Search results for "Reflection"
showing 10 items of 645 documents
Dielectric Behavior of Aqueous Solutions of α,β-Poly(aspartyl hydrazide) and α,β-Poly(N-hydroxyethyl aspartamide): An Investigation of the Structural…
1994
The dielectric properties of aqueous solutions of α,β-poly(aspartyl hydrazide) (PAHy) and of α,β-poly( N-hydroxyethyl aspartamide) (PHEA) were measured at 25 ° C in the frequency range of 100 MHz to 15 GHz using a time domain reflection method (TDR). Single time relaxation processes were found at 2 GHz and 15 GHz, respectively. The low frequency dispersion was inter preted in terms of the dynamics of polymeric segments based on the dielectric relaxation strength and the relaxation time. The high frequency process which is attributed to the rotational relaxation of water, indicated that water mole cules surrounding the polymeric backbone and in the pure state have a similar rotational behav…
Attenuated total reflectance infrared determination of sodium nitrilotriacetate in alkaline liquid detergents
2005
Abstract An attenuated total reflectance infrared (ATR–FTIR) method has been developed for the direct determination of the chelating agent sodium nitrilotriacetate (NTA) in high pH cleaning formulations. Aqueous samples and standards were placed directly on the diamond ATR cell without any pre-treatment and FTIR spectra were recorded between 4000 and 600 cm−1. Measurement conditions were evaluated. Results obtained for five different commercial formulations containing from 6.22 to 9.25% (w/w) of NTA were in good agreement with the manufacturer's declared content (differences between 3.2 and −3.7%). Recovery studies evidenced the accuracy of the developed method, having found values between …
Analyzing chemical changes in verdigris pictorial specimens upon bacteria and fungi biodeterioration using voltammetry of microparticles
2017
[EN] It is reported the application of the voltammetry of microparticles (VMP), complemented with attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and field emission scanning electron microscopy (FESEM) techniques, to monitor the deterioration of verdigris pictorial specimens under the action of different biological agents. This methodology would be of application for identifying the type of biological agent causing deterioration of paintings, which is an important problem affecting cultural heritage. The analysis of biodeterioration processes is complicated by the fact that the action of microorganisms can affect both pigment and binding media. The deteriorat…
Study of the reflection spectrum of the accreting neutron star GX 3+1 using XMM-Newton and INTEGRAL
2015
Broad emission features of abundant chemical elements, such as Iron, are commonly seen in the X-ray spectra of accreting compact objects and their studies can provide useful information about the geometry of the accretion processes. In this work, we focus our attention on GX 3+1, a bright, persistent accreting low mass X-ray binary, classified as an atoll source. Its spectrum is well described by an accretion disc plus a stable comptonizing, optically thick corona which dominates the X-ray emission in the 0.3-20 keV energy band. In addition, four broad emission lines are found and we associate them with reflection of hard photons from the inner regions of the accretion disc where doppler an…
Discriminating irrigated and rainfed olive orchards with thermal ASTER imagery and DART 3D simulation
2009
Article in Press
Autonomous Measurements of Sea Surface Temperature Using In Situ Thermal Infrared Data
2004
Abstract In situ and autonomous measurements of sea surface temperature (SST) have been performed with a thermal infrared radiometer mounted on a fixed oil rig. The accuracy limit was established at ±0.3 K for these SST measurements in order to meet the requirements of the Tropical Ocean Global Atmosphere (TOGA) program for global climate research and the Soil Moisture and Ocean Salinity (SMOS) mission for salinity retrieval. With this aim, the optimal observation angle and spectral channel for SST measurements have been identified. Then, a methodology has been developed for the radiometer calibration and the emissivity correction, including the reflection of the downwelling sky radiance, w…
Evaluation of Surface Temperature and Emissivity Derived from ASTER Data: A Case Study Using Ground-Based Measurements at a Volcanic Site
2010
Abstract The land surface temperature (LST) and emissivity (LSE) derived from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data were evaluated in a low spectral contrast volcanic site at an altitude of 2000 m on the island of Tenerife, Spain. The test site is almost flat, thermally homogeneous, and without vegetation cover or variation in its surface composition. ASTER data correspond to six scenes, under both day- and nighttime conditions during 2008. This case study analyzes the impacts of the sources of inaccuracies using the temperature–emissivity separation (TES) algorithm. Uncertainties associated with inaccurate atmospheric correction were minimized by means…
Temperature and Emissivity Separation From MSG/SEVIRI Data
2014
In this paper, we analyze the feasibility of applying the temperature and emissivity separation (TES) algorithm to thermal-infrared data acquired with three bands of the Spinning Enhanced Visible and Infrared Imager (SEVIRI) onboard the Meteosat Second Generation platform (SEVTES). The performance of the SEVTES algorithm was tested using data simulated over different atmospheric conditions and surface emissivities, with errors around 1.5% for emissivity and 1.5 K for temperature when atmospheric correction is accurate enough. In contrast, errors on land-leaving radiances higher than 2% or uncertainties on total atmospheric water vapor amount higher than 5% lead to errors on emissivity highe…
Reactivity of H2S and H2S/H2 Mixture With Molybdenum Oxide Thin Films Epitaxied on CoO (100) : Characterization by Rheed and Auger Spectroscopy
2010
Molybdenum-Cobalt composite oxide films were prepared by the evaporation of molybdenum trioxide on a fresh cleaved CoO (100) surface (Thickness = 10 A). The MoO3-CoO interface has been characterized simultaneously by reflexion high electron diffraction (RHEED) and Auger Electron Spectroscopy (AES). The thin film structure and composition depend on the annealing temperature. After a 300°C treatment, metallic cobalt islands nucleate at the interface thin film - CoO (100) and crystallize with the cubic FCC symmetry. After a 700°C treatment cobalt molybdate (a CoMoO4) islands grow. The metastable crystallites are epitaxied on CoO (100). After a 900°C treatment, the thin film consists of flat tw…
Effect of the surface stoichiometry on the interaction of Mo with TiO2 (110)
2000
Abstract Molydenum has been deposited at room temperature on (110) TiO2 surfaces with different stoichiometries, roughnesses and crystallinities. Whatever the substrate preparation is, in-situ Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) studies as well as ex-situ atomic force microscopy (AFM) and reflexion high-energy electron diffraction (RHEED) studies reveal a Stranski–Krastanov growth mode: the completion of three monolayers followed by islands growth is observed in every case. The three monolayers are always composed of amorphous molybdenum oxide with an oxidation state of molybdenum less than IV. The oxidation of the molybdenum layers generates Ti3+ an…