Search results for "Recycling"
showing 10 items of 207 documents
Friction stir consolidation of aluminum machining chips
2017
Friction stir consolidation (FSC) is a solid-phase manufacturing process that consolidates metal powder, chips, or scraps into solid blocks via severe plastic deformation and solid state welding. It has the potential to be a more economical and âgreenâ process to recycle metal waste. In this study, solid discs were made from AA6061 aluminum alloy machining chips by FSC. The progression of the process was revealed by analyzing the motion of the tool, consolidating force, power history, and macro/microstructure of discs produced from a series of partial consolidation experiments. A bowl-shaped recrystallized zone in the vertical cross-sections of the disc products was observed and conside…
Multi-material based functionally graded billets manufacturing through friction stir consolidation of aluminium alloys chips
2022
New deal of Friction Stir Consolidation (FSC) is its evolution from Recycling technique towards Upcycling. In this paper, the potential of FSC to manufacture Functionally Graded billets is proved. Processing chips of two different aluminium alloys (AA7075, AA2011-T3), graded hardness distributions were obtained along the longitudinal direction of the manufactured billet. Material flow was analysed by EDX analyses and numerical simulations; mechanical properties were assessed through hardness measurements. The influence of material's position, mass fraction of each material and process parameters was considered. Results reveal that FSC offers a proper control in the design of billets with gr…
The composition of fluids stored in the central Mexican lithospheric mantle: Inferences from noble gases and CO2 in mantle xenoliths
2021
We present the first isotopic (noble gases and CO2) characterization of fluid inclusions coupled to Raman microspectroscopy analyses in mantle xenoliths from Central Mexico, a geodynamically complex area where the Basin and Range extension was superimposed on the Farallon subduction (terminated at 28 Ma). To characterize the isotopic signature of the Central Mexican lithospheric mantle, we focus on fluid inclusions entrapped in mantle xenoliths found in deposits of the Joya Honda maar (JH), a Quaternary monogenetic volcano belonging to the Ventura Espiritu Santo Volcanic Field (VESVF) in the state of San Luis Potosí (central Mexico). Thirteen ultramafic plagioclase-free xenoliths were selec…
Forgeability characterization of multi-material based functionally graded materials manufactured through friction stir consolidation
2022
Solid state recycling allows direct recycling of metal chips into semi-finished products. This process category proved to lower the environmental impact of metals recycling. Friction stir consolidation (FSC) is a new solid-state technique taking advantage of friction heat generation and severe plastic deformation to consolidate chips into billets. The new frontier of FSC process could be its evolution from recycling techniques towards the concept of upcycling technique: reuse (discarded objects or material) in such a way as to create a product of higher quality or value than the original. The authors have recently successfully applied FSC for producing multi-material based functionally grad…
Kimberlite, carbonatite, and potassic magmatism as part of the geochemical cycle
2013
M20 M21
Constraints on mantle source and interactions from He-Sr isotope variation in Italian Plio-Quaternary volcanism
2008
[1] Helium isotope ratios of olivine and pyroxene phenocrysts from Plio-Quaternary volcanic rocks from southern Italy (seven Aeolian Islands, Mt. Vulture, Etna, Ustica, and Pantelleria) range from 2.3 to 7.1 Ra. Importantly, the phenocryst 3He/4He correlate well with whole rock Sr isotopic composition (0.70309–0.70711), reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near-linear He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr (and a…
Continental collision and the dynamic and thermal evolution of the Variscan orogenic crustal root — numerical models
2001
Abstract Orogeny is modelled numerically by treating continental collision within full convection solutions, in order to better understand some aspects of the Variscan structures and processes. Three different approaches are taken: (1) collision where one ‘continental plate’ is ‘pushed’ against another across a zone of weakness; (2) gravitational instability of a lithospheric mantle root leading to delamination, slab break-off and crustal root reduction; (3) melting in the lower part of a crustal orogenic root. The first approach demonstrates that thick (but in the models: cool) roots can accumulate, in which upper crustal rocks are carried to great depth and mantle material may be carried …
Physical and mechanical properties of sustainable hydraulic mortar based on marble slurry with waste glass
2021
This paper aims to propose and characterize a sustainable hydraulic mortar entirely obtained by the reuse of waste materials, with marble slurry coming from quarries in the north-western Sicily and glass powder coming from a waste collection plant in Marsala (Province of Trapani). The first was used as raw material to produce the mortar binder by a kilning and slaking process, while the second was used as a pozzolanic additive. The chemical and morphological characterization of the marble slurry was done by XRD, FTIR, STA and SEM analyses. Glass powder was analyzed through particle size distribution measurements, XRD and standard pozzolanic tests. Hydraulic mortars constituted by slaked lim…
Activity of a Heterogeneous Catalyst in Deep Eutectic Solvents: The Case of Carbohydrate Conversion into 5-Hydroxymethylfurfural
2019
Obtaining industrially relevant products from renewable resources and developing processes under the light of sustainable chemistry is a prominent endeavor of present-day chemical research. In this context, herein we investigated the dehydration of fructose and sucrose in deep eutectic solvents promoted by the ion-exchange resin Amberlyst 15 as heterogeneous catalyst. We optimized the reaction conditions in terms of temperature, catalyst loading, and initial amount of substrate. Then, we looked at the effect of structural variations in the solvent components on the reaction outcome. Under the best experimental conditions, we obtained very good yields of 78% at 60 °C and 69% at 80 °C for fru…
Cluster Preface: Heterogeneous Catalysis
2016
International audience; Jean-Cyrille Hierso is full professor of Chemistry since 2009, heading the group of ‘Organometallic Chemistry and Catalysis’ at the Institute of Molecular Chemistry at the University of Bourgogne Franche-Comté (UBFC). He has interest in the fields of organometallic chemistry, ligand design, homo- and heterogeneous catalysis, chemical physics, and material sciences. In 2011 he was awarded the National Prize for Coordination Chemistry from the French Chemical Society (SCF), and at the end of 2012 he was elected a junior Member of the French Professors Academy ‘Institut Universitaire de France’ (IUF).Yasuhiro Uozumi is a full professor at the Institute for Molecular Sci…