Search results for "Rossi"
showing 10 items of 267 documents
Non nuocere, aiutare, non offendere. Rileggere il De officiis di Cicerone nel conflitto tra prossimi e lontani
2019
Can Cicero’s De officiis be considered as an excuse for justifying and supporting the common idea that rights, aid and solidarity have been reserved only to those are “close” to us? In the current debate concerning the real universality and the value of human rights, the interpretation of the last work of Arpino’s author, framed in its historical and cultural context, may contribute to a fair restitution of the meaning we assume for the virtue named ratio societatis et communitatis.
Il valore della prossimità per una nuova interfaccia metabolica
2016
L’interfaccia territoriale rappresenta oggi una ricchezza di valori e presenta una sfida per gli stakeholder del territorio (pubbliche amministrazioni, imprese, commercio, imprese sociali)2. L’interfaccia – mutuando la definizione che danno le discipline tecniche al termine con il significato di dispositivo fisico o virtuale che permette la comunicazione fra due o più entità di tipo diverso – non può più essere considerata solo come un “punto di contatto”, non è certo un limite tra elementi che si traguardano che, molto spesso, negando il concetto stesso di prossimità, si trasformano in rigidi confini geografici, normativi, sociali e culturali, ma deve essere considerata come un elemento di…
Riflessioni sul ruolo dell'assistente sociale nella presa in carico di migranti vittime di violenza di prossimità
2018
Le autrici affrontano il problema della violenza di prossimità subita dai rifugiati / richiedenti asilo durante il loro percorso migratorio. Inoltre, riflettono sul ruolo assunto dall'assistente sociale nel cosiddetto "processo di accompagnamento" verso un percorso di sensibilizzazione, emancipazione e responsabilizzazione personale delle vittime. The authors addresses the issue of proximity violence suffered by refugees/asylum seekers during their migration path. Furthermore, they reflects on the role assumed by the social worker on the so-called “accompaniment process” towards an awareness path, emancipation and personal empowerment of the victims.
A new Northeast Asian Lynceus (Crustacea: Branchiopoda: Laevicaudata) with uniquely modified thoracopods and an evaluation of DNA barcoding for clam …
2020
A new species of smooth clam shrimp (Branchiopoda: Laevicaudata) from Mongolia and China is described here based on both morphological and genetic differences. The new species, Lynceus grossipedia n. sp., has unique features, including asymmetrically modified male thoracopods (left side thoracopods III-VI), male claspers “movable finger” (=endopod) with delicate setation, and broad, bicarinate male and female rostrum. Lynceus grossipedia n. sp. is compared with the genera Paralimnetis Gurney, 1931 and Lynceiopsis Daday, 1912 and a recently described Lynceus Müller, 1776 from China, also showing modified male thoracopods. Lynceus mandsuricus Daday, 1927 is declared nomen inquirendum. DNA bar…
Molecular Basis of DNA Photodimerization: Intrinsic Production of Cyclobutane Cytosine Dimers
2008
Based on CASPT2 results, the present contribution establishes for the first time that cytosine photodimer formation (CC) is mediated along the triplet and singlet manifold by a singlet-triplet crossing, (T1/S0)X, and by a conical intersection, (S1/S0)CI, respectively. The former can be accessed in a barrierless way from a great variety of photochemical avenues and exhibits a covalent single bond between the ethene C6-C6' carbon atoms of each monomer. The efficiency of the stepwise triplet mechanism, however, would be modulated by the effectiveness of the intersystem crossing mechanism. The results provide the grounds for the understanding of the potential photogenotoxicity of endogenous and…
Photostability and Photoreactivity in Biomolecules: Quantum Chemistry of Nucleic Acid Base Monomers and Dimers
2008
The great potentials of high-level ab initio methods, in particular, the CASPT2//CASSCF protocol, are fully illustrated through: (i) the study of ultrafast energy relaxation in DNA/RNA base monomers, (ii) the intrinsic population mechanism of the lowest triplet state, and (iii) how bioexcimers can be considered as precursors of charge transfer and photoinduced reactivity. In order to describe these processes properly, the presence of conical intersections (CIs) and the topology of the involved pathways have to be determined correctly. Thus, in theoretical calculations the dynamic electronic correlation has to be considered. The accessibility of the CIs (or the seam of CIs) becomes crucial t…
Inverse square root level-crossing quantum two-state model
2020
We introduce a new unconditionally solvable level-crossing two-state model given by a constant-amplitude optical field configuration for which the detuning is an inverse-square-root function of time. This is a member of one of the five families of bi-confluent Heun models. We prove that this is the only non-classical exactly solvable field configuration among the bi-confluent Heun classes, solvable in terms of finite sums of the Hermite functions. The general solution of the two-state problem for this model is written in terms of four Hermite functions of a shifted and scaled argument (each of the two fundamental solutions presents an irreducible combination of two Hermite functions). We pr…
Photosensitization and phototherapy with furocoumarins: A quantum-chemical study
2008
Abstract The effect of electromagnetic radiation on biological objects extends from heating to complex photochemistry, and includes DNA alteration, that properly modified in damaged cells may entail beneficial effects. In this regard, psoralen + UV-A (PUVA) therapy, in which furocoumarins, psoralen-like chromophores, are used as photosensitizers and photoreactants with DNA bases, is one of the most promising strategies against a plethora of diseases. Understanding the underlying photochemical mechanisms is crucial to design effective drugs without undesired side effects. We have undertaken a quantum-mechanical study on the photophysics and photochemistry of furocoumarins, analyzing firstly …
Temperature and excitation energy dependence of decay processes of luminescence in Ge-doped silica
2003
We report experimental results on the time decay of photoluminescence at 4.2 eV in Ge-doped silica. This optical emission is assigned to a singlet-singlet transition between electronic states localized on an oxygen deficiency nearby a Ge atom and its radiative decay rate is in competition with an intersystem crossing mechanism that populates an excited triplet state. We investigate the dependence of the lifetime of this photoluminescence on the temperature, in the 6--295 K range, and on the excitation energy, in the ultraviolet and vacuum ultraviolet region. The mean value of the decay time decreases on increasing the temperature, in agreement with the phonon-assisted nature of the intersys…
Exploring two-state reaction pathways in the photodimerization of cyclohexadiene.
2006
The ground- (S0) and lowest triplet-state (T1) pathways associated with dimerization of cyclohexadiene to give [2+2] and [4+2] cycloadducts have been theoretically studied at the UBLYP and UB3LYP levels of theory with the 6-31G* basis set. The DFT energies were validated by CCSD(T) single-point energy calculations. These cycloaddition reactions follow stepwise mechanisms with formation of bis-allylic biradical (BB) intermediates. In the S0 ground state, the interaction between two cyclohexadiene molecules with formation of BB intermediate IN(S0) has a large activation enthalpy of 32.0 kcal mol(-1). On the other hand, C-C bond-formation in the lowest triplet state (T1) leading to BB intermed…