Search results for "Resolution"
showing 10 items of 1928 documents
Capillary Electrophoresis of Free Fatty Acids by Indirect Ultraviolet Detection: Application to the Classification of Vegetable Oils According to The…
2011
A method for the determination of fatty acids in vegetable oils by capillary electrophoresis with indirect UV–vis detection has been developed. The separation of fatty acids was optimized in terms of Brij surfactant nature and concentration and organic modifier (2-propanol) percentage. The optimal background electrolyte consisted of 10 mM p-hydroxybenzoate, 5 mM Tris at pH 8.8, 80 mM Brij 98, 40% acetonitrile, and 10% 2-propanol. Under these conditions, vegetable oils from five botanical origins (avocado, corn, extra virgin olive, hazelnut, and soybean) were analyzed and the fatty acid contents established. Linear discriminant analysis (LDA) models were constructed using fatty acid peak are…
Seasonal cycles and variability of O<sub>3</sub> and H<sub>2</sub>O in the UT/LMS during SPURT
2005
Abstract. Airborne high resolution in situ measurements of a large set of trace gases including ozone (O3) and total water (H2O) in the upper troposphere and the lowermost stratosphere (UT/LMS) have been performed above Europe within the SPURT project. With its innovative campaign concept, SPURT provides an extensive data coverage of the UT/LMS in each season within the time period between November 2001 and July 2003. Ozone volume mixing ratios in the LMS show a distinct spring maximum and autumn minimum, whereas the O3 seasonal cycle in the UT is shifted by 2 to 3 month later towards the end of the year. The more variable H2O measurements reveal a maximum during spring/summer and a minimum…
Monthly Land Surface Temperature maps over European Zone using Advanced Along Track Scanning Radiometer data for 2007
2009
Land Surface Temperature (LST) monthly maps are necessary in climatic studies and remote sensing is a key tool used to obtain these maps. For this reason, we used the LST product of AATSR on board Envisat. This product uses a split-window algorithm which depends on vertical column water vapour content (W) and viewing angle. The algorithm proposed in Galve et al. [1] was also used, which is based on the Coll and Caselles [2] split-window model and depends explicitly on the emissivity and W. This algorithm was tested with concurrent ground measurements in the Valencia validation site, yielding an error of + 0.5 K. With both algorithms we perform LST maps over Europe with a spatial resolution …
Resolution and Determination of the Absolute Configuration of a Twisted Bis-Lactam Analogue of Tröger's Base: A Comparative Spectroscopic and Computa…
2015
The first reported twisted bis-lactam, a racemic Tröger's base (TB) analogue (2), was resolved into its enantiomers on a chiral stationary phase HPLC column. The absolute configuration of (+)-2 was determined to be (R,R)-2 by comparing experimental and calculated vibrational circular dichroism (VCD) and electronic circular dichroism (ECD) spectra. The absolute configuration of (-)-2 was determined by comparing experimental and calculated electronic circular dichroism (ECD) spectra. The corresponding theoretical spectra were calculated using the lowest energy conformation of (R,R)-2 and (S,S)-2 at the B3LYP/6-31G(d,p) level of theory. The absolute configuration of (+)-2 was also determined t…
Surface Defects as a Tool to Solubilize and Functionalize WS 2 Nanotubes
2017
Layered transition metal dichalcogenides contain a number of crystal defects which significantly change their properties may be beneficial or detrimental for a specific application. We have prepared defect-rich multiwalled WS2 nanotubes by reductive sulfidization of W18O49 nanowires that were obtained solvothermally from tungsten chloride in different alcohols. The synthesis of the W18O49 nanowires was monitored and their morphological characteristics (e. g. length, rigidity and aspect ratio) are described in detail. The effect of morphology of the nanowires on the synthesis of WS2 nanotubes was investigated in order to obtain WS2 nanotubes that are highly solvent dispersible. Dispersions o…
A new efficient, highly dispersed, Pd nanoparticulate silica supported catalyst synthesized from an organometallic precursor. Study of the homogeneou…
2018
[EN] A new Pd(0) catalyst supported on silica UVM-7 has been synthesized from the organometallic [Pd-2(mu-(C6H4) Pp(2))(2)(CH3CN)(4)](BF4)(2) precursor, characterized by the high dispersion, activity, and small size of the palladium nanoclusters fixed on the silica surface. The catalyst was tested for the Suzuki-Miyaura (SM) reaction of different 4-substitutedphenyl halides with phenylboronic acid. The kinetic study concurs with most of the catalytic action was carried out by Pd species originated by the partial solubilization of Pd immobilized on mesoporous silica. The Schmidt's analysis of differential selectivity (SADS) in several competitive SM reactions, together the STEM-HAADF and HRT…
Direct activation of zebrafish neurons by ultrasonic stimulation revealed by whole CNS calcium imaging
2020
Abstract Objective. Ultrasounds (US) use in neural engineering is so far mainly limited to ablation through high intensity focused ultrasound, but interesting preliminary results show that low intensity low frequency ultrasound could be used instead to modulate neural activity. However, the extent of this modulatory ability of US is still unclear, as in in vivo studies it is hard to disentangle the contribution to neural responses of direct activation of the neuron by US stimulation and indirect activation due either to sensory response to mechanical stimulation associated to US, or to propagation of activity from neighboring areas. Here, we aim to show how to separate the three effects and…
Some tests of 3D ultrasonic traveltime tomography on the Eleonora d'Aragona statue (F. Laurana, 1468)
2013
Abstract The use of a non-destructive technique in situ can be a valuable diagnostic tool to support verification of restoration, as well as a monitoring technique in works of art or historical monuments. We present a high resolution 3D ultrasonic tomography to one of the most important statues of the Regional Gallery of Palazzo Abatellis of Palermo, the bust of Eleonora d'Aragona by F. Laurana (1430–1502). This technique allowed to study the structural continuity of the material of the marble. Some tests have been carried out to optimize inversion parameters, such as voxel size and to choose between straight and curved rays. We propose to calculate a minimum lateral resolution using the sa…
L’occupation de l’Iraq. Le Conseil de sécurité, le droit de la guerre et le droit des peuples à disposer d’eux-mêmes
2004
By Resolutions No. 1483 and 1511 (2003), the Security Council authorized the occupying powers in Iraq to intervene in the political and economic affairs of the occupied territory beyond the limits provided for by international law of war. At the same time, this authorization restricts the right of the Iraqui peole to self- determination, considered in its external aspect. Thus, the problem arises whether it is within the Security Council's powers to adopt resolutions which restrict the enjoyment of rights protected by rules of jus cogens. Furthermore, because the occupying government interpreted these resolutions broadly, it may be asked whether this interpretation is lawful. From a close e…
Endoureterotomy with the Lovaco technique for treatment of ureterointestinal strictures: outcomes in an experienced center and factors associated wit…
2021
INTRODUCTION The study aimed to present the outcomes of an endoureterotomy series using the Lovaco technique for the treatment of ureterointestinal strictures. Factors influencing the success or failure of this technique were also determined. MATERIALS AND METHODS Data were collected from all endoureterotomies for ureterointestinal strictures performed in a single-center between 2017 and 2020. Clinical variables and characteristics of the stricture were recorded in each case, and success was defined as the complete resolution of ureterohydronephrosis. Univariate analysis was used to correlate the variables recorded with procedural success or failure. RESULTS A total of 25 patients were recr…