Search results for "SAMPLE"
showing 10 items of 2270 documents
A method for the determination of dimethylamine in air by collection on solid support sorbent with subsequent derivatization and spectrophotometric a…
2005
A new method for dimethylamine determination in air is reported. The proposed assay is based on the employment of C18-packed solid phase extraction cartridges for sampling. The retained amine is then derivatized inside the cartridges with the reagent 1,2-naphthoquinone-4-sulfonate. By observing the coloured area of the cartridge, a semiquantitative estimation of the amine can be made. It was also possible to distinguish between primary and secondary amines by visual inspection. Quantitative tests entailed desorption from the cartridges of the derivatives formed, and measurement of the absorbance of the collected extracts. The selected conditions were applied to quantify dimethylamine up to …
Coherent Microscopy for 3-D Movement Monitoring and Super-Resolved Imaging
2010
In this chapter we present three types of microscopy-related configurations while the first one is used for 3-D movement monitoring of the inspected samples, the second one is used for super-resolved 3-D imaging, and the last one presents an overview digital holographic microscopy applications. The first configuration is based on temporal tracking of secondary reflected speckles when imaged by properly defocused optics. We validate the proposed scheme by using it to monitor 3-D spontaneous contraction of rat’s cardiac muscle cells while allowing nanometric tracking accuracy without interferometric recording. The second configuration includes projection of temporally varying speckle patterns…
Super-resolved imaging with randomly distributed, time- and size-varied particles
2009
In this paper we present a super-resolved approach aimed at overcoming the diffraction limit in imaging systems. It is based on place randomly and time-varied particles having different sizes on the top of the sample. By considering particle sizes smaller than the object's minimum detail that an imaging system can resolve, it is possible to recover a high resolution image from a set of low resolution images while before capturing each image we produce a randomly modified distribution of the particles by vibrating the sample. The simulation process as well as experimental results validates the proposed approach that includes effectively decreasing the F number of the imaging system while bei…
Structural study of α-Bi2O3 under pressure
2013
An experimental and theoretical study of the structural properties of monoclinic bismuth oxide (alpha-(BiO3)-O-2) under high pressures is here reported. Both synthetic and mineral bismite powder samples have been compressed up to 45 GPa and their equations of state have been determined with angle-dispersive x-ray diffraction measurements. Experimental results have been also compared with theoretical calculations which suggest the possibility of several phase transitions below 10 GPa. However, experiments reveal only a pressure-induced amorphization between 15 and 25 GPa, depending on sample quality and deviatoric stresses. The amorphous phase has been followed up to 45 GPa and its nature di…
Superresolved phase-shifting Gabor holography by CCD shift
2009
Holography in the Gabor regime is restricted to weak diffraction assumptions. Otherwise, diffraction prevents an accurate recovery of the object's complex wavefront. We have recently proposed a modified Gabor-like setup to extend Gabor's concept to any sample provided that it be non-diffusive. However, the resolution of the final image becomes limited as a consequence of the additional elements considered in the proposed setup. In this paper we present an experimental approach to overcome such a limitation in which the former configuration is used while the CCD camera is shifted to different off-axis positions in order to generate a synthetic aperture. Thus, once the whole image set is reco…
Structure solution of zeolites by automated electron diffraction tomography - Impact and treatment of preferential orientation
2014
Abstract In this paper the reliability of structure solution of nano-crystalline porous compounds with preferred orientation based on automated electron diffraction tomography (ADT) is discussed. It will be shown that the limitations of the data acquisition geometry can be overcome by completing the missing diffraction data with additional diffraction information. Apart from different ways of sample preparation, data merging with either additional ADT data sets or intensities derived from X-ray powder diffraction comprise an effective way to improve the accuracy of the structure solution.
Modelling mode choice for freight transport using advanced choice experiments
2015
Abstract In this paper we use advanced choice modelling techniques to analyse demand for freight transport in a context of modal choice. To this end, a stated preference (SP) survey was conducted in order to estimate freight shipper preferences for the main attributes that define the service offered by the different transport modes. From a methodological point of view, we focus on two critical issues in the construction of efficient choice experiments. Firstly, in obtaining good quality prior information about the parameters; and secondly, in the improved quality of the experimental data by tailoring a specific efficient design for every respondent in the sample. With these data, different …
Using Wave Propagation Simulations and Convolutional Neural Networks to Retrieve Thin Film Thickness from Hyperspectral Images
2021
Ill-posed inversion problems are one of the major challenges when there is a need to combine measurements with the theory and numerical model. In this study, we demonstrate the use of wave propagation simulations to train a convolutional neural network (CNN) for retrieving sub-wavelength thickness profiles of thin film coatings from hyperspectral images. The simulations are produced by solving numerically one-dimensional wave equation with a method based on Discrete Exterior Calculus (DEC). This approach provides a powerful tool to produce large sets of training data for the neural network. CNN was verified by simulated verification sets and measured reflectance spectra, both of which showe…
Sample Preparation to Determine Pharmaceutical and Personal Care Products in an All-Water Matrix: Solid Phase Extraction
2020
© 2020 by the authors. Pharmaceuticals and personal care products (PPCPs) are abundantly used by people, and some of them are excreted unaltered or as metabolites through urine, with the sewage being the most important source to their release to the environment. These compounds are in almost all types of water (wastewater, surface water, groundwater, etc.) at concentrations ranging from ng/L to µg/L. The isolation and concentration of the PPCPs from water achieves the appropriate sensitivity. This step is mostly based on solid-phase extraction (SPE) but also includes other approaches (dispersive liquid-liquid microextraction (DLLME), buckypaper, SPE using multicartridges, etc.). In this rev…
Means of 2D and 3D Shapes and Their Application in Anatomical Atlas Building
2015
This works deals with the concept of mean when applied to 2D or 3D shapes and with its applicability to the construction of digital atlases to be used in digital anatomy. Unlike numerical data, there are several possible definitions of the mean of a shape distribution and procedures for its estimation from a sample of shapes. Most popular definitions are based in the distance function or in the coverage function, each with its strengths and limitations. Closely related to the concept of mean shape is the concept of atlas, here understood as a probability or membership map that tells how likely is that a point belongs to a shape drawn from the shape distribution at hand. We devise a procedur…