Search results for "SEPARATION"
showing 5 items of 865 documents
Calculation of ternary polymer solution phase diagram via compressible lattice fluid model extended to specific interactions
2012
Ternary polymer solutions are currently employed for the production of porous structures (e.g. membranes and scaffolds for tissue engineering) via liquid-liquid phase separation techniques. The relation between processing conditions and thermodynamic features of the considered polymeric system determines the morphology of the as-prepared membrane. Therefore, in order to achieve a better control on a porous structure, a deep characterization of the phase behavior of a polymer solution is needed. The experimental derivation of phase diagrams is highly cost and time consuming, thus usually the cloud point curves of the system are directly measured. In this work, the compressible lattice fluid …
La preservación del favor filii en supuestos de ruptura de la convivencia de los acogedores, tutores o guardadores del menor
2021
Cuando la guarda del menor por parte de los progenitores no es posible y esta es atribuida de forma conjunta a dos personas convivientes que posteriormente cesan dicha convivencia, resulta necesario determinar cuál de ellas va a ejercer a partir de ese momento las funciones inherentes a dicha guarda. Las posibles soluciones dependerán de si se trata de un supuesto de acogimiento, de tutela o de siempre guarda. When care of the child by the parents is not possible and is attributed jointly to two people living together who subsequently stop living together, it is necessary to determine which of them will exercise the functions inherent to the care from that moment on. The possible solutions …
The mechanism of retro-cue effect in visual working memory : Cognitive phase separation
2020
Retro-cue effect (RCE) refers to the phenomenon that individuals can use retro-cues to improve their visual working memory (VWM) performance of target items after memory stimuli disappear. To explain the mechanism of RCE in VWM, five different hypotheses have been proposed by previous studies: the hypothesis of enhancing target representations, the hypothesis of forgetting non-target representations, the hypothesis of preventing memory degradation, the hypothesis of preventing interference from probe array and the hypothesis of cognitive phase separation. Although RCE has been repeatedly observed in previous studies, the mechanism of RCE remains unclear. In this study, we conducted three ex…
Diallyldimethylammonium Chloride (DADMAC) in Water Treated with Poly-Diallyldimethylammonium Chloride (PDADMAC) by Reversed-Phase Ion-Pair Chromatogr…
2023
Poly-diallyldimethylammonium (PDADMAC) chloride is a flocculant agent extensively used in water clarification treatments. Commercial polyelectrolyte formulations often contain residual monomer (DADMAC), reaction by-products and other reactants as contaminants that could potentially affect human health. In the present study, we optimized an analytical method based on reversed-phase ion-pair chromatography coupled with mass spectrometry for quantifying ultra-trace levels of DADMAC, without preliminary treatments, in drinking water distributed by the Palermo aqueduct. The method was validated in terms of accuracy (recovery between 80 to 120%), precision (RSD < 10%), linearity range (from 0.…
Kinetics of phase separation in thin films: Lattice versus continuum models for solid binary mixtures
2008
A description of phase separation kinetics for solid binary (A,B) mixtures in thin film geometry based on the Kawasaki spin-exchange kinetic Ising model is presented in a discrete lattice molecular field formulation. It is shown that the model describes the interplay of wetting layer formation and lateral phase separation, which leads to a characteristic domain size $\ell(t)$ in the directions parallel to the confining walls that grows according to the Lifshitz-Slyozov $t^{1/3}$ law with time $t$ after the quench. Near the critical point of the model, the description is shown to be equivalent to the standard treatments based on Ginzburg-Landau models. Unlike the latter, the present treatmen…