Search results for "Roth"

Charm quark mass with calibrated uncertainty

2016

We determine the charm quark mass ${\hat m}_c({\hat m}_c)$ from QCD sum rules of moments of the vector current correlator calculated in perturbative QCD. Only experimental data for the charm resonances below the continuum threshold are needed in our approach, while the continuum contribution is determined by requiring self-consistency between various sum rules, including the one for the zeroth moment. Existing data from the continuum region can then be used to bound the theoretical error. Our result is ${\hat m}_c({\hat m}_c) = 1272 \pm 8$ MeV for $\hat\alpha_s(M_Z) = 0.1182$. Special attention is given to the question how to quantify and justify the uncertainty.

Umbrales de transformación en la transición de la literatura infantil a la juvenil: el símbolo del espejo

2018

This article approaches the study of children’s literature as a threshold of change that allows readers to explore the reality around them, imagine other worlds and understand other perspectives. Based on the notion of the child’s cognitive development organized into four stages ―pre-reading, fantastic stage, fantastic-realistic stage and aesthetics stage― reading becomes a resource to combine fantasy and experience where the mirror is a highly suggestive element and prone to hundreds of interpretations and applications as can be seen in the plots of well-known books such as the brother Grimm’s Snow White, Lewis Carroll’s Through the Looking-Glass, Michael Ende’s The Neverending story and J…

Phosphorothioate cap analogs increase stability and translational efficiency of RNA vaccines in immature dendritic cells and induce superior immune r…

2010

Vaccination with in vitro transcribed RNA coding for tumor antigens is considered a promising approach for cancer immunotherapy and has already entered human clinical testing. One of the basic objectives for development of RNA as a drug is the optimization of immunobioavailability of the encoded antigen in vivo. By analyzing the effect of different synthetic 5' mRNA cap analogs on the kinetics of the encoded protein, we found that m(2)(7,2'-O)Gpp(S)pG (beta-S-ARCA) phosphorothioate caps, in particular the D1 diastereoisomer, profoundly enhance RNA stability and translational efficiency in immature but not mature dendritic cells. Moreover, in vivo delivery of the antigen as beta-S-ARCA(D1)-c…

Pb–Pb age, stable isotope and chemical composition of Archaean magnesite, Barberton Greenstone Belt, South Africa

2010

International audience; Trace-element, carbon, oxygen and lead-isotope analyses were carried out to determine the formation mode and crystallization age of magnesite from the Budd ultramafic complex of the Archaean Barberton Greenstone Belt, South Africa. Its significantly high Ti contents probably relate to a soluble Ti-rich accessory mineral, probably dissolved during magnesite precipitation. Primitive mantle-normalized REE patterns of the magnesite show negative Ce and Eu anomalies induced by two events: (1) the Eu anomaly indicates reducing conditions probably induced by the emplacement of the ultramafic source rock; (2) the Ce anomaly implies oxidizing conditions, probably during a hyd…

Zirconium–hafnium and rare earth element signatures discriminating the effect of atmospheric fallout from hydrothermal input in volcanic lake water

2016

The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidicwaters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr a nd Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y-Ho and Zr-Hf (twin pairs) have a…

Discrimination between effects induced by microbial activity and water-rock interactions under hydrothermal conditions according to REE behaviour

2013

AbstractRare earth elements (REE) were investigated in siliceous stromatolites forming in the Specchio di Venere Lake on Pantelleria Island. Chondrite-normalised patterns show significant La enrichments and Eu depletions suggesting that fluids involved in stromatolite growth experienced strong rock-water interactions under hydrothermal conditions. At the same time, enrichments in heavy REE (HREE) with respect to intermediate REE (MREE) suggest that hydrothermal fluids interacted with microbial mats during deposition of the stromatolites. The above-mentioned features suggest that rock-water interactions and bacterial activity were simultaneously recorded in the REE patterns of stromatolites,…

Geochemistry of Zr, Hf and REE in extreme water environments: hyperacid, hyper saline and lake waters in hydrothermal systems

This PhD thesis concerns the geochemistry of Zr, Hf and REE in extreme water environments characterized by a wide spectrum of chemical physical-parameters and compositions. The investigations were carried out in hypersaline waters covering a wide range of Eh values along Dead Sea Fault (Israel), in hyperacid waters circulating in Nevado del Ruiz volcano-hydrothermal system (Colombia) and in CO2-rich waters belonging to the Pantelleria volcano-hydrothermal system (Italy), including the alkaline lake “Specchio di Venere” formed within a calderic depression. The wide spectrum of chemical-physical conditions and various water chemical compositions interacting with different solid phases allowed…

Diastereoselective Synthesis of Spiro[pyrazolone-4,3′-tetrahydrothiophenes] via a Sulfa-Michael/Aldol Domino Reaction

2016

Synthesis : journal of synthetic organic chemistry 48(23), 4091-4098(2016). doi:10.1055/s-0035-1562473

The effect of trivalent framework heteroatoms in Cu-CHA on the Selective Catalytic Reduction of NO

2021

Abstract The effect of the trivalent framework atoms (Si4+/M3+ = 13-105) in Cu exchanged CHA-type zeolites was investigated for the selective catalytic reduction of NO with NH3. While the increased hydrophobicity of B-CHA compared to Al-CHA could make it a good candidate for low temperature SCR, the material was too unstable under reaction conditions and the exchanged Cu2+ did not remain isolated. Consequently a lower activity and selectivity than for Al-CHA were observed. Ga-CHA on the other hand showed a similar Cu2+ speciation as Al-CHA at similar Si4+/M3+ ratios. The difference in catalytic activity was remarkably small. While Ga-CHA was less stable upon hydrothermal aging, this was mar…

Synthesis of Nanoferroics

2013

The Chapter covers the technological aspects of many chemical and physico-chemical nanofabrication methods relevant to making nanoferroic materials and composites. First, the classification of relevant synthesis methods of nanoferroics has been presented. Synthesis of particular nanoferroics with different chemical bonding like metallic, oxide and non-oxide compounds is considered in details. Among the methods, the mechanochemical, sonochemical, hydrothermal, co-precipitation, emulsion, thermal decomposition of unstable precursors have been analyzed. The competition between new phase nucleation and nuclei growth has been revealed to be controlled using feedback between reaction rate and tem…