near Rimini. Later, in 1917-1921, seismicity (up to Mw approximate to 6.5) shifted into the axial zone and clearly migrated north-westward, along the belt of active normal faults. The collection of fault-slip data focused on the active normal faults potentially involved in this earthquake series. The acquired data allowed us to better characterize the geometry and kinematics of the faults. In a few instances, the installation of local seismic networks durin…

Models and data analysis tools for the Solar Orbiter mission

2020

All authors: Rouillard, A. P.; Pinto, R. F.; Vourlidas, A.; De Groof, A.; Thompson, W. T.; Bemporad, A.; Dolei, S.; Indurain, M.; Buchlin, E.; Sasso, C.; Spadaro, D.; Dalmasse, K.; Hirzberger, J.; Zouganelis, I.; Strugarek, A.; Brun, A. S.; Alexandre, M.; Berghmans, D.; Raouafi, N. E.; Wiegelmann, T.; Pagano, P.; Arge, C. N.; Nieves-Chinchilla, T.; Lavarra, M.; Poirier, N.; Amari, T.; Aran, A.; Andretta, V.; Antonucci, E.; Anastasiadis, A.; Auchère, F.; Bellot Rubio, L.; Nicula, B.; Bonnin, X.; Bouchemit, M.; Budnik, E.; Caminade, S.; Cecconi, B.; Carlyle, J.; Cernuda, I.; Davila, J. M.; Etesi, L.; Espinosa Lara, F.; Fedorov, A.; Fineschi, S.; Fludra, A.; Génot, V.; Georgoulis, M. K.; Gilbe…