Search results for "Reversible"
showing 10 items of 140 documents
Annealed Invariance Principle for Random Walks on Random Graphs Generated by Point Processes in R-d
2016
International audience; We consider simple random walks on random graphs embedded in R-d and generated by point processes such as Delaunay triangulations, Gabriel graphs and the creek-crossing graphs. Under suitable assumptions on the point process, we show an annealed invariance principle for these random walks. These results hold for a large variety of point processes including Poisson point processes, Matern cluster and Matern hardcore processes which have respectively clustering and repulsiveness properties. The proof relies on the use the process of the environment seen from the particle. It allows to reconstruct the original process as an additive functional of a Markovian process und…
Development of the wing discs of Zophobas atratus under natural and experimental conditions: occurrence of a gradual larval-pupal commitment in the e…
1999
Using light and electron microscopy, we studied the development of the wing discs in the large beetle Zophobas atratus, under natural and experimental conditions. A reversible differentiation of the wing discs is usually observed during supernumerary instars of crowded larvae. Juvenile hormone analog (JHA) application during the wandering period or compelled experimental crowding during the larval-pupal switchover – or commitment – inhibits the onset of metamorphosis. Isolation, followed by recrowding, also induces the disc cells to secrete unusual cuticular material. Recrowding is able to trigger the reversal of metamorphosis during the 4-day period when larval-pupal commitment is taking p…
Reactive surface coatings based on polysilsesquioxanes: defined adjustment of surface wettability.
2009
We have investigated a generally applicable protocol for a substrate-independent reactive polymer coating that offers interesting possibilities for further molecular tailoring via simple wet chemical derivatization reactions. Poly(methylsilsesquioxane)-poly(pentafluorophenyl acrylate) hybrid polymers have been synthesized by RAFT polymerization, and stable reactive surface coatings have been prepared by spin-coating on the following substrates: Si, glass, gold, PMMA, PDMS, and steel. These coatings have been used for a defined adjustment of surface wettability by surface-analogous reaction with various amines (e.g., glutamic acid to obtain hydrophilic surfaces (Theta(a) = 18 degrees) or per…
Functionalization and patterning of reactive polymer brushes based on surface reversible addition and fragmentation chain transfer polymerization
2012
We present the synthesis of reactive polymer brushes prepared by surface reversible addition–fragmentation chain transfer polymerization of pentafluorophenyl acrylate. The reactive ester moieties can be used to functionalize the polymer brush film with virtually any functionality by simple post-polymerization modification with amines. Dithiobenzoic acid benzyl-(4-ethyltrimethoxylsilyl) ester was used as the surface chain transfer agent (S-CTA) and the anchoring group onto the silicon substrates. Reactive polymer brushes with adjustable molecular weight, high grafting density, and conformal coverage through the grafting-from approach were obtained. Subsequently, the reactive polymer brushes …
Substrate-Independent Stable and Adherent Reactive Surface Coatings and their Conversion with Amines
2007
To create stable, adherent and reactive surface coatings, a hybrid polymer composed of poly(methylsilsesquioxane) (PMSSQ) and poly(pentafluorophenyl acrylate) PFPA with a M n of 32000 g/mol was prepared by a RAFT polymerization procedure. These hybrid polymer has been used for coating experiments. The PFPA part enabled a variable functionalization of the coating afterwards. The stability on various substrates (e.g. glass, PMMA, steel) was tested in an ISO tape test. These reactive surface coatings were modified using different amines, such as amino-terminated PEG, dodecyl amine and N-isopropyl amine. The conversion was analyzed by FT-IR and contact angle measurements.
Langmuir-Blodgett films of biocompatible poly(HPMA)-block-poly(lauryl methacrylate) and poly(HPMA)-random-poly(lauryl methacrylate): influence of pol…
2010
Membranes based on functional biocompatible polymers can be regarded as a useful model system to study biological interactions, e.g. antibody-antigen interactions or protein polymer interactions. These model systems may give a better insight into these processes and may help to find suitable polymeric structures offering biocompatibility as well as reduced polymer protein interaction. In this respect, Langmuir-Blodgett (LB) layer formation at the air/water (A/W) interface is studied in respect to polymer architecture in this article. For this purpose, narrowly distributed N-(2-hydroxypropyl)-methacrylamide (HPMA) random and block copolymers have been prepared by the RAFT polymerization meth…
Radioactive labeling of defined HPMA-based polymeric structures using [18F]FETos for in vivo imaging by positron emission tomography.
2009
During the last decades polymer-based nanomedicine has turned out to be a promising tool in modern pharmaceutics. The following article describes the synthesis of well-defined random and block copolymers by RAFT polymerization with potential medical application. The polymers have been labeled with the positron-emitting nuclide fluorine-18. The polymeric structures are based on the biocompatible N-(2-hydroxypropyl)-methacrylamide (HPMA). To achieve these structures, functional reactive ester polymers with a molecular weight within the range of 25,000-110,000 g/mol were aminolyzed by 2-hydroxypropylamine and tyramine (3%) to form (18)F-labelable HPMA-polymer precursors. The labeling procedure…
Functionalization of TiO2Nanoparticles with Semiconducting Polymers Containing a Photocleavable Anchor Group and Separation via Irradiation Afterward
2014
The controlled radical polymerization (RAFT polymerization) of semiconducting polymers based on poly(4,4′-dimethyl-triphenylamine) is described. These polymers are afterward end-functionalized with a photocleavable group and an anchor unit (catechol) for oxidic nanoparticles (NPs). Serving as a reference, polystyrene oligomers with the same end groups are also synthesized. Using these polymers allows functionalization of the TiO2-NPs, leading to an improved solubility and miscibility in organic solvents or polymer matrices. Irradiation in the UV region is used to split the photocleavable group and remove the polymer chains from the NPs, which leads to their aggregation.
Liquid crystalline phases from polymer functionalized ferri-magnetic Fe3O4nanorods
2017
Here, we present the surface functionalization of anisotropic in form ferri-magnetic Fe3O4-nanorods (NRs) with a diblock copolymer, having a PMMA- or PDEGMEMA-block, for solubilization, and a dopamine anchor block. These polymers were synthesized through RAFT polymerization via a macro-initiator approach. The successful surface functionalization, performed via a grafting-to method, was monitored using TGA, IR and TEM measurements. The NRs were very soluble in organic solvents after functionalization. Afterwards, the liquid crystalline (LC) behavior was investigated. During solvent evaporation, birefringent domains were formed. The self-assembly into lyotropic LC structures could be observed…
Temperature-Responsive Surface Coatings Based on Poly(methylsilsesquioxane)-hybrid Polymers
2007
The present paper presents a new method to build up temperature-responsive surfaces. First a poly(silsesquioxane)-block-poly(N-isopropyl-acrylamide) (PMSSQ-b-PNIPAM) was successfully synthesized using RAFT polymerization. Spin-coating or dip-coating of PMSSQ-b-PNIPAM onto glass surfaces resulted in temperature-responsive surfaces. Surface ATR FT-IR measurements proofed the successful surface modification using PMSSQ-b-PNIPAM. IR fine structures of PNIPAM and PMSSQ could be assigned, respectively. In capillary rise experiments a change of the meniscus height measured at temperatures below or above LCST was observed, indicating a different wetting behavior. Thus, a simple spin- or dip-coating…