Search results for "SAMPLE"

Automated multi-dimensional liquid chromatography

2004

A comprehensive on-line sample clean-up with an integrated two-dimensional HPLC system was developed for the analysis of natural peptides. Samples comprised of endogenous peptides with molecular weights up to 20 kDa were generated from human hemofiltrate (HF) obtained from patients with chronic renal failure. The (poly-)peptides were separated using novel silica-based restricted access materials with strong cation-exchange functionalities (SCX-RAM). The size-selective sample fractionation step is followed by cation-exchange chromatography as the first dimension. The subsequent second dimension of separation is based on hydrophobic interaction using four parallel short reversed-phase (RP) co…

On-fibre solid-phase microextraction coupled to conventional liquid chromatography versus in-tube solid-phase microextraction coupled to capillary li…

2006

This paper compares the advantages and disadvantages of two different configurations for the extraction of triazines from water samples: (1) on-fibre solid-phase microextraction (SPME) coupled to conventional liquid chromatography (LC); and (2) in-tube SPME coupled to capillary LC. In-tube SPME has been effected either with a packed column or with an open capillary column. A critical evaluation of the main parameters affecting the performance of each method has been carried out in order to select the most suitable approach according to the requirements of the analysis. In the on-fibre SPME configuration the fibre coating was polydimethylsiloxane (PDMS)-divinylbenzene (DVB). The limits of de…

Applications of the X-ray fluorescence analysis to the cultural patrimony of the Comunidad Valenciana (Spain): Painting, metal and paper

1999

We present examples of the application of the X-ray fluorescence (XRF) to the study of the artistic and cultural patrimony of the Comunidad Valenciana in the following areas: a) Valencian paintings of the XV and XVI centuries; b) silver ornaments coming from Iberian towns (s. III b.C.); c) ink and paper samples in manuscripts and engravings of the XVII and XIX centuries. The non destructive analyses are carried out “in situ” using a XRF system that consists of a tube of X-rays of 50 kV and 1 mA, and a detector of Si(Li) with an energy resolution 140 eV (FWHM at 5.9 keV).

Characterization of the bacterial community isolated from a High Middle Age soil sample dated since 980 AD

2016

Mindful Attention Awareness in Spanish Palliative Care Professionals

2017

Abstract. Mindfulness is conceived as a state in which the individual pays full attention to everything that is happening around him or her. The Mindful Attention Awareness Scale (MAAS) is the most popular instrument for assessing mindfulness. Studies on its structure have shown some conflicting results. This study aims to offer new evidence on the dimensionality and reliability of the MAAS, handling both SEM and IRT procedures, in palliative professionals. The sample was composed of 385 professionals from a national online survey. First, two Confirmatory Factor Analyses (CFAs) were specified, estimated, and tested, with one- and two-factor structures, respectively. Second, the Graded Resp…

Changes in the Scheduling Process According to Observed Activity-travel Flexibility

2014

Abstract In this work we analyze the reasons for changing pre-planned activities and travels episodes considering the type of modification observed during the scheduling process. Specifically we selected a small sample from those pre-planned episodes that are no executed at all as a pilot study. The data analyzed was collected in the first wave of a weekly activity-travel panel survey carried out in Valencia (Spain) in 2010. Each survey wave consisted on a face-to-face interview to generate a pre-planned activity agenda for the following week, an activity-travel diary implemented on mobile phones to collect activities and travels as they are executed, and in-depth telephone interviews to in…

Test procedures for obtaining representative extracts suitable for reliable in vitro toxicity assessment of paper and board intended for food contact.

2009

International audience; This paper describes the use of a suite of extraction procedures applicable to the assessment of the in vitro toxicity of paper/board samples intended for food-contact applications. The sample is extracted with ethanol, water, or exposed to modified polyphenylene oxide (Tenax) for fatty, non-fatty and dry food applications, respectively. The water extracts are directly suitable for safety assessment using in vitro bioassays. The ethanol extracts of the paper/board and of the exposed Tenax require pre-concentration to give acceptable sensitivity. This is because the in vitro bioassays can tolerate only a small percentage of added organic solvent before the solvent its…

Search for a Higgs Boson Decaying to Two W Bosons at CDF

2008

We present a search for a Higgs boson decaying to two W bosons in p (p) over bar collisions at root s = 1.96 TeV center-of-mass energy. The data sample corresponds to an integrated luminosity of 3.0 fb(-1) collected with the CDF II detector. We find no evidence for production of a Higgs boson with mass between 110 and 200 GeV/c(2), and determine upper limits on the production cross section. For the mass of 160 GeV/c(2), where the analysis is most sensitive, the observed (expected) limit is 0.7 pb (0.9 pb) at 95% Bayesian credibility level which is 1.7 (2.2) times the standard model cross section.

Study on resolution capacity and secondary mechanisms of three different TSK gels for organic SEC.

2005

A comparative study on the elution behavior in size-exclusion chromatography (SEC) of three polymeric TSK gel packings, named H, H H R , and H X L types, is performed. The deviations of the universal calibration (u.c.) curves of seven solvent-polymer systems show evidence that the existence of secondary effects accompanying the main SEC mechanism. These secondary mechanisms are a consequence of the binary enthalpic interactions between the different components of the chromatographic system, such as polymer-solvent, polymer-gel and solvent-gel. However, in the present case, the observed deviations from a unique u.c. curve can mainly be attributed to adsorption of polymeric solutes (analytes)…

SPME of 52 pesticides and polychlorinated biphenyls: Extraction efficiencies of the SPME coatings poly(dimethylsiloxane), polyacrylate, poly(dimethyl…

2001

Fiber/water partition coefficients (Kfw) of 52 pesticides, including triazines, organophosphorus pesticides, organochlorine pesticides, and polychlorinated biphenyls (PCBs) were experimentally calculated for the five polymeric coatings poly(dimethylsiloxane) (PDMS), polyacrylate (PA), poly(dimethylsiloxane)-Divinylbenzene (PDMS-DVB), Carboxen-poly(dimethylsiloxane) (CAR-PDMS), and Carbowax-divinylbenzene (CW-DVB) commercially available for solid-phase microextraction coupled to gas chromatography. The equilibrium-time profiles for the five coatings were previously studied in order to establish the time needed for equilibrium. To calculate Kfw the amount of analyte extracted at equilibrium w…