Search results for "Rongalite"

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X-ray absorption spectroscopic study of trivalent and tetravalent actinides in solution at varying pH values

2009

Abstract We perform X-ray absorption spectroscopy (XAS) investigations to monitor the stabilization of redox sensitive trivalent and tetravalent actinide ions in solution at acidic conditions in a pH range from 0 to 3 after treatment with holding reductants, hydroxylamine hydrochloride (NH2OHHCl) and Rongalite (sodium hydroxymethanesulfinate, CH3NaO3S). X-ray absorption near edge structure (XANES) measurements clearly demonstrate the stability of the actinide species for several hours under the given experimental conditions. Hence, structural parameters can be accurately derived by extended X-ray absorption fine structure (EXAFS) investigations. The coordination structure of oxygen atoms be…

RongaliteX-ray absorption spectroscopychemistry.chemical_compoundAbsorption spectroscopyExtended X-ray absorption fine structureChemistryMetal ions in aqueous solutionInorganic chemistryActinidePhysical and Theoretical ChemistryAbsorption (chemistry)XANESRadiochimica Acta

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PEPhysical Sciences and Engineering
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