Search results for "Rubber"
showing 10 items of 146 documents
Physical Cross Links in Amorphous PET, Influence of Cooling Rate and Ageing
2003
A Continuous Cooling Transformation (CCT) procedure can be used to distinguish the initial “state” of the amorphous PET samples produced upon solidification from the melt at different cooling rates. The material frozen at this stage behaves as a rubber when brought above the Tg due to the onset of physical cross links. The rubber is not a stable network, however, since physical cross links may eventually dissolve. Their size distribution, and possibly their number, depend on cooling rate and ageing. Some may be even stable above the glass transition and act as nuclei for further crystallization from the glass. Upon increasing cooling rate, size distribution becomes smaller and stability of …
Polymeric scaffolds prepared via Thermally Induced Phase Separation (TIPS): Tuning of structure and morphology
2007
Scaffolds suitable for tissue engineering applications were prepared by Thermally Induced Phase Separation (TIPS) starting from a ternary solution PLLA/dioxane/water. The experimental protocol consisted of three consecutive steps, a first quench from the homogeneous solution to an appropriate demixing temperature (within the metastable region), a holding stage for a given residence time and a final quench from the demixing temperature to a low temperature (within the unstable region). A large variety of morphologies, in terms of average pore size and interconnection, were obtained upon modifying the demixing time and temperature, owing to the interplay of nucleation and growth processes dur…
Partial Discharge on-line measures in cable's EPR insulation
2004
In this paper, an experimental study, carried out on an operating MV cable, is presented. The aim is to identify, locate and characterize defects in the cable's EPR (ethylene-propylene copolymer rubber) insulation. Direct partial discharge measurements have been compared to those obtained by high frequency electromagnetic field measures. The latter have been carried out using a sensor which does not require any galvanic connection with the system under test and that performs an intrinsic localization of the defect. Moreover, an analysis of an MV cable junction has been carried out using the same tools.
Glassy PEEK‐WC vs Rubbery Pebax®1657 Polymers: Effect on the Gas Transport in CuNi‐MOF Based Mixed Matrix Membranes
2020
Mixed matrix membranes (MMMs) are seen as promising candidates to overcome the fundamental limit of polymeric membranes, known as the so-called Robeson upper bound, which defines the best compromise between permeability and selectivity of neat polymeric membranes. To overcome this limit, the permeability of the filler particles in the MMM must be carefully matched with that of the polymer matrix. The present work shows that it is not sufficient to match only the permeability of the polymer and the dispersed phase, but that one should consider also the individual contributions of the diffusivity and the solubility of the gas in both components. Here we compare the gas transport performance o…
Landfill gas upgrading with pilot-scale water scrubber: Performance assessment with absorption water recycling
2012
Abstract A pilot-scale counter current absorption process for upgrading municipal solid waste (MSW) landfill gas to produce vehicle fuel was studied using absorption, desorption and drying units and water as an absorbent. Continuous water recycling was used without adding new water to the system. The process parameters were defined by a previous study made with this pilot system. The effect of pressure (20–25 bar), temperature (10–25 °C) and water flow speed (5.5–11 l/min) on the upgrading performance, trace compounds (siloxanes, halogenated compounds) and water quality were investigated. Raw landfill gas flow was kept constant at 7.41 Nm3/h. Methane (CH4) and carbon dioxide (CO2) contents …
Toward more realistic viscosity measurements of tyre rubber–bitumen blends
2014
AbstractThe measurement of rheological properties of the tyre rubber bitumen blends is often challenging due to presence of suspended tyre rubber’s crumbs. Furthermore, the phase separation during the course of measurements makes the viscosity of these non-homogeneous blends difficult to ascertain. In this study, a new dual helical impeller was designed and manufactured to be used with a rotational viscometer in order to have a real-time control of the viscosity while performing a laboratory mixing of the blends. Layer based manufacturing techniques showed to be a convenient method to produce complex shaped impeller prototypes before manufacturing the more expensive stainless steel assembly…
Estudio del embodiment y las alteraciones de la integración multisensorial corporal y su papel en la psicopatología de los trastornos de la conducta …
2016
En los últimos años, ha habido un interés renovado sobre los estudios del cuerpo, fundamentalmente a través de las teorías del embodiment. Entre sus muchas definiciones, la experiencia del embodiment se describe específicamente como el sentido mediante el cual un individuo se localiza dentro de sus límites físicos de su propio cuerpo. Ese sentido de localización se complementa con el de auto-reconocimiento y propiedad corporal, que se conforman desde la integración de diversas señales sensoriales del cuerpo (ej., visión, tacto, propiocepción, etc.), junto con el sentido de la agencia del cuerpo, es decir, la conciencia subjetiva de que nosotros somos quienes ejecutamos y controlamos las acc…
The effect of a liquid CTBN rubber modifier on the thermo-kinetic parameters of an epoxy resin during a pultrusion process
2003
Abstract Rheo-kinetic behaviour of an epoxy resin, coupled with an anhydride hardener, with different CTBN liquid rubber concentration (0–15 phr), used in fibre reinforced plastics, was analysed comparing experimental data with theoretical models. The modelling of technological pultrusion process for thermoset matrix composites, developed through a numerical code realised with MATLAB, is reported, too. The model includes conduction and cure heat, degree of cure and viscosity evolution during the curing within the die. Considerable differences in process condition, using different rubber amount, are obtained. The numerical modelling of process conditions shows that the CTBN rubber presence i…
Modelling of phase transitions and residual thermal stress of CTBN rubber modified epoxy resins during a pultrusion process
2007
Abstract The implicit finite difference and fourth order Runge-Kutta method are used both to solve the heat transfer problem in the pultrusion reaction and to calculate the temperature and conversion distributions within a thermoset composite profile. The aim of our work is to study the influence of a rubbery phase added to the epoxy matrix in production conditions. The results have shown that the rubber modified systems have a low exothermic temperature peak value, so that neither the amount of cured resin nor the final product properties are limited. First of all we will show that the phase transition (gelation and vitrification) zones within the die change as the amount of rubber varies …
Constructive Optimization of Vulcanization Installations in Order to Improve the Performance of Conveyor Belts
2019
Conveyor belts of special importance must have superior mechanical characteristics. The joining by vulcanization of the conveyor belts allows to obtain superior performances, but it has been found that at the vulcanizing joint of the conveyor belts, there is a &ldquo