Search results for "Raman spectroscopy."
showing 10 items of 790 documents
Development of a Temperature Distributed Monitoring System Based On Raman Scattering in Harsh Environment
2014
Raman Distributed Temperature Sensors (RDTSs) offer exceptional advantages to monitor the envisioned French deep geological repository for nuclear wastes, called Cigeo. Both $\gamma $ -ray and hydrogen release from nuclear wastes can strongly affect the temperature measurements made with RDTS. We present experimental studies on how the performances of RDTS evolve in harsh environments like those associated with $\gamma $ -rays or combined radiations and ${{\rm H}_2}$ release. The response of two standard and one radiation tolerant multimode fibers (MMFs) are investigated. In all fibers the differential induced attenuation between Stokes and anti-Stokes signal, ${({{\alpha _{\rm AS}} - {\alp…
Structural and vibrational study of Bi2Se3under high pressure
2011
The structural and vibrational properties of bismuth selenide (Bi${}_{2}$Se${}_{3}$) have been studied by means of x-ray diffraction and Raman scattering measurements up to 20 and 30 GPa, respectively. The measurements have been complemented with ab initio total-energy and lattice dynamics calculations. Our experimental results evidence a phase transition from the low-pressure rhombohedral ($R$-3$m$) phase (\ensuremath{\alpha}-Bi${}_{2}$Se${}_{3}$) with sixfold coordination for Bi to a monoclinic $C$2/$m$ structure (\ensuremath{\beta}-Bi${}_{2}$Se${}_{3}$) with sevenfold coordination for Bi above 10 GPa. The equation of state and the pressure dependence of the lattice parameters and volume …
Ab initiostudy of compressedAr(H2)2: Structural stability and anomalous melting
2010
We study the structural stability and dynamical properties of $\text{Ar}{({\text{H}}_{2})}_{2}$ under pressure using first-principles and ab initio molecular-dynamics techniques. At low temperatures, $\text{Ar}{({\text{H}}_{2})}_{2}$ is found to stabilize in the cubic C15 Laves structure $({\text{MgCu}}_{2})$ and not in the hexagonal C14 Laves structure $({\text{MgZn}}_{2})$ as it has been assumed previously. Based on enthalpy energy and phonon calculations, we propose a temperature-induced ${\text{MgCu}}_{2}\ensuremath{\rightarrow}{\text{MgZn}}_{2}$ phase transition that may rationalize the existing discrepancies between the sets of Raman and infrared vibron measurements. Our AIMD simulati…
Comparison between observation and simulation of sodium LGS return flux with a 20W CW laser on Tenerife
2016
We report on the comparison between observations and simulations of a completed 12-month field observation campaign at Observatorio del Teide, Tenerife, using ESO's transportable 20 watt CW Wendelstein laser guide star system. This mission has provided sodium photon return flux measurements of unprecedented detail regarding variation of laser power, polarization and sodium D2b repumping. The Raman fiber laser and projector technology are very similar to that employed in the 4LGSF/AOF laser facility, recently installed and commissioned at the VLT in Paranal. The simulations are based on the open source LGSBloch density matrix simulation package and we find good overall agreement with experim…
Raman and Infrared Spectra of Acoustical, Functional Modes of Proteins from All-Atom and Coarse-Grained Normal Mode Analysis
2018
The directions of the largest thermal fluctuations of the structure of a protein in its native state are the directions of its low-frequency modes (below 1 THz), named acoustical modes by analogy with the acoustical phonons of a material. The acoustical modes of a protein assist its conformational changes and are related to its biological functions. Low-frequency modes are difficult to detect experimentally. A survey of experimental data of low-frequency modes of proteins is presented. Theoretical approaches, based on normal mode analysis, are of first interest to understand the role of the acoustical modes in proteins. In this chapter, the fundamentals of normal mode analysis using all-ato…
Coarse grained and fine dynamics in trapped ion Raman schemes
2004
A novel result concerning Raman coupling schemes in the context of trapped ions is obtained. By means of an operator perturbative approach, it is shown that the complete time evolution of these systems (in the interaction picture) can be expressed, with a high degree of accuracy, as the product of two unitary evolutions. The first one describes the time evolution related to an effective coarse grained dynamics. The second is a suitable correction restoring the {\em fine} dynamics suppressed by the coarse graining performed to adiabatically eliminate the nonresonantly coupled atomic level.
Perturbative Treatment of the Evolution Operator Associated with Raman Couplings
2006
A novel perturbative treatment of the time evolution operator of a quantum system is applied to the model describing a Raman-driven trapped ion in order to obtain a suitable 'effective model'. It is shown that the associated effective Hamiltonian describes the system dynamics up to a certain transformation which may be interpreted as a 'dynamical dressing' of the effective model.
High-resolution spectroscopy and preliminary global analysis of C–H stretching vibrations of C2H4 in the 3000 and 6000cm−1 regions
2010
Abstract Ethylene (ethene, H2C=CH2) is a naturally occurring compound in ambient air that affects atmospheric chemistry and global climate. The C2H4 spectrum is available in databases only for the 1000 and 3000 cm−1 ranges. In this work, the ethylene absorption spectrum was measured in the 6030–6250 cm−1 range with the use of a high resolution Bruker IFS 125HR Fourier-spectrometer and a two-channel opto-acoustic spectrometer with a diode laser. As a secondary standard of wavelengths, the methane absorption spectrum was used in both cases. A preliminary analysis was realized thanks to the tensorial formalism developed by the Dijon group that is implemented in the XTDS software package [39] .…
A direct study of the vibrational bending effect in line mixing: The hot degenerate 1110 ← 0110 transition of CO2
1997
Abstract The study of the isotropiv Raman Q -branch of a hot band Π ← Π allows one to establish a direct connection between the vibration-rotation angular momentum coupling and the resulting spectra. Due to the l -doubling, the Q -branch is split into two subbranches characterized by either even or odd rotational quantum number j . The vibrational bending reduces the rotational transfer rates inside each of these subbranches by a factor of about two and induces an inter-subbranch coupling. The expected propensity rule towards conservation of the parity index for high rotational levels is well observed. Calculated spectra are in excellent agreement with CARS experiments for the v 1 + v 2 ← v…
Collisional broadening and shifting parameters of the RamanQbranch ofH2perturbed byN2determined from speed-dependent line profiles at high temperatur…
1996
The broadening and shifting of the {ital Q} branch of H{sub 2} diluted in N{sub 2} are studied at temperatures between 300 and 1200 K. (i) In order to account for the observed anomalies (asymmetric profiles and nonlinearity of the linewidth versus perturber concentration), the results are interpreted using a speed-dependent model in its general form. This model introduces the speed dependence of the shift and the broadening. In contrast with the previous H{sub 2}{endash}rare-gas studies, the high-temperature measurements prove the necessity to include speed-dependent broadening that was ignored in the previous studies. (ii) Concomitantly, we report as well pure H{sub 2} results including Ra…