Search results for "SELE"
showing 10 items of 4721 documents
Unexplored nucleophilic ring opening of aziridines.
2010
The reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields g-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles. A comparative study with the reactivity of this enediolates with epoxides is included.
Data from: Maintenance costs of male dominance and sexually antagonistic selection in the wild
2019
1. Variation in dominance status determines male mating and reproductive success, but natural selection for male dominance can be detrimental or antagonistic for female performance, and ultimately their fitness. Attaining and maintaining a high dominance status in a population of competing individuals is physiologically costly for males. But how male dominance status is mediated by maintenance energetics is currently not well understood, nor are the correlational effects of male energetics on his sisters recognized. 2. We conducted laboratory and field experiments on rodent populations to test whether selective breeding for male dominance status (dominant vs. subordinate breeding lines) ant…
Maintenance costs of male dominance and sexually antagonistic selection in the wild
2018
Variation in dominance status determines male mating and reproductive success, but natural selection for male dominance can be detrimental or antagonistic for female performance, and ultimately their fitness. Attaining and maintaining a high dominance status in a population of competing individuals is physiologically costly for males. But how male dominance status is mediated by maintenance energetics is currently not well understood, nor are the corresponding effects of male energetics on his sisters recognized. We conducted laboratory and field experiments on rodent populations to test whether selective breeding for male dominance status (dominant vs. subordinate breeding lines) antagonis…
Timing of reproductive effort as an alternative mating strategy in young black grouse (Tetrao tetrix) males
2014
Seksuaalivalinta aiheuttaa yksilöiden välille kilpailua parittelukumppaneista, minkä johdosta osa yksilöistä lisääntyy toisia enemmän. Elinkiertoteorian mukaan yksilöt eivät niukkojen resurssien vuoksi pysty tehokkaasti kohdentamaan energiaa samanaikaisesti useisiin toimintoihin, kuten kasvuun, selviytymiseen ja lisääntymiseen. Ikä, suuri koko ja näyttävät seksuaaliornamentit ovat seksuaalivalinnassa menestyvän yksilön merkkejä, sillä tällaisilla yksilöillä riittää energiaa elintärkeiden toimintojen lisäksi myös lisääntymiseen. Tavallisesti ne menestyvätkin parhaiten kilpailussa parittelukumppaneista. Nuoret tai huonokuntoiset yksilöt voivat kuitenkin turvautua vaihtoehtoisiin lisääntymisst…
Influence of Surface-Related Phenomena on Mechanism, Selectivity, and Conversion of TiO2 -Induced Photocatalytic Reactions
2018
Heterogeneous photocatalysis is the result of an inextricable connection of several factors differently contributing to the overall process. Photon absorption is the “sine qua non” condition for the reaction to occur. In fact, photons can be considered as immaterial reactants, and all of the phenomena related to the interaction of light–matter play a prominent role. However, other factors contribute in a concerted way to address the reaction, so that the relative contribution of each of them is often difficult to evaluate. In this framework, the present paper highlights some aspects of the interaction of TiO 2 surface-adsorbate species that could be underestimated and their influence on the…
Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Function…
2017
International audience; Reported herein is the first stereoselective controlled ROP of a specific family of racemic functional β-lactones, namely 4-alkoxymethylene-β-propiolactones (BPL(OR) s). This process is catalyzed by an yttrium complex stabilized by a nonchiral tetradentate amino alkoxy bisphenolate ligand _ONOO(R'2) ₍2-) , which features both a good activity and a high degree of control over the molar masses of the resulting functional poly(3-hydroxyalkanoate)s. A simple modification of the R' substituents in ortho and para position on the ligand platform allows for a complete reversal from virtually pure syndioselectivity (Ps up to 0.91 with R'=cumyl) to very high isoselectivity (Pi…
La selección de tareas para la evaluación de textos en comprensión lectora
2023
La literatura existente establece que las características de las preguntas o de los textos influyen en el rendimiento en comprensión lectora del alumnado. El objetivo de esta investigación fue determinar qué criterios se pueden utilizar para medir la compresión lectora a partir de la selección de tareas y del tipo de texto seleccionado. Específicamente, se han estudiado las características del texto (legibilidad y situación lectora) y las tareas de comprensión (procesos lectores y modalidad de la pregunta). Mediante una técnica de contrabalanceo se analizan las interacciones entre las diferentes variables para valorar cómo influyen en la comprensión de alumnado de 4º de Primaria. (N=122). D…
A hybrid MCDM approach for ranking suppliers by considering ethical factors
2016
One of the negative effects of cooperating with un-ethically behaving suppliers is that it may devastate the companies' credibility among employees, customers and the public. In this paper, a hybrid Multiple Criteria Decision Making (MCDM) approach (Disjunctive-WPM method) is proposed to resolve this limitation. The proposed methods consist of the following steps: 1. drop unethical solutions and 2. rank the remaining solutions. Therefore, the aim of this paper is the application of the DisjunctiveWPM method to supplier selection problem by adding ethical factors into the analysis. In addition, a comparative analysis to the traditional WMP method is carried out. The proposed method appears t…
Darwin i la millora genètica animal: evolució aplicada a la producció animal
2013
Darwin va reflexionar sobre la potencialitat de la selecció natural comparant-la amb els efectes que han aconseguit els éssers humans amb la selecció artifi cial. En aquest treball s’analitza com, encara que la similitud entre ambdós tipus de selecció és visible, hi ha també importants diferències. També es presenten dos exemples d’aplicacions de la teoria evolutiva: la possible importància de la selecció sexual en la introducció de peixos transgènics i la selecció de caràcters socials en el context d’una millora genètica respectuosa amb el benestar animal.
Bateman gradients from first principles
2022
In 1948, Angus Bateman presented experiments and concepts that remain influential and debated in sexual selection. The Bateman gradient relates reproductive success to mate number, and Bateman presented this as the cause of intra-masculine selection. A deeper causal level was subsequently asserted: that the ultimate cause of sex differences in Bateman gradients is the sex difference in gamete numbers, an argument that remains controversial and without mathematical backup. Here I develop models showing how asymmetry in gamete numbers alone can generate steeper Bateman gradients in males. This conclusion remains when the further asymmetry of internal fertilisation is added to the model and fe…