Search results for "Rare-earth"
showing 10 items of 42 documents
Comment on: Application of Raman Spectroscopy to Distinguish Metamorphic and Igneous Zircon (Xian et al., Anal. Lett. 2004, v. 37, p. 119)
2005
Abstract We critically discuss a recently proposed technique ((Xian et al. 2004)) used to distinguish igneous (i.e., magmatic) from metamorphic growth of the mineral zircon according to the intensity of the 1461 cm−1 band observed in those author's Raman spectra. The band evaluated by Xian et al. (2004) is actually due to laser‐induced photoluminescence of trace amounts of the trivalent rare earth element Er, which, as an analytical artefact, overlays the Raman spectrum when green Ar+ laser excitation is used. We demonstrate that this band is not a Raman band, and discuss why the intensity of Er3+ luminescence is not uniquely indicative of the geologic origin of a zircon crystal. The techni…
Roadmap on STIRAP applications
2019
STIRAP (stimulated Raman adiabatic passage) is a powerful laser-based method, usually involving two photons, for efficient and selective transfer of populations between quantum states. A particularly interesting feature is the fact that the coupling between the initial and the final quantum states is via an intermediate state, even though the lifetime of the latter can be much shorter than the interaction time with the laser radiation. Nevertheless, spontaneous emission from the intermediate state is prevented by quantum interference. Maintaining the coherence between the initial and final state throughout the transfer process is crucial. STIRAP was initially developed with applications in …
Finite amplitude method applied to giant dipole resonance in heavy rare-earth nuclei
2015
Background: The quasiparticle random phase approximation (QRPA), within the framework of the nuclear density functional theory (DFT), has been a standard tool to access the collective excitations of the atomic nuclei. Recently, finite amplitude method (FAM) has been developed, in order to perform the QRPA calculations efficiently without any truncation on the two-quasiparticle model space. Purpose: We discuss the nuclear giant dipole resonance (GDR) in heavy rare-earth isotopes, for which the conventional matrix diagonalization of the QRPA is numerically demanding. A role of the Thomas-Reiche-Kuhn (TRK) sum rule enhancement factor, connected to the isovector effective mass, is also investig…
Effect of hydrothermal time on the forming specific morphology of YPO4:Eu3+ nanoparticles for dedicated luminescent applications as optical markers
2023
A way to control the desired shape and microstructure of YPO4:Eu3+ nanoparticles through the precipitation method followed by a hydrothermal treatment is reported. This method is useful for achieving very high control over the YPO4:Eu3+ formation process with the selection of appropriate synthesis parameters. In detail, the autoclave processing time allows control of the shape and size of nano-needle-shaped particles independently in both directions, as confirmed by X-ray powder diffraction, FT-IR Spectroscopy and Electron Transmission Microscopy. In order to analyse the effect of the nanoparticles’ surroundings on the excitation and relaxation processes of luminescent ions, Eu3+ ion was us…
Radiation responses of Yb/Er-doped phosphosilicate optical fibers: hardening mechanisms related to Ce-codoping
2012
International audience; In this paper, we investigated the origins of the Ce positive influence on the radiation response of Yb/Er-doped phosphosilicate optical fibers. To this purpose, we carried out during γ-irradiations an online characterization on active optical fiber prototypes, made with different Ce concentrations and integrated in optical amplifiers. The hardening effect of Ce-codoping is highlighted, as well as some aspects related to the radiation response of the phosphosilicate host glass of the active optical fibers.
Zirconium–hafnium and rare earth element signatures discriminating the effect of atmospheric fallout from hydrothermal input in volcanic lake water
2016
The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidicwaters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr a nd Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y-Ho and Zr-Hf (twin pairs) have a…
Design of Radiation-Hardened Rare-Earth Doped Amplifiers through a Coupled Experiment/Simulation Approach
2013
International audience; We present an approach coupling a limited experimental number of tests with numerical simulations regarding the design of radiation-hardened (RH) rare earth (RE)-doped fiber amplifiers. Radiation tests are done on RE-doped fiber samples in order to measure and assess the values of the principal input parameters requested by the simulation tool based on particle swarm optimization (PSO) approach. The proposed simulation procedure is validated by comparing the calculation results with the measured degradations of two amplifiers made with standard and RH RE-doped optical fibers, respectively. After validation, the numerical code is used to theoretically investigate the …
ChemInform Abstract: Rare Earth Element Catalysts
2010
Microanalytical methods for in-situ high-resolution analysis of rock varnish at the micrometer to nanometer scale
2015
Abstract A wide range of analytical techniques were used to investigate rock varnish from different locations (Negev, Israel; Knersvlakte, South Africa; Death Valley and Mojave Desert, California): a 200 nm-femtosecond laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS), an electron probe microanalyzer (EPMA), focused ion beam (FIB) slicing, and scanning transmission X-ray microscopy–near edge X-ray absorption fine structure spectroscopy (STXM–NEXAFS). This combination enables comprehensive high-spatial-resolution analysis of rock varnish. Femtosecond LA-ICP-MS and EPMA were used for quantitative determination of element concentrations. In-situ measurements were conducte…
Rare earth element contents of Jurassic fish and reptile teeth and their potential relation to seawater composition (Anglo-Paris Basin, France and En…
2002
The rare earth element (REE) chemistry of Jurassic shelf seawater from western Europe (Anglo-Paris Basin) was investigated by analyzing the fish and reptile teeth deposited in shallow to deeper water (<200 m) environments. REE patterns in apatites are controlled by the host sediments. Vertebrate teeth sampled from the siliciclastic sediments (calcareous sandstones and shales) show flat shale-normalized REE patterns that reflect the dominant influence of the continental source from which the REE were derived. Carbonate deposits, protected from the clastic sources, contain fish and reptile teeth whose REE patterns reflect more accurately the REE composition of the overlying water column. The …