Search results for "Reduction"
showing 10 items of 2058 documents
Ascorbic Acid Oxidation in Sucrose Aqueous Model Systems at Subzero Temperatures
2004
The reduction of Tempol by ascorbic acid in concentrated sucrose solutions was measured by electron paramagnetic resonance (EPR) at temperatures ranging from 16 to −16 °C. This method allowed the determination of the rate constants (k) of this fast reaction, by recording the Tempol reduction as a function of time. The two reactants were initially separated and had to migrate for the reaction to occur. The experimental findings were compared with predicted values according to the equation for diffusion-controlled reaction proposed by Atkins. The experimental reaction rate constants were observed to be lower than the calculated ones. However, the experimental values were found to be controlle…
Chalcogenide-capped triiron clusters [Fe3(CO)9(μ3-E)2], [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] and [Fe3(CO)7(μ3-E)2(μ-dppm)] (E = S, Se) as proton-reduction…
2019
Chalcogenide-capped triiron clusters [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] and [Fe3(CO)7(μ3-E)2(μ-dppm)] (E = S, Se) have been examined as proton-reduction catalysts. Protonation studies show that [Fe3(CO)9(μ3-E)2] are unaffected by strong acids. Mono-capped [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] react with HBF4.Et2O but changes in IR spectra are attributed to BF3 binding to the face-capping carbonyl, while bicapped [Fe3(CO)7(μ3-E)2(μ-dppm)] are protonated but in a process that is not catalytically important. DFT calculations are presented to support these protonation studies. Cyclic voltammetry shows that [Fe3(CO)9(μ3-Se)2] exhibits two reduction waves, and upon addition of strong acids, proton-reducti…
Baeyer–Villiger oxidation of ketones with a silica-supported peracid in supercritical carbon dioxide under flow conditions
2009
[2-Percarboxyethyl]-functionalized silica reacts with ketones in supercritical carbon dioxide at 250 bar and 40 °C under flow conditions to yield the corresponding esters and lactones. The solid reagent can be easily recycled through treatment with 70% hydrogen peroxide in the presence of an acid at 0 °C. This procedure not only simplifies the isolation of the reaction products, but has the advantage of using only water and carbon dioxide as solvents under mild conditions.
Electrochemical reduction of carbon dioxide to formic acid at a tin cathode in divided and undivided cells: effect of carbon dioxide pressure and oth…
2016
Abstract The reduction of carbon dioxide to formic acid at a tin cathode was studied in both divided and undivided cells. In the first stage of the study, the effect of some operating parameters, including the working potential and the nature of the supporting electrolyte and of the cathode, on both the cathodic reduction of CO2 and the anodic oxidation of formic acid was investigated in a divided cell. In a second stage, the reduction of carbon dioxide was performed in an undivided cell with the aim of studying the effect on the generation of formic acid of various operating parameters such as current density, cathode to anode area ratio, mixing rate and nature of the anode and of the supp…
Carbohydrate-supramolecular gels : adsorbents for chromium(VI) removal from wastewater.
2019
Abstract Hypothesis To overcome the contamination of water by heavy metals the adsorption of the pollutant on gel phases is an attractive solution since gels are inexpensive, potentially highly efficient and form a distinct phase while allowing diffusion of the contaminated water throughout the material. This work tests the chromium(VI) adsorbent capacity of new supramolecular gels for Chromium(VI) removal from wastewater. Experiments First hydrophobic imidazolium salts of carbohydrate anions were synthesised as new gelators. Subsequently, they were dissolved in a solvent by heating and, after cooling overnight, to give the formation of supramolecular gels. The properties of the resulting g…
Numerical-Experimental Study Regarding the Single Point Incremental Forming Process
2021
The present paper proposes a numerical-experimental comparative study on the single point incremental forming process. A DC04 steel sheet with a thickness of 0.6 mm was used for both the numerical simulation using the finite element method and the experimental research. The type of trajectory used was a spiral trajectory and the finished part obtained was a truncated cone-shaped part. The analysis program used for simulation was Ls-Dyna. The simulations were performed in several variants: with a fixed mesh and with an adaptive mesh, using two different element formulations: 25 (Belytschko-Tsay formulation with thickness stretch) and -16 (fully integrated shell element modified for higher ac…
Multiresolution Analysis for Meshes with Appearance Attributes
2005
International audience; We present a new multiresolution analysis framework for irregular meshes with attributes based on the lifting scheme. We introduce a surface prediction operator to compute the detail coefficients for the geometry and the attributes of the model. Attribute analysis gives appearance information to complete the geometrical analysis of the model. A set of experimental results are given to show the efficiency of our framework. We present two applications to adaptive visual-ization and denoising.
Multiresolution Analysis for Irregular Meshes
2003
International audience; The concept of multiresolution analysis applied to irregular meshes has become more and more important. Previous contributions proposed a variety of methods using simplification and/or subdivision algorithms to build a mesh pyramid. In this paper, we propose a multiresolution analysis framework for irregular meshes with attributes. Our framework is based on simplification and subdivision algorithms to build a mesh pyramid. We introduce a surface relaxation operator that allows to build a non-uniform subdivision for a low computational cost. Furthermore, we generalize the relaxationoperator to attributes such as color, texture, temperature, etc. The attribute analysis…
The oxidation state of a protein observed molecole-by-molecule.
2005
We report the observation of the redox state of the blue copper protein azurin on the single-molecule level. The fluorescence of a small fluorophore attached to the protein is modulated by the change in absorption of the copper center via fluorescence resonance energy transfer (FRET). In our model system, the fluorescence label Cy5 was coupled to azurin from Pseudomonas aeruginosa via cysteine K27C. The Cy5 fluorescence was partially quenched by the absorption of the copper center of azurin in its oxidized state. In the reduced state, absorption is negligible, and thus no quenching occurs. We report on single-molecule measurements, both in solution by using fluorescence correlation spectros…
The REFLEX galaxy cluster survey VIII. Spectroscopic observations and optical atlas
2009
We present the final data from the spectroscopic survey of the ROSAT-ESO Flux-Limited X-ray (REFLEX) catalog of galaxy clusters. The REFLEX survey covers 4.24 steradians (34% of the entire sky) below a declination of 2.5 deg and at high Galactic latitude (|b| > 20 deg). The REFLEX catalog includes 447 entries with a median redshift of 0.08 and is better than 90% complete to a limiting flux fx = 3x10^{-12} erg s^{-1} cm^{-2} (0.1 to 2.4 keV), representing the largest statistically homogeneous sample of clusters drawn from the ROSAT All-Sky Survey (RASS) to date. Here we describe the details of the spectroscopic observations carried out at the ESO 1.5 m, 2.2 m, and 3.6 m telescopes, as wel…