Search results for "SELE"

Evaluation of enniatins A, A1, B, B1 and beauvericin in Portuguese cereal-based foods.

2012

Sixty-one samples of Portuguese cereal-based foods were analysed for the occurrence of emerging mycotoxins called enniatins (A, A1, B and B1) and beauvericin. Samples were extracted with a mixture of acetonitrile/water (85/15, v/v) using an Ultra-Turrax homogeniser, and mycotoxins were detected with liquid chromatography coupled to a mass spectrometer. This method was validated and adequate values of recovery (70-103%) and relative standard deviation (15%) were obtained. Signal suppression/enhancement was studied and matrix-matched calibration used to minimise this effect, but no additional clean-up step was necessary. The mass spectrometer was operated in selected reaction monitoring (SRM)…

Chemoenzymatic Synthesis of Functional Sialyl LewisX Mimetics with a Heteroaromatic Core

2014

Functional mimetics of the sialyl Lewis(X) tetrasaccharide were prepared by the enzymatic sialylation of a 1,3-diglycosylated indole and a glycosyl azide, which was subsequently transformed into a 1,4-diglycosylated 1,2,3-triazole, by using the trans-sialidase of Trypanosoma cruzi. These compounds inhibited the binding of E-, L-, and P-selectin-coated nanoparticles to polyacrylamide-bound sialyl-Lewis(X) -containing neighboring sulfated tyrosine residues (sTyr/sLe(X) -PAA) at low or sub-millimolar concentrations. Except for E-selectin, the mimetics showed higher activities than the natural tetrasaccharide.

Author response: Individual differences in selective attention predict speech identification at a cocktail party

2016

Selenium affects biosilica formation in the demosponge Suberites domuncula

2005

Selenium is a trace element found in freshwater and the marine environment. We show that it plays a major role in spicule formation in the demosponge Suberites domuncula. If added to primmorphs, an in vitro sponge cell culture system, it stimulates the formation of siliceous spicules. Using differential display of transcripts, we demonstrate that, after a 72-h exposure of primmorphs to selenium, two genes are up-regulated; one codes for selenoprotein M and the other for a novel spicule-associated protein. The deduced protein sequence of selenoprotein M (14 kDa) shows characteristic features of metazoan selenoproteins. The spicule-associated protein (26 kDa) comprises six characteristic repe…

Spin-crossover in the [Fe(abpt)2(NCX)2] (X=S, Se) system: Structural, Magnetic, calorimetric and photomagnetic studies

1999

[EN] The compounds [Fe(abpt)(2)(NCS)(2)] (1) and [Fe(abpt)(2)(NCSe)(2)] (2) with abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole have been synthesized. The X-ray structures have been determined at 293 K. 1 and 2 are isostructural and crystallize in the monoclinic space group P2(1)/n with Z = 2, a = 8.538(8), b = 10.246(8), c = 16.45(2) Angstrom, beta = 93.98(9)degrees for 1 and a = 8.623(2), b = 10.243(3), c = 16.585(3) Angstrom, beta = 93.19(2)degrees for 2. In both complexes, the coordination core has a similar pseudo-octahedral geometry with the NCS- (1) and NCSe- (2) groups in the trans-position. Variable-temperature magnetic susceptibility data give evidence for a low-spin (LS)high…

Enantioselective Guest Effect on the Spin State of a Chiral Coordination Framework

2015

The diversity of spin crossover (SCO) complexes that, on the one hand, display variable temperature, abruptness and hysteresis of the spin transition, and on the other hand, are spin-sensitive to the various guest molecules, makes these materials unique for the detection of different organic and inorganic compounds. We have developed a homochiral SCO coordination polymer with a spin transition sensitive to the inclusion of the guest 2-butanol, and these solvates with (R)- and (S)-alcohols demonstrate different SCO behaviours depending on the chirality of the organic analyte. A stereoselective response to the guest inclusion is detected as a shift in the temperature of the transition both fr…

Spoken Word Production

2018

This chapter examines two distinct stages of the production of spoken words: the retrieval of semantic and lexical representations, followed by morphological and phonological processing. In both cases, it summarizes models of lexical representation and lexical selection that have focused on the retrieval of single words. These models agree that different lexical information becomes available at different points in time, with access to semantic and syntactic information preceding access to information about lexical form. The structure of this review reflects this dichotomy. Comprehensive production models must also account for the sequencing and timing of lexical processing in multiword utte…

Search for WH production with a light Higgs boson decaying to prompt electron-jets in proton–proton collisions at \(\sqrt {s}=7\)  TeV with the ATLAS…

2013

A search is performed for WH production with a light Higgs boson decaying to hidden-sector particles resulting in clusters of collimated electrons, known as electron-jets. The search is performed with 2.04 fb[superscript −1] of data collected in 2011 with the ATLAS detector at the Large Hadron Collider in proton–proton collisions at √s=7 TeV . One event satisfying the signal selection criteria is observed, which is consistent with the expected background rate. Limits on the product of the WH production cross section and the branching ratio of a Higgs boson decaying to prompt electron-jets are calculated as a function of a Higgs boson mass in the range from 100 to 140 GeV.

Effects of weekend starvation and the duration of daily feeding on production parameters of rainbow trout Oncorhynchus mykiss

2021

Abstract It would often be practical to starve the cultivated fishes over the weekends, e.g. to save in labour costs. We evaluated the possibility that domesticated juvenile rainbow trout (Oncorhynchus mykiss) could compensate for the lost growth of the 2-day weekend starvation by either hyperphagic response and/or by lower feed conversion ratio, compared to the fish fed every day in an 8-week experiment. Rainbow trout (initial weight c. 30 g, temperature 16 °C) starved during the weekends were able to increase feed intake during the weekdays clearly above the intake of the control fish after the first two weekends, also seen as an increase of the compensation coefficients over the last fou…

The Multivariate Individual Selection of Diagnostic Tests and the Reserved Diagnostic Statement: An Optimum Combination of Two New Methods for the Co…

1984

A combination of two new methods for the diagnostic procedure in computer-aided differential diagnosis is presented. It is constructed on the basis of new results of our own in the field of mathematical decision theory and is demonstrated by the differential diagnosis of congenital heart diseases by means of ECG features.