Search results for "Rotational spectroscopy"

Theoretical rotational constants of MeCnN species

1990

Abstract By means of SCF HF “ab initio” calculations with STO-3G and 6-31G basis sets, the geometric parameters of methylcyanopolyynes (MeCnN n=3, 5, 7 and 9) have been obtained. B0=0.3748 GHz for MeC7N and B0=0.2708 GHz for MeC9N, with a STO-3G basis set, were obtained. Both species, unstable in the laboratory, are still undetected in the interstellar medium, although their existence is very probable.

High-resolution stimulated Raman spectroscopy of O2

1992

Abstract The S S and O O branches of the fundamental vibrational band of molecular oxygen in its electronic ground state have been resolved for the first time in Raman spectroscopy. The spectra have been observed, at room temperature and low pressure, with a stimulated Raman scattering (S.R.S.) spectrometer including a multipass cell. From these accurate Raman data combined with microwave data, we have improved the values of the vibrational, rotational, spin-spin, and spin-rotation interactions constants in the v = 1 vibrational state. Moreover, Raman Q branches of the first and second hot-bands have been recorded, allowing us to determine a set of molecular parameters for the v = 2 and v =…

High-resolution microwave spectroscopy on trapped ion clouds

1994

Ion traps are particular usefully devices for precision spectroscopy on ionic ground states in the microwave domain. Although ultimate precision is achieved only with laser-cooled single ions, in many cases the precision obtained using large uncooled clouds of ions is sufficient for many requirements in atomic physics. The stronger signal in this case makes possible experiments on forbidden transitions or on systems with complex spectra and many substates. Recent examples of laser-microwave double resonance spectra on Pb+ and Eu+ are presented along with attempts to laser-cool a large ion cloud in order to reduce uncertainties from the second-order Doppler effect.

Ultrahigh-Resolution Microwave Spectroscopy on TrappedYb+171Ions

1982

Unveiling the Sulfur–Sulfur Bridge: Accurate Structural and Energetic Characterization of a Homochalcogen Intermolecular Bond

2018

open 12 si MIUR “PRIN 2015” funds (Grant Number 2015F59J3R) By combining rotational spectroscopy in supersonic expansion with the capability of state-of-the-art quantum-chemical computations in accurately determining structural and energetic properties, the genuine nature of a sulfur–sulfur chalcogen bond between dimethyl sulfide and sulfur dioxide has been unveiled in a gas-jet environment free from collision, solvent and matrix perturbations. A SAPT analysis pointed out that electrostatic S⋅⋅⋅S interactions play the dominant role in determining the stability of the complex, largely overcoming dispersion and C−H⋅⋅⋅O hydrogen-bond contributions. Indeed, in agreement with the analysis of the…

Determination of accurate rest frequencies and hyperfine structure parameters of cyanobutadiyne, HC5N

2020

Very accurate transition frequencies of HC$_5$N were determined between 5.3 and 21.4 GHz with a Fourier transform microwave spectrometer. The molecules were generated by passing a mixture of HC$_3$N and C$_2$H$_2$ highly diluted in neon through a discharge valve followed by supersonic expansion into the Fabry-Perot cavity of the spectrometer. The accuracies of the data permitted us to improve the experimental $^{14}$N nuclear quadrupole coupling parameter considerably and the first experimental determination of the $^{14}$N nuclear spin-rotation parameter. The transition frequencies are also well suited to determine in astronomical observations the local speed of rest velocities in molecula…

Physics at CERN's Antiproton Decelerator

2013

The Antiproton Decelerator of CERN began operation in 1999 to serve experiments for studies of CPT invariance by precision laser and microwave spectroscopy of antihydrogen ($\bar{\rm H}$) and antiprotonic helium ($\bar{p}{\rm He}^+$). The first 12 years of operation saw cold $\bar{\rm H}$ synthesized by overlapping clouds of positrons ($e^+$) and antiprotons ($\bar{p}$) confined in magnetic Penning traps. Cold $\bar{\rm H}$ was also produced in collisions between Rydberg positronium atoms and $\bar{p}$. Ground-state $\bar{\rm H}$ was later trapped for up to $\sim 1000$ s in a magnetic bottle trap, and microwave transitions excited between its hyperfine levels. In the $\bar{p}{\rm He}^+$ ato…

Ion traps and their application in spectroscopy

1996

The general behaviour of Paul- and Penning ion traps is briefly described and some emphasis is given to the storage of highly charged ions. In the second part recent examples of laser and microwave spectroscopy on stored ions are given which illustrate the high precision and high sensitivity of these devices. We point out the possible application to laser spectroscopy on highly charged ions.

Back Cover: Microwave spectroscopy on heavy-fermion systems: Probing the dynamics of charges and magnetic moments (Phys. Status Solidi B 3/2013)

2013

Radio and Microwave Spectroscopy of 0.2PMN-0.4PSN-0.4PZN Relaxor Ceramics

2005

Dielectric spectroscopy results of 0.2PbMg 1/3 Nb 2/3 O 3 -0.4PbSc 1/2 Nb 1/2 O 3 -0.4PbZn 1/3 Nb 2/3 O 3 ceramics are reported for 200 < T < 450 K and 20 Hz < v < 11 GHz. Dielectric constant is very high (more than 12000) in the vicinity of the peak. Anomalous broad dielectric relaxation has been observed near and below the temperature of the maximum permittivity, T m (at 1 kHz). The distribution of relaxation times have been calculated directly from the dielectric spectra. At higher temperatures than the maximum permittivity, T m the distribution of the relaxation times is symmetrically shaped (Cole-Cole function satisfactory describes the dielectric response). At lower temperatures, the …