Search results for "Roche"
showing 10 items of 2666 documents
Micelles in Mixtures of Sodium Dodecyl Sulfate and a Bolaform Surfactant
2006
Mixtures composed of water, sodium dodecyl sulfate (SDS), and a bolaform surfactant with two aza-crown ethers as polar headgroups (termed Bola C-16) were investigated by modulating the mole ratios between the components. The two surfactants have ionic and nonionic, but ionizable, headgroups, respectively. The ionization is due to the complexation of alkali ions by the aza-crown ether unit(s). Structural, thermodynamic, and transport properties of the above mixtures were investigated. Results from surface tension, translational self-diffusion, and small angle neutron scattering ( SANS) are reported and discussed. Interactions between the two surfactants to form mixed micelles result in a com…
Le petit mobilier en fer des habitats du Hallstatt D-La Tène A : un mobilier sous-exploité
2007
Modern excavations of settlement sites from the end of the First Iron Age and the beginning of the second, together with a re-examination of those undertaken in the past, permit us to better approach some material that has traditionally been neglected as a result of its unpromising aspect: notably some of the iron material. This article will attempt to show the diversity of this material, and some new methods permitting its quantification. The aim is to deepen our understanding of the role and status of this metal in Hallstatt society by a consideration of the material from occupation sites as opposed to funerary monuments.
The competency-based approach in developing countries
2013
For decades, all analyzes converge on the idea of the relative inefficiency of education systems in sub-Saharan Africa. Dropout, repetition, overstaffing, low quality of learning student failure and obsolescence of facilities, teaching materials and teachers, including sometimes the levels and quality of education remain somewhat uncertain, inadequate educational programs. In short, these are some of the ills that plague these systems and confirm the findings made by many reports.Given this weakness finding, educational authorities, supported by international aid mobilized in many countries to improve their systems to qualitatively, but also quantitatively equity because we must not forget …
STUDY OF LARGE PELAGIC FISH LIFE-HISTORY TRAITS IN THE CENTRAL MEDITERRANEAN SEA AND PROJECTION UNDER FUTURE CLIMATE CHANGE SCENARIOS
2022
One of the most sensitive life periods for each species is the first life stages (larval and juvenile). The survival rates of pelagic fish larvae in these phases are usually very low and subject to fluctuations, consequently affecting the recruitment of new generations. From historical Tuna landing data, the stock's abundance is fluctuating, especially for Atlantic Bluefin Tuna (ABT) (Thunnus thynnus, Linnaeus, 1758) Eastern stock. It is the largest Mediterranean Tuna and one of the most expensive species in the world. Some studies hypothesized that the fluctuations are dictated by environmental factors, particularly in the early life stages. Therefore, it appears necessary to better unders…
Unveiling the Relationship Between Sea Surface Hydrographic Patterns and Tuna Larval Distribution in the Central Mediterranean Sea
2021
Thunnus thynnus (Atlantic bluefin tuna, ABT) and other tuna species reproduce in the Mediterranean Sea during the summer period. Despite the Central Mediterranean Sea, the Strait of Sicily in particular, being a key spawning site for many tuna species, little is known on the effects of oceanographic variability on their larval distribution in this area. The abundance and presence-absence of larval specimens for three tuna species (ABT, bullet tuna and albacore) were modeled in order to examine their relationships with environmental factors, by analysing historical in situ information collected during seven annual surveys (2010–2016). The results revealed that most tuna larvae for the three …
STABILITY AND ORGANOCATALYTIC EFFICIENCY OF N-HETEROCYCLIC CARBENES ELECTROGENERATED IN ORGANIC SOLVENTS FROM IMIDAZOLIUM IONIC LIQUIDS
2015
The kinetic of degradation of 1-butyl-3-methylimidazole-2-ylidene (selected as model N-heterocyclic carbene - NHC), generated in organic solvents by cathodic reduction of the parent 1-butyl-3- methylimidazolium salts BMIm-X, was studied by a simple voltammetric analysis. The effect of NHC degradation rate on the efficiency of an organocatalyzed reaction (the synthesis of g-butyrolactone from cinnamaldehyde and trifluoromethylacetophenone) was investigated. The nature of the solvent and of the anion X have a remarkable effect on the stability of the NHC, the bis(trifluoromethylsulfonyl) imide anion being the best for a long lasting carbene (while acetonitrile seems to be the worst solvent). …
Crosslinking of polymers activated by electrogenerated hydroxyl radicals.
2015
Nanogels (NGs) are systems created by crosslinking of polymers taking nanosized dimensions and they have been proposed for biomedical and pharmaceutical applications due to their soft consistency, biocompatibility and good chemical properties that make them excellent drug delivery agents (1). Differently from typical hydrogels, nanogels are able to dissolve in solvents and to swell releasing the drug molecules loaded in the nano-vector. Furthermore, if properly functionalized with reactive groups, these materials can represent a very interestingly vector for different pharmacological treatments (2). Several methods have been investigated to prepare polymeric nanogels starting from preformed…
Interaction en champ proche entre une sonde nanométrique et le champ de composants à cristal photonique:- interaction faible, microscopie spatialemen…
2008
With the improvement of fabrication techniques, the nanophotonics and more especially the photonics crystals which are periodic structure at the Wavelength scale have been recently developed. In this work, by using a scanning near-field optical microscope, we study such components. Firslty, we use the local probe to visualize the light distribution inside photonic crystal microcavities etched into semiconductor III/V. We focus us on the explanation of the near-field maps formation and on the probe influence on these maps. Thus, we have visualize degeneracy splitting of optical cavity modes and clearly observed in near-field cavity modes which were not visible in far-field. Moreover, in the …
Etude en champ proche et en champ lointain de composants périodiquement nanostructurés : cristaux photoniques et tamis à photons
2004
Recently, a new class of optical components is appeared. Its main characteristic is to be formed by a periodical sub-wavelength pattern, leading to the apparition of a spectral domain where propagation of light inside the structure is forbidden -- a photonic bandgap. This work is devoted to the study in the near- and far-field of two kinds of periodical optical components: photonic crystals (PCs) and nanostructured metallic films that exhibit the so-called enhanced transmission. First, we study two-dimensional PCs with a scanning near-field optical microscope (SNOM) in collection mode. With this SNOM, we directly map the intensity distribution inside PC-based microcavities. We also evidence…
Preparation of Nd:YAG Nanopowder in a Confined Environment
2007
Nanopowder of yttrium aluminum garnet (YAG, Y3Al5O12) doped with neodymium ions (Nd:YAG) was prepared in the water/cetyltrimethylammonium bromide/1-butanol/n-heptane system. Aluminum, yttrium, and neodymium nitrates were used as starting materials, and ammonia was used as a precipitating agent. Coprecipitate hydroxide precursors where thermally treated at 900 degrees C to achieve the garnet phase. The starting system with and without reactants was characterized by means of the small-angle neutron scattering technique. The system, without reactants, is constituted by a bicontinuous structure laying near the borderline with the lamellar phase region. The introduction of nitrates stabilizes th…