Search results for "Rut"

The White Stone of South-Eastern Sicily: Urban and Territorial Identity

2017

La Sicilia è un territorio fortemente "segnato" dall'impiego massiccio della ricca varietà di materiali lapidei che la natura ha messo a disposizione: materia prima dalle differenti qualità petrografiche, colore, caratteristiche tecniche e con una vasta possibilità di impiego, sia come elemento costruttivo sia come pietra ornamentale. La "pietra bianca" di Siracusa, il basalto dell'Etna, la "pietra forte" del ragusano, la pietra di Sabucina di Caltanissetta e Niscemi, le calcareniti e le rocce tufacee delle cave di Carini e Aspra, il calcare grigio di billiemi nel palermitano e il tufo calcareo di Agrigento, caratterizzano gran parte degli insediamenti antropici dell'isola, espressione di u…

A convenient route for the preparation of the monohydride catalyst trans-[RuCl(H)(dppe)2] (dppe=Ph2PCH2CH2PPh2): improved synthesis and crystal struc…

2013

Abstract A novel and improved room temperature synthesis of the monohydride catalyst trans-[RuCl(H)(dppe)2] complex (1, dppe (1,2-bis(diphenylphosphino)ethane) = Ph2PCH2CH2PPh2) proceeds through oxidation of methanol (the solvent) by the pentacoordinated cis-[RuCl(dppe)2][PF6] complex and t-BuOK as the base is described. Compound 1 was fully characterized by NMR (1H, 13C, 31P), ESI-MS(TOF +), FTIR and elemental analysis. The X-ray structure of 1 was reported for the first time and unambiguously confirms the trans-configuration of the complex.

A beam theory for layered composites subjected to uniformly distributed load

2015

A theory for multilayered composite beams undergoing transverse uniformly distributed loads is presented. The formulation starts by assuming a layer-wise kinematical model characterized by third order approximation of the axial displacements and fourth order approximation of the transverse displacements. By enforcing the point-wise balance equations as well as the interface continuity conditions, the layer-wise kinematical model is rewritten in terms of a set of generalized kinematical variables associated with the beam as a whole. Stress resultants are then obtained in terms of the generalized variables derivatives and of the normal stresses applied to the top and bottom surfaces of the la…

Il benessere organizzativo degli operatori penitenziari: i cambiamenti normativi e la trasformazione dei ruoli

2017

Biogenic methane contributes to the food web of a large, shallow lake

2013

Summary Biogenic methane as an alternative carbon and energy source for freshwater organisms has been receiving increasing attention, but the phenomenon is still poorly understood for shallow lakes. We measured the carbon and nitrogen stable isotope signatures (δ13C, δ15N) for key groups of pelagic and benthic organisms, including crustacean zooplankton, chironomid larvae, young-of-the-year and adult fish, to assess whether biogenic methane contributes to pelagic and benthic food webs in a large, shallow lake, Lake Vortsjarv, Estonia. In the southern part of the lake, covered by macrophytes, crustacean zooplankton showed strong seasonal variation of δ13C, with the lowest values occurring in…

Application of the 3-D boundary element method to delaminated composite structures

2013

A three-dimensional boundary element model for anisotropic solids is presented to study the fracture mechanics behavior of delaminated composite structures. The multi-domain technique is implemented to model the layered configurations and the cracks occurring at bi-material interface. The Modified Crack Closure Integral technique is implemented to characterize the fracture mechanics behavior of delaminations in terms of the total energy release rate and mode mix phase angles. Validating analyses, performed on different delaminated configurations, have shown the effectiveness of the proposed approach. Moreover, some original results are presented to investigate the effects of the stacking se…

Bibliometric analysis of publications by South African viticulture and oenology research centres

2012

We analysed the production, impact factor of, and scientific collaboration involved in viticulture and oenology articles associated with South African research centres published in international journals during the period 1990–2009. The articles under scrutiny were obtained from the Science Citation Index database, accessed via the Web of Knowledge platform. The search strategy employed specific viticulture and oenology terms and was restricted to the field ‘topic’. The results showed that 406 articles were published during the review period, with the most number of publications being in the South African Journal of Enology and Viticulture (n = 34), American Journal of Enology and Vit…

The fluxional behaviour of η6(bicyclo[6.2.0]deca-2,4,6-triene) hexacarbonyl diruthenium (Ru-Ru) by 1H and 13C NMR techniques

1977

Abstract The variable temperature 1 H NMR spectra of [Ru 2 (CO) 6 η 6 -C 10 H 12 )] (C 10 H 12 = bicyclo [6.2.0]-deca-2,4,6-triene) shows that this molecule undergoes the fluxional behaviour previously reported for [M 2 (CO) 6 (η 6 -polyolefin)] complexes (M = Fe, Ru) which have in the solid an asymmetric skew-type structure. The use of 13 C NMR techniques, employed for the first time for a diruthenium complex of the above type, allows a comparison of the mechanism of the fluxional process with that of the diiron analog. Although the observed line shape changes of the carbonyl resonances in the two complexes are somewhat different the process are basically the same. In the case of the dirut…

Reactivity of anticancer metallodrugs with serum proteins: New insights from size exclusion chromatography-ICP-MS and ESI-MS

2010

International audience; A method based on the coupling of high resolution size-exclusion liquid chromatography using a polymer stationary phase with inductively coupled plasma mass spectrometry was developed to study the interactions of two metallodrugs - cisplatin and RAPTA-T - with the serum proteins albumin and transferrin. In contrast to previous approaches, the technique allowed the total recovery of the metals from the column and was able to discriminate between the different species of the metallodrugs and their complexes with the proteins at femtomolar detection levels. Metal binding was found to be dependent on the protein concentration and on the incubation time of the sample. Cis…

Novel heterobimetallic radiotheranostic: preparation, activity, and biodistribution.

2014

A novel Ru(II) (arene) theranostic complex is presented. It is based on a 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid macrocycle bearing a triarylphosphine and can be tracked in vivo by using the γ emission of (153) Sm atoms. Notably, the heteroditopic ligand can be selectively metalated with ruthenium at the phosphorus atom despite the presence of other functionalities that are prone to metal coordination. Subsequent labeling with radionuclides such as (153) Sm can then be performed easily. The resulting heterobimetallic complex exhibits favorable solubility and stability properties in biologically relevant media. It also shows in vitro cytotoxicity in line with that expected …